Stimulated Emission of Active Media in the Red Spectral Range

Spectral, luminescent, and lasing characteristics of chromene dyes and their julolidine analogs emitting in the red spectral range are investigated experimentally and theoretically. It is shown that the cause for a low lasing efficiency of oxochromene compared with iminochromene is a high intersystem crossing to the T1 state and the presence of the induced T1→Tn absorption in the region of the luminescence band.

[1]  V. Plotnikov Theoretical Foundations of the Classification of Molecules by Luminescence Spectra , 1980 .

[2]  T. Kopylova,et al.  Theoretical investigation of photoprocesses in complex organic compounds upon high-power laser excitation , 2009 .

[3]  A. Becke Density-functional thermochemistry. III. The role of exact exchange , 1993 .

[4]  A. Semeikin,et al.  The computational and experimental investigations of photophysical and spectroscopic properties of BF2 dipyrromethene complexes. , 2014, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[5]  A. Vasdekis,et al.  Amplification of optical pulse sequences at a high repetition rate in a polymer slab waveguide , 2007 .

[6]  G. V. Mayer,et al.  Lasing of pyrromethene 567 in solid matrices , 2013 .

[7]  D. Sundholm,et al.  Computational studies of photophysical properties of porphin, tetraphenylporphyrin and tetrabenzoporphyrin. , 2012, Physical chemistry chemical physics : PCCP.

[8]  J. Lakowicz Principles of fluorescence spectroscopy , 1983 .

[9]  A. Granovsky,et al.  Extended multi-configuration quasi-degenerate perturbation theory: the new approach to multi-state multi-reference perturbation theory. , 2011, The Journal of chemical physics.

[10]  Study of the dynamics of induced emission from organic compounds under pulsed laser pumping , 2013 .

[11]  Á. Costela,et al.  Solid state dye lasers with scattering feedback , 2013 .

[12]  Uli Lemmer,et al.  Compact spectroscopy system based on tunable organic semiconductor lasers , 2010 .

[13]  A. B. Harvey,et al.  Cars measurement of vibrational temperatures in electric discharges , 1976 .

[14]  Wolfgang Kowalsky,et al.  An Ultraviolet Organic Thin‐Film Solid‐State Laser for Biomarker Applications , 2005 .

[15]  T. A. Solodova,et al.  Computational and experimental investigation of the optical properties of the chromene dyes. , 2015, The journal of physical chemistry. A.

[16]  Helena Jelínková,et al.  Lasers for medical applications , 2013 .