On-line monitoring equipment for wastewater treatment processes: state of the art.

A (non-exhaustive) survey of new and existing technologies for the monitoring of wastewater treatment plants is presented. Emphasis is given to the way these sensors can provide insight in the ongoing (bio-) processes. Three different uses for sensors can be found: for monitoring (operator support), in automatic control systems and as tools for plant auditing/optimization/modelling by consultants. From this, sensors have been classified in two basic types: (i) reliable, simple and low maintenance sensors for day-to-day monitoring and control and (ii) advanced, higher maintenance sensors that are used in auditing, model calibration and optimisation. The paper is organized according to the typical unit processes of biological wastewater treatment systems: anaerobic digestion, activated sludge, nutrient removal and sedimentation. Attention is drawn to a number of practical problems associated with the use of sophisticated sensors in the harsh (dirty) conditions of wastewater treatment processes. The use of autocalibration and built-in sensor checks, cleaning systems and reliable sample preparation units is illustrated. The paper ends with a discussion of the applicability of the different sensors.

[1]  M W Peck,et al.  On‐line fluorescence‐monitoring of the methanogenic fermentation , 1992, Biotechnology and bioengineering.

[2]  Frédéric Ehlinger,et al.  Control Parameter Variations in an Anaerobic Fluidised Bed Reactor Subjected to Organic Shockloads , 1992 .

[3]  Daniel R. Thévenot,et al.  Elements in the Interpretation of Platinum Electrode Potentials in Biological Treatment , 1992 .

[4]  T. Waite,et al.  Rapid Structure Characterization of Bacterial Aggregates , 1998 .

[5]  Willy Verstraete,et al.  Image analysis to estimate the settleability and concentration of activated sludge , 1997 .

[6]  A. E. Greenberg,et al.  Standard methods for the examination of water and wastewater : supplement to the sixteenth edition , 1988 .

[7]  K. Gernaey,et al.  Biosensing activated sludge. , 1999 .

[8]  N. Matsché,et al.  UV absorption as control-parameter for biological treatment plants , 1996 .

[9]  Richard M. Stuetz,et al.  On‐line monitoring of wastewater quality: a review , 2001 .

[10]  B. Teichgräber Control Strategies for a Highly Loaded Biological Ammonia Elimination Process , 1993 .

[11]  N. Revsbech,et al.  A Microscale NO(3)(-) Biosensor for Environmental Applications. , 1997, Analytical chemistry.

[12]  P A Vanrolleghem,et al.  Automatic buffer capacity model building for the purpose of water quality monitoring. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[13]  N. Revsbech,et al.  Fast responding biosensor for on-line determination of nitrate/nitrite in activated sludge , 2000 .

[14]  André Pauss,et al.  Hydrogen monitoring in anaerobic sludge bed reactors at various hydraulic regimes and loading rates , 1993 .

[15]  J Tramper,et al.  Automation of selective assays for on-line bioprocess monitoring by flow-injection analysis. , 1996, Trends in biotechnology.

[16]  Peter A. Vanrolleghem,et al.  RESPIROMETRY AS TOOL FOR RAPID CHARACTERIZATION OF WASTEWATER AND ACTIVATED SLUDGE , 1995 .

[17]  M. Pons,et al.  Automated monitoring of activated sludge in a pilot plant using image analysis. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[18]  D. L. Hawkes,et al.  The Stability of Anaerobic Digesters Operating on a Food-Processing Wastewater , 1992 .

[19]  G. K. Anderson,et al.  pH control in anaerobic treatment of industrial wastewater , 1992 .

[20]  Andrea G. Capodaglio,et al.  Wastewater Treatment Plants under Transient Loading – Performance, Modelling and Control , 1993 .

[21]  J. Ruzicka,et al.  Flow injection analyses , 1975 .

[22]  G. A. Ekama,et al.  Oxygen Utilization Rate as a Control Parameter for the Aerobic Stage in Dual Digestion , 1990 .

[23]  K. L. Andersen,et al.  TESTING ON-LINE MONITORS FOR AMMONIA, NITRATE, ORTHO-PHOSPHATE AND SUSPENDED SOLIDS IN ACTIVATED SLUDGE SEWAGE TREATMENT PLANTS , 1990 .

[24]  J. M. C. Reid,et al.  Automatic monitoring of activated sludge settling characteristics and plant control applications , 1993 .

[25]  A. Andreadakis PHYSICAL AND CHEMICAL PROPERTIES OF ACTIVATED SLUDGE FLOC , 1993 .

[26]  H. Soeberg,et al.  A REAL TIME MEASUREMENT SYSTEM FOR AN ACTIVATED SLUDGE WASTEWATER TREATMENT PLANT , 1990 .

[27]  G. Olsson,et al.  Determining Influent Short-Term Biochemical Oxygen Demand by Combined Respirometry and Estimation , 1993 .

[28]  Linda M. Harvey,et al.  Monitoring of Submerged Bioprocesses , 1999 .

[29]  M. Beccari,et al.  Inhibitory effects on nitrification by typical compounds in coke plant wastewaters Inhibitory effect , 1980 .

[30]  Peter A. Vanrolleghem,et al.  Advanced instrumentation, data interpretation, and control of biotechnological processes , 1998 .

[31]  K. Okano,et al.  Measurement of cell density in cultures of aggregative organisms by continuous-dilution-photometric-assay , 1993 .

[32]  Willy Verstraete,et al.  Automated buffer capacity based sensor for effluent quality monitoring , 1995 .

[33]  Robert B. Dean,et al.  The use of ultra-violet absorbance for monitoring the total organic carbon content of water and wastewater , 1972 .

[34]  K. Gernaey,et al.  Modeling aerobic carbon source degradation processes using titrimetric data and combined respirometric–titrimetric data: Experimental data and model structure , 2002, Biotechnology and bioengineering.

[35]  Peter A. Vanrolleghem,et al.  Optimal design of in-sensor-experiments for on-line modelling of nitrogen removal processes , 1995 .

[36]  Tore Hägglund,et al.  Automatic tuning of simple regulators with specifications on phase and amplitude margins , 1984, Autom..

[37]  E. Ficara,et al.  Characterization of textile wastewater and other industrial wastewaters by respirometric and titration biosensors , 1999 .

[38]  J Harmand,et al.  On-line measurements of COD, TOC, VFA, total and partial alkalinity in anaerobic digestion processes using infra-red ectrometry. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[39]  J. Ganczarczyk,et al.  Structure of activated sludge floes , 1990, Biotechnology and bioengineering.

[40]  D. L. Hawkes,et al.  A new instrument for on-line measurement of bicarbonate alkalinity , 1993 .

[41]  Krist V. Gernaey,et al.  Nitrification monitoring in activated sludge by oxygen uptake rate (OUR) measurements. , 1996 .

[42]  A. C. Di Pinto,et al.  ANAEROBIC PROCESS CONTROL BY AUTOMATED BICARBONATE MONITORING , 1990 .

[43]  J. G. Kuenen,et al.  Continuous measurement of microbial heat production in laboratory fermentors , 1993, Biotechnology and bioengineering.

[44]  Krist V. Gernaey,et al.  Measurement of ammonium concentration and nitrification rate by a new titrimetric biosensor , 1998 .

[45]  Sang-eun Lee,et al.  Evaluation of alternative sludge settleability indices , 1983 .

[46]  M. Healey Improvements in the activated sludge process in the U.K. and U.S. , 1989 .

[47]  Kenneth T. V. Grattan,et al.  Cross Comparison of Techniques for the Monitoring of Total Organic Carbon (TOC) in Water Sources and Supplies , 1993 .

[48]  H. Wacheux,et al.  NH4 automatic analysers for wastewater treatment plant: evaluation test at laboratory and field level , 1996 .

[49]  G. Brunner,et al.  On-line monitoring of organic substances with high-pressure liquid chromatography (HPLC) during the anaerobic fermentation of waste-water , 1994, Applied Microbiology and Biotechnology.

[50]  A. Molloy,et al.  A WASTEWATER/WATER PROCESS MONITORING SYSTEM ALLOWING OPERATIONAL CONTROL — DEVELOPED BY AN OPERATIONAL MANAGER , 1990 .

[51]  R T Hatch,et al.  Monitoring of Saccharomyces cerevisiae in commercial bakers' yeast fermentation , 1995, Biotechnology and bioengineering.

[52]  D B Kell,et al.  Quantification of microbial productivity via multi‐angle light scattering and supervised learning , 1998, Biotechnology and bioengineering.

[53]  Hong Niu,et al.  A new biosensor for rapid oxygen demand measurement , 1998 .

[54]  Manuela Antonelli,et al.  The Denicon: a novel biosensor to control denitrification in biological wastewater treatment plants , 1996 .

[55]  George T. Tsao,et al.  Dissolved oxygen electrodes , 1979 .

[56]  W. Verstraete,et al.  On-line quantification of settling properties with in-sensor-experiments in an automated settlometer , 1995 .

[57]  T. Golden,et al.  Use of Methanogenic Activity Tests to Characterize Anaerobic Sludges, Screen for Anaerobic Biodegradability and Determine Toxicity Thresholds against Individual Anaerobic Trophic Groups and Species , 1992 .

[58]  Daniel I. C. Wang,et al.  Estimating cell concentration in the presence of suspended solids: A light scatter technique , 1992, Biotechnology and bioengineering.

[59]  Ken J. Hall,et al.  Real-Time Control of Wastewater Treatment Systems Using ORP , 1993 .

[60]  Peter A. Vanrolleghem,et al.  Respirometry in Control of the Activated Sludge Process: Principles , 1998 .

[61]  W. Verstraete,et al.  A new pH-based procedure to model toxic effects on nitrifiers in activated sludge. , 1999 .

[62]  K. Baba,et al.  OPERATING CONDITION DIAGNOSIS SYSTEM FOR ACTIVATED SLUDGE PROCESSES BASED ON MICROORGANISM IMAGE INFORMATION , 1990 .

[63]  K. Gernaey,et al.  Anoxic activated sludge monitoring with combined nitrate and titrimetric measurements. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[64]  U. Faust,et al.  Determination of Biomass by Ultrasonic Measurements , 1989, Applied and environmental microbiology.

[65]  Henrik A. Thomsen,et al.  N and P on-line meters: Requirements, maintenance and stability , 1996 .

[66]  Frieder W. Scheller,et al.  A fast estimation of biochemical oxygen demand using microbial sensors , 1988, Applied Microbiology and Biotechnology.

[67]  P A Vanrolleghem,et al.  A new one-dimensional clarifier model--verification using full-scale experimental data. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[68]  Pernille Ingildsen,et al.  Realising full-scale control in wastewater treatment systems using in situ nutrient sensors , 2002 .

[69]  H. Vandenhove Microcalorimetric Characterization of Bacterial Inocula , 1998 .

[70]  Ingo Klimant,et al.  Optical Fiber Sensor for Biological Oxygen Demand , 1994 .

[71]  In Situ Particle Size Characterisation on a Circular Clarifier of a Wastewater Treatment Plant , 2002 .

[72]  B. Ahring,et al.  A novel in-situ sampling and VFA sensor technique for anaerobic systems. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[73]  M. Henze,et al.  Effect of Supplemental Carbon Source on Phosphate Removal in an Alternating Activated Sludge Process , 1993 .

[74]  Peter A. Vanrolleghem,et al.  NDBEPR process optimization in SBRs: reduction of external carbon-source and oxygen supply , 1994 .

[75]  K. Barbusiński,et al.  Influence of substrate loading intensity on floc size in activated sludge process , 1995 .

[76]  W. Verstraete,et al.  An On-Line Respirographic Biosensor for the Characterization of Load and Toxicity of Wastewaters , 1994 .

[77]  D L Hawkes,et al.  Characterization of a prototype industrial on‐line analyzer for bicarbonate/carbonate monitoring , 1994, Biotechnology and bioengineering.

[78]  Ian W. Marison,et al.  The use of calorimetry in biotechnology , 1989 .

[79]  W. Pretorius,et al.  Optimisation of primary sludge acidogenic fermentation for biological nutrient removal , 1998 .

[80]  P. Vanrolleghem,et al.  Activated sludge monitoring with combined respirometric-titrimetric measurements. , 2001, Water research.

[81]  P. Vesilind The sludge volume index what is it , 1969 .

[82]  J. Nielsen,et al.  On-line and in situ monitoring of biomass in submerged cultivations , 1997 .

[83]  Yasuji Yamamoto,et al.  Simultaneous Removal of Nitrogen and Phosphorus in Intermittently Aerated 2-Tank Activated Sludge Process Using DO and ORP-Bending-Point Control , 1993 .

[84]  B. Martin,et al.  Comparison of gold and platinum electrode responses in activated sludge , 1993 .

[85]  J. Londong Strategies for Optimized Nitrate Reduction with Primary Denitrification , 1992 .

[86]  W. D. Meredith RECENT INNOVATIONS IN INSTRUMENTATION FOR SEWAGE TREATMENT PLANT MONITORING AND CONTROL , 1990 .

[87]  W. Frey,et al.  Nitrification Inhibition - A Source Identification Method for Combined Municipal and/or Industrial Wastewater Treatment Plants , 1992 .

[88]  H Bogaert,et al.  A titrimetric respirometer measuring the nitrifiable nitrogen in wastewater using insensor-experiment. , 2001, Water research.

[89]  Manuela Antonelli,et al.  A VFA measuring biosensor based on nitrate reduction , 1997 .

[90]  M. C. Tomei,et al.  Monitoring toxicity in anaerobic digesters by the rantox biosensor: theoretical background. , 1997, Biotechnology and bioengineering.

[91]  M. Henze,et al.  FLUORESCENCE MONITORING OF AN ALTERNATING ACTIVATED SLUDGE PROCESS , 1994 .

[92]  G. K. Anderson,et al.  Determination of bicarbonate and total volatile acid concentration in anaerobic digesters using a simple titration , 1992 .

[93]  I Karube,et al.  Microbial electrode BOD sensors , 1977, Biotechnology and bioengineering.

[94]  J. Bouvier On-line titrimetric sensor for the control of VFA and/or alkalinity in anaerobic digestion processes treating industrial vinas , 2002 .

[95]  Gustaf Olsson,et al.  SIMULTANEOUS DO CONTROL AND RESPIRATION ESTIMATION , 2002 .

[96]  S. Brookman,et al.  Estimation of biochemical oxygen demand in slurry and effluents using ultra-violet spectrophotometry , 1997 .

[97]  Z. Qian,et al.  RESPONSE CHARACTERISTICS OF A DEAD-CELL BOD SENSOR , 1998 .

[98]  Paul Lant,et al.  Activated sludge flocculation: on-line determination of floc size and the effect of shear , 2000 .

[99]  D. Archer,et al.  On‐line titration method for monitoring buffer capacity and total volatile fatty acid levels in anaerobic digesters , 1989, Biotechnology and bioengineering.

[100]  William B. Armiger,et al.  Control of BNR Processes by Regulation of the VFA/M Ratio , 1993 .

[101]  On-line Measurement of Viable Biomass , 1998 .

[102]  J F Van Impe,et al.  On-line viable biomass measurement and estimation of the specific growth rate of activated sludge from municipal wastewater treatment. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[103]  H. Wacheux,et al.  Inventory and Assessment of Automatic Nitrate Analyzers for Urban Sewage Works , 1993 .

[104]  A Rozzi,et al.  An automated system for monitoring the kinetics of biological oxidation of ammonia , 1980 .

[105]  T. Larsen,et al.  On-line measurements of settling characteristics in activated sludge , 1997 .

[106]  Christopher L. Davey,et al.  Introduction to the dielectric estimation of cellular biomass in real time, with special emphasis on measurements at high volume fractions , 1993 .

[107]  B. C. Blake‐Coleman,et al.  Determination of reactor biomass by acoustic resonance densitometry , 1986, Biotechnology and bioengineering.

[108]  W. Verstraete,et al.  On-line nitrification monitoring in activated sludge with a titrimetric sensor. , 1997 .

[109]  C. R. Thomas,et al.  The use of image analysis for morphological measurements on filamentous microorganisms. , 1988, Biotechnology and bioengineering.

[110]  W. Verstraete,et al.  Linking floc structure and settling properties to activated sludge population dynamics in an SBR. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[111]  W. Verstraete,et al.  Simultaneous Biokinetic Characterization of Heterotrophic and Nitrifying Populations of Activated Sludge with an On-Line Respirographic Biosensor , 1993 .

[112]  Olivier Thomas,et al.  Wastewater quality monitoring , 1997 .

[113]  On the use of structured compartment models for the activated sludge biodegradation process , 1992 .

[114]  J. J. Heijnen,et al.  The sharon process: an innovative method for nitrogen removal from ammonium-rich waste water , 1998 .

[115]  H. Tsugura,et al.  Evaluation of settleability of activated sludge using a sludge settling analyzer , 1989 .

[116]  Takashi Korenaga,et al.  WATER QUALITY MONITORING SYSTEM USING A FLOW-THROUGH SENSING DEVICE , 1990 .

[117]  P A Vanrolleghem,et al.  Status and future trends of ICA in wastewater treatment--a European perspective. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[118]  P A Vanrolleghem,et al.  An integrated sensor for the monitoring of aerobic and anoxic activated sludge activities in biological nitrogen removal plants. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[119]  A. Fiechter,et al.  Biomass determination. , 1992, Journal of biotechnology.

[120]  Ammonium concentration measurements using a titrometric biosensor , 1995 .

[121]  A. Turner,et al.  Whole-cell biosensors for environmental monitoring. , 1989, Biosensors.

[122]  A. Lynggaard-Jensen,et al.  Description and test of a new generation of nutrient sensors , 1996 .

[123]  S. Strand,et al.  Rapid BOD measurement for municipal wastewater samples using a biofilm electrode , 1984 .

[124]  J Villadsen,et al.  Semi-on-line analysis for fast and precise monitoring of bioreaction processes. , 2000, Biotechnology and bioengineering.

[125]  E. Arnold,et al.  Standard methods for the examination of water and wastewater. 16th ed. , 1985 .

[126]  J. Sørensen,et al.  Combined Oxygen and Nitrous Oxide Microsensor for Denitrification Studies , 1988, Applied and environmental microbiology.

[127]  W. Verstraete,et al.  On-Line stBOD Measurement and Toxicity Control of Wastewaters with a Respirographic Biosensor , 1996 .

[128]  Terry J. Mah,et al.  Automatic monitoring of denitrification rates and capacities in activated sludge processes using fluorescence or redox potential , 1998 .

[129]  A Rozzi,et al.  Methanogenic activity measurements by the MAIA biosensor: instructions guide. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[130]  Krist V. Gernaey,et al.  Evaluation of an ASM1 model calibration procedure on a municipal-industrial wastewater treatment plant , 2002 .