Processing metallic glasses by selective laser melting

Metallic glasses and their descendants, the so-called bulk metallic glasses (BMGs), can be regarded as frozen liquids with a high resistance to crystallization. The lack of a conventional structure turns them into a material exhibiting near-theoretical strength, low Young's modulus and large elasticity. These unique mechanical properties can be only obtained when the metallic melts are rapidly cooled to bypass the nucleation and growth of crystals. Most of the commonly known and used processing routes, such as casting, melt spinning or gas atomization, have intrinsic limitations regarding the complexity and dimensions of the geometries. Here, it is shown that selective laser melting (SLM), which is usually used to process conventional metallic alloys and polymers, can be applied to implement complex geometries and components from an Fe-base metallic glass. This approach is in principle viable for a large variety of metallic alloys and paves the way for the novel synthesis of materials and the development of parts with advanced functional and structural properties without limitations in size and intricacy.

[1]  A. Takeuchi,et al.  Recent development and application products of bulk glassy alloys , 2011 .

[2]  David L. Bourell,et al.  Selective laser sintering of metals and ceramics , 1992 .

[3]  K. Osakada,et al.  Rapid Manufacturing of Metal Components by Laser Forming , 2006 .

[4]  D. Turnbull Metastable structures in metallurgy , 1981 .

[5]  C. Angell,et al.  Formation of Glasses from Liquids and Biopolymers , 1995, Science.

[6]  W. Johnson,et al.  A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 , 1993 .

[7]  Weihua Wang,et al.  Elastic constants and their pressure dependence of Zr41Ti14Cu12.5Ni9Be22.5C1 bulk metallic glass , 1999 .

[8]  Hung Chen REVIEW ARTICLE: Glassy metals , 1980 .

[9]  A. L. Greer,et al.  Metallic glasses…on the threshold , 2009 .

[10]  M. Stoica,et al.  New ternary Fe-based bulk metallic glass with high boron content , 2006 .

[11]  William L. Johnson,et al.  Thermodynamic and kinetic aspects of the crystal to glass transformation in metallic materials , 1986 .

[12]  M. Demetriou,et al.  Beating Crystallization in Glass-Forming Metals by Millisecond Heating and Processing , 2011, Science.

[13]  Mingwei Chen,et al.  Mechanical Behavior of Metallic Glasses: Microscopic Understanding of Strength and Ductility , 2008 .

[14]  A. L. Greer,et al.  Bulk Metallic Glasses: At the Cutting Edge of Metals Research , 2007 .

[15]  A. Inoue,et al.  The world's biggest glassy alloy ever made , 2012 .

[16]  Michael D. Gilchrist,et al.  Towards nano-injection molding , 2012 .

[17]  Daniel B. Miracle A structural model for metallic glasses , 2004 .

[18]  A. J. Barnes,et al.  Thermoplastic blow molding of metals , 2011 .

[19]  D. Turnbull,et al.  Structure and Properties of Metallic Glasses , 1978, Science.

[20]  Jingsheng Wang,et al.  Amorphous and nanostructured Al85Ni5Y6Co2Fe2 powder prepared by nitrogen gas-atomization , 2007 .

[21]  Chung-Yu Wu,et al.  Nanoimprint of gratings on a bulk metallic glass , 2007 .

[22]  M. Elahinia,et al.  Manufacturing and processing of NiTi implants: A review , 2012 .

[23]  Weihua Wang,et al.  Bulk metallic glasses , 2004 .

[24]  E. Lavernia,et al.  Spray Atomization and Deposition , 1996 .

[25]  Baolong Zheng,et al.  Processing and Behavior of Fe-Based Metallic Glass Components via Laser-Engineered Net Shaping , 2009 .

[26]  W. Johnson Bulk Glass-Forming Metallic Alloys: Science and Technology , 1999 .

[27]  M. Telford The case for bulk metallic glass , 2004 .

[28]  H. Liebermann The dependence of the Geometry of glassy alloy ribbons on the chill block melt-spinning process parameters , 1980 .

[29]  John J. Lewandowski,et al.  Mechanical Properties of Bulk Metallic Glasses , 2007 .

[30]  Kenneth F. Kelton,et al.  Structural Aspects of Metallic Glasses , 2007 .

[31]  A. Yavari,et al.  Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties , 2003, Nature materials.

[32]  L. Froyen,et al.  Fundamentals of Selective Laser Melting of alloyed steel powders , 2006 .

[33]  A. Inoue Stabilization of metallic supercooled liquid and bulk amorphous alloys , 2000 .

[34]  C. Pampillo Flow and fracture in amorphous alloys , 1975 .

[35]  J. F. Löffler Bulk metallic glasses , 2003 .

[36]  T. Hufnagel,et al.  Mechanical behavior of amorphous alloys , 2007 .

[37]  S. Pang,et al.  Ductile Fe–Mo–P–C–B–Si bulk metallic glasses with high saturation magnetization , 2009 .

[38]  W. L. Johnson,et al.  A highly processable metallic glass: Zr[sub 41. 2]Ti[sub 13. 8]Cu[sub 12. 5]Ni[sub 10. 0]Be[sub 22. 5] , 1993 .

[39]  D. Turnbull Under what conditions can a glass be formed , 1969 .