Combined Styrene/MMA/Nanoclay Cross-linker Effect on Wood-Polymer Composites (WPCs)

In the present study, batai wood (Paraserianthes moluccana) was impregnated with a combination of styrene, methyl methacrylate, and nanoclay in order to improve compression strength, thermal stability, and surface morphology. Styrene (ST) and methyl methacrylate (MMA) cross-linker introduced a co-polymerization reaction with cellulose in the wood cell wall and produced wood polymer composites (WPCs), as confirmed by Fourier Transform Infrared (FT-IR) Spectroscopy. The mechanical properties of the WPCs were significantly increased compared to the raw wood. Thermal properties of both raw wood and WPCs were evaluated by thermogravimetric analysis (TGA). WPCs exhibited higher thermal stability relative to the raw wood due to the co-polymerization reaction. The surface morphologies of the fracture surface for both the raw wood and WPCs were recorded using scanning electron microscopy (SEM). The SEM micrographs reveal that after polymerization, WPCs show smoother texture and adhesion compared to that of raw wood.

[1]  Mats Westin,et al.  Moisture Sorption, Biological Durability, and Mechanical Performance of WPC Containing Modified Wood and Polylactates , 2012 .

[2]  Khalina Abdan,et al.  MECHANICAL AND PHYSICAL PROPERTIES OF KENAF-DERIVED CELLULOSE (KDC)-FILLED POLYLACTIC ACID (PLA) COMPOSITES , 2012 .

[3]  Mohamad Rusop,et al.  Dimensional stability and water repellent efficiency measurement of chemically modified tropical light hardwood , 2012, BioResources.

[4]  S. Hamdan,et al.  The effect of alkali pretreatment on mechanical and morphological properties of tropical wood polymer composites , 2012 .

[5]  S. Hamdan,et al.  The effect of crosslinker on mechanical and morphological properties of tropical wood material composites , 2011 .

[6]  S. Hamdan,et al.  DYNAMIC YOUNG’S MODULUS, MORPHOLOGICAL, AND THERMAL STABILITY OF 5 TROPICAL LIGHT HARDWOODS MODIFIED BY BENZENE DIAZONIUM SALT TREATMENT , 2011 .

[7]  S. Hamdan,et al.  INFLUENCE OF N, N-DIMETHYLACETAMID ON THE THERMAL AND MECHANICAL PROPERTIES OF POLYMER-FILLED WOOD , 2010 .

[8]  S. Hamdan,et al.  MECHANICAL AND BIOLOGICAL PERFORMANCE OF SODIUM METAPERIODATE-IMPREGNATED PLASTICIZED WOOD (PW) , 2010 .

[9]  S. Hamdan,et al.  Effect of chemical treatment on rice husk (RH) reinforced polyethylene (PE) composites , 2010, BioResources.

[10]  S. Hamdan,et al.  Dynamic Young's modulus measurement of treated and post-treated tropical wood polymer composites (WPC) , 2009, BioResources.

[11]  Abdullah Al Mamun,et al.  Abaca fibre reinforced PP composites and comparison with jute and flax fibre PP composites , 2007 .

[12]  R. Rowell Chemical modification of wood: A short review , 2006 .

[13]  S. Yıldız,et al.  Mechanical properties and decay resistance of wood-polymer composites prepared from fast growing species in Turkey. , 2005, Bioresource technology.

[14]  S. Tohmura,et al.  Influence of the melamine content in melamine-urea-formaldehyde resins on formaldehyde emission and cured resin structure , 2001, Journal of Wood Science.

[15]  M. Misra,et al.  Sustainable Bio-Composites from Renewable Resources: Opportunities and Challenges in the Green Materials World , 2002, Renewable Energy.

[16]  G. Marx,et al.  Thermogravimetric and differential scanning calorimetric analysis of natural fibres and polypropylene , 1999 .

[17]  R. Zabel,et al.  Wood Microbiology: Decay and Its Prevention , 1993 .

[18]  M. Ramiah,et al.  Thermogravimetric and differential thermal analysis of cellulose, hemicellulose, and lignin , 1970 .

[19]  R. C. Mcilhenny,et al.  Bending strength of radiation-produced Southern Pine wood-plastic combinations. , 1970 .