论文信息 - N → N′ ACYL MIGRATION IN AN ETHYLENEDIAMINE DERIVATIVE: ISOLATION AND NMR CHARACTERIZATION OF A REACTION INTERMEDIATE - 字舞流文

N → N′ ACYL MIGRATION IN AN ETHYLENEDIAMINE DERIVATIVE: ISOLATION AND NMR CHARACTERIZATION OF A REACTION INTERMEDIATE

The isolation and characterization by 1H and 13C-NMR spectroscopy of a reaction intermediate in a rearrangement with acyl migration in an ethylenediamine derivative is presented.

A. M. Reverdito | M. Blanco | A. Salerno | I. Perillo | María B. García

[1] A. Salerno,et al. Reduction of Substituted 1H‐4,5‐Dihydroimidazolium Salts. , 1993 .

[2] A. Salerno,et al. Reduction of substituted 1H‐4,5‐dihydroimidazolium salts , 1992 .

[3] A. M. Reverdito,et al. Synthesis and hydrolysis of substituted tetrahydropyrimidinium salts. Behaviour of the degradation products on varying pH , 1991 .

[4] A. M. Reverdito,et al. HPTLC : a valuable tool for elucidating the mechanism of intramolecular N→N' acyl transfer in N-acylalkylenediamine derivatives , 1991 .

[5] A. M. Reverdito,et al. Synthesis and hydrolysis of substituted imidazolinium salts. Behaviour of the degradation products on varying pH , 1987 .

[6] A. Ghosh,et al. Direct observation of simple tetrahedral intermediates , 1981 .

[7] I. Perillo,et al. ALKALINE HYDROLYSIS OF 1,2,3‐TRISUBSTITUTED CYCLIC AMIDINIUM SALTS. KINETIC STUDY OF N→N′ ACYL MIGRATION IN ALKALINE SOLUTION IN AN ETHYLENEDIAMINE DERIVATIVE , 1978 .

[8] I. Perillo,et al. Reaction of an asymmetric imidazolinium compound with nucleophiles , 1975 .

[9] T. H. Siddall,et al. Nuclear magnetic resonance studies of amides , 1970 .

[10] D. Robinson. Direct observation of a tetrahedral intermediate during amidine hydrolysis , 1970 .

[11] W. Jencks,et al. MECHANISM AND CATALYSIS OF THE HYDROLYSIS OF A FORMAMIDINIUM COMPOUND. , 1967 .

[12] D. Beke. Heterocyclic Pseudo Bases , 1963 .