The hydrolysis of isocyanic acid (HNCO) was investigated on various oxidic catalysts, including TiO2, V2O5/TiO2, and V2O5−WO3/TiO2. The kinetics were studied using powdered samples in a microreactor. The conversions of HNCO are high even at the high space velocities (106 h-1) and low temperatures (150 °C) used in the tests. The highest rate for the hydrolysis of HNCO was found on pure TiO2 powder, while the addition of vanadia and tungsta decreased the activity slightly. To compare the rate of HNCO hydrolysis with the rate of the SCR reaction, uncorrected first-order rate constants were calculated for both reactions using the integral equation for a plug flow reactor. For a catalyst sample containing both WO3 and V2O5, the rate constant for hydrolysis of HNCO at low temperatures is about 2 orders of magnitude higher than the respective rate constant for the SCR reaction, whereas at high temperatures, the rate constants are of comparable magnitude. The apparent activation energy of the hydrolysis reaction ...