A Review of FFA Esterification for Biodiesel Production

Because of the limited reserve of fossil sources such as petroleum, natural gas and coal, biodiesel that is produced from biomass is an attractive energy resource. Biodiesel is a clean energy that has the closest quality to diesel fuel. However, the conventional biodiesel production cost is higher than petroleum-based diesel since its being produced mostly from expensive high-quality virgin oil. Many researchers interest in using low-cost high free fatty acid (FFA) oils as the feedstock for biodiesel production by esterification process. This paper reviews the effect of operating parameters on the FFA conversion to biodiesel with esterification, including alcohol to oil molar ratio, reaction temperature, reaction time, catalyst amount and type. The esterification technologies and economic aspects of biodiesel as also addressed.

[1]  Yong Wang,et al.  COMPARISON OF TWO DIFFERENT PROCESSES TO SYNTHESIZE BIODIESEL BY WASTE COOKING OIL , 2006 .

[2]  A. Kondo,et al.  Biodiesel fuel production by transesterification of oils. , 2001, Journal of bioscience and bioengineering.

[3]  A. Kondo,et al.  Whole cell biocatalyst for biodiesel fuel production utilizing Rhizopus oryzae cells immobilized within biomass support particles. , 2001, Biochemical engineering journal.

[4]  Udo Kreutzer,et al.  Manufacture of fatty alcohols based on natural fats and oils , 1984 .

[5]  A. S. Ramadhas,et al.  Biodiesel production from high FFA rubber seed oil , 2005 .

[6]  S. Deng,et al.  Optimization of biodiesel production from edible and non-edible vegetable oils , 2009 .

[7]  Elio Santacesaria,et al.  Synthesis of biodiesel via homogeneous Lewis acid catalyst , 2005 .

[8]  H. Raheman,et al.  Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology. , 2006, Bioresource technology.

[9]  M. Haas Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock , 2005 .

[10]  Marc A. Dubé,et al.  Acid-catalyzed production of biodiesel from waste frying oil , 2006 .

[11]  M. Almeida,et al.  Production of biodiesel from acid waste lard. , 2009, Bioresource technology.

[12]  Sources of Methyl Ester Yield Reduction in Methanolysis of Recycled Vegetable Oil , 2009 .

[13]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis. , 2003, Bioresource technology.

[14]  A. Phan,et al.  Biodiesel production from waste cooking oils , 2008 .

[15]  Dadan Kusdiana,et al.  Effects of water on biodiesel fuel production by supercritical methanol treatment. , 2004, Bioresource technology.

[16]  Olivera S. Stamenković,et al.  Biodiesel production from tobacco (Nicotiana tabacum L.) seed oil with a high content of free fatty acids , 2006 .

[17]  Shweta Shah,et al.  Biodiesel Preparation by Lipase-Catalyzed Transesterification of Jatropha Oil , 2004 .

[18]  T. Foglia,et al.  Lipase-catalyzed production of biodiesel , 1996 .

[19]  Yomi Watanabe,et al.  Conversion of degummed soybean oil to biodiesel fuel with immobilized Candida antarctica lipase , 2002 .

[20]  N. R. Kamini,et al.  Lipase catalyzed methanolysis of vegetable oils in aqueous medium by Cryptococcus spp. S-2 , 2001 .

[21]  A. S. Ramadhas,et al.  Biodiesel Production from Rubber Seed Oil , 2008 .

[22]  Jon Van Gerpen,et al.  Biodiesel Production and Fuel Quality , 2004 .

[23]  Adam Khan Research into Biodiesel KINETICS & CATALYST DEVELOPMENT , 2002 .

[24]  Lawrence L. Tavlarides,et al.  Investigations on supercritical transesterification of chicken fat for biodiesel production from low-cost lipid feedstocks , 2010 .

[25]  G. Corro,et al.  Biodiesel from waste frying oil. Two step process using acidified SiO2 for esterification step , 2011 .

[26]  S. Al-zahrani,et al.  Ethanesulfonic acid-based esterification of industrial acidic crude palm oil for biodiesel production. , 2011, Bioresource technology.

[27]  Chakrit Tongurai,et al.  Continuous esterification for biodiesel production from palm fatty acid distillate using economical process , 2009 .

[28]  M. Hanna,et al.  THE EFFECTS OF CATALYST, FREE FATTY ACIDS, AND WATER ON TRANSESTERIFICATION OF BEEF TALLOW , 1998 .

[29]  A. Kondo,et al.  Biodiesel fuel production from plant oil catalyzed by Rhizopus oryzae lipase in a water-containing system without an organic solvent. , 1999, Journal of bioscience and bioengineering.

[30]  Sininart Chongkhong,et al.  Biodiesel production by esterification of palm fatty acid distillate , 2007 .

[31]  W. H. Wu,et al.  Optimizing production of ethyl esters of grease using 95% ethanol by response surface methodology , 1999 .

[32]  M. Gürü,et al.  Biodiesel production from waste chicken fat based sources and evaluation with Mg based additive in a diesel engine , 2010 .

[33]  T. Foglia,et al.  Production of alkyl esters from tallow and grease using lipase immobilized in a phyllosilicate sol-gel , 2001 .

[34]  H. Raheman,et al.  Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids , 2005 .

[35]  James I. Chang,et al.  Biodiesel production from residual oils recovered from spent bleaching earth , 2010 .

[36]  Chawalit Ngamcharussrivichai,et al.  Al2O3-supported alkali and alkali earth metal oxides for transesterification of palm kernel oil and coconut oil. , 2009 .

[37]  Shiro Saka,et al.  Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process , 2006 .

[38]  J. V. Gerpen,et al.  BIODIESEL PRODUCTION VIA ACID CATALYSIS , 1999 .

[39]  S. Yusup,et al.  Reactive extraction and in situ esterification of Jatropha curcas L. seeds for the production of biodiesel , 2010 .

[40]  S. Furuta,et al.  Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure , 2004 .

[41]  Dae Won Lee,et al.  The heterogeneous catalyst system for the continuous conversion of free fatty acids in used vegetable oils for the production of biodiesel , 2008 .

[42]  C. Muraleedharan,et al.  Use of vegetable oils as I.C. engine fuels—A review , 2004 .

[43]  Kadir Aydin,et al.  Using of cotton oil soapstock biodiesel–diesel fuel blends as an alternative diesel fuel , 2008 .