Synthesis and filtration properties of polyimide nanofiber membrane/carbon woven fabric sandwiched hot gas filters for removal of PM 2.5 particles

Abstract In this work, hot gas filters composed of polyimide nanofiber membrane sandwiched between carbon woven fabrics are fabricated to capture fine particles of PM 2.5 level. Polyimide (PI) nanofibers with an average diameter of 190 nm are electrospun on supporting carbon fabrics as filtration layers. The filtration performance tests show that the maximum filtration efficiency reaches 99.99% for PM 2.5, while the maximum pressure drop is only 251.86 Pa after continuously testing for 25 min under a constant flow rate of 20 L/min. As the areal density of the PI nanofiber membrane increases, the filtration efficiency increases first and then levels off when the areal density reaches 11.64 g/m2. In regeneration performance test with back air flush at a pressure of 500 KPa, the composite filter maintains a filtration efficiency of 99.99% and a pressure drop of about 410 Pa. After heat treatment at 260 and 300 °C, the composite filter shows a relatively high filtration efficiency while the tensile strength of the carbon fabric does not change significantly.

[1]  Christopher J. Hogan,et al.  Nanoparticle filtration by electrospun polymer fibers , 2007 .

[2]  Seeram Ramakrishna,et al.  Nanofibrous filtering media: Filtration problems and solutions from tiny materials , 2007 .

[3]  Jing Wang,et al.  Figure of Merit of Composite Filters with Micrometer and Nanometer Fibers , 2008 .

[4]  H. Tafreshi,et al.  Modeling performance of thin fibrous coatings with orthogonally layered nanofibers for improved aerosol filtration , 2013 .

[5]  Steffen Heidenreich,et al.  Hot gas filtration – A review , 2013 .

[6]  Gang Xiao,et al.  Granular bed filter: A promising technology for hot gas clean-up , 2013 .

[7]  L. Weinhardt,et al.  Synthesis and characterization of conductive polyimide/carbon composites with Pt surface deposits , 2011 .

[8]  Ronald E Shaffer,et al.  Evaluation of the filtration performance of 21 N95 filtering face piece respirators after prolonged storage , 2009, American Journal of Infection Control.

[9]  Bin Xu,et al.  Semi-analytical and computational investigation of different dust loading structures affecting the performance of a fibrous air filter , 2014 .

[10]  Jianlong Li,et al.  Effect of uniformity of the residual dust cake caused by patchy cleaning on the filtration process , 2015 .

[11]  Jooyoun Kim,et al.  Design of ultra-fine nonwovens via electrospinning of Nylon 6: Spinning parameters and filtration efficiency , 2009 .

[12]  W. Koros,et al.  Thermal analysis and its application in evaluation of fluorinated polyimide membranes for gas separation , 2011 .

[13]  Alexander V. Mamishev,et al.  Novel electrodes of an electrostatic precipitator for air filtration , 2015 .

[14]  Si Cheng,et al.  Preparation of nonwoven polyimide/silica hybrid nanofiberous fabrics by combining electrospinning and controlled in situ sol-gel techniques , 2009 .

[15]  Hemanthram Varadaraju,et al.  Antimicrobial nano-fibrous membranes developed from electrospun polyacrylonitrile nanofibers , 2011 .

[16]  José Manuel Domínguez,et al.  On the limits of gas separation in CO2/CH4, N2/CH4 and CO2/N2 binary mixtures using polyimide membranes , 2007 .

[17]  Wolfgang M. Sigmund,et al.  Improvement in nanofiber filtration by multiple thin layers of nanofiber mats , 2010 .

[18]  S. A. Hosseini,et al.  On the importance of fibers' cross-sectional shape for air filters operating in the slip flow regime , 2011 .

[19]  J. Seville,et al.  Patchy cleaning of rigid gas filters—II. Experiments and model validation , 1997 .

[20]  Xiaoqiu Chen,et al.  Chemical characteristics of PM2.5 during haze episodes in the urban of Fuzhou, China , 2013 .

[21]  V. Jacobs,et al.  Performance evaluation of electrospun nanofibrous membrane , 2010 .

[22]  Yu Liang,et al.  Temperature effect on the pressure drop across the cake of coal gasification ash formed on a ceramic filter , 2008 .

[23]  Il-Doo Kim,et al.  Synthesis of an Al2O3-coated polyimide nanofiber mat and its electrochemical characteristics as a separator for lithium ion batteries , 2014 .

[24]  K. Kit,et al.  Nanofibrous chitosan non-wovens for filtration applications , 2009 .

[25]  B. Ding,et al.  Superamphiphobic nanofibrous membranes for effective filtration of fine particles. , 2014, Journal of colloid and interface science.

[26]  A. Podǵorski,et al.  Deposition efficiency of fractal-like aggregates in fibrous filters calculated using Brownian dynamics method. , 2007, Journal of colloid and interface science.

[27]  W. Sambaer,et al.  3D air filtration modeling for nanofiber based filters in the ultrafine particle size range , 2011 .

[28]  C. Lind,et al.  Preparation and properties of polyimide nanocomposites with negative thermal expansion nanoparticle filler , 2012 .

[29]  T. Czech,et al.  Modern electrostatic devices and methods for exhaust gas cleaning: A brief review , 2007 .

[30]  V. Rüdinger,et al.  Particulate emissions from a LLW incinerator and off-gas cleaning with a new type of ceramic candle filter , 1989 .

[31]  E. Hardman High performance textiles for industrial filtration , 2014 .

[32]  Kikuo Okuyama,et al.  Morphology optimization of polymer nanofiber for applications in aerosol particle filtration , 2010 .

[33]  E Diapouli,et al.  Levels of ultrafine particles in different microenvironments--implications to children exposure. , 2007, The Science of the total environment.

[34]  Haoqing Hou,et al.  Electrospun polyimide nanofiber-based nonwoven separators for lithium-ion batteries , 2013 .

[35]  Na Wang,et al.  Tortuously structured polyvinyl chloride/polyurethane fibrous membranes for high-efficiency fine particulate filtration. , 2013, Journal of colloid and interface science.

[36]  Young-Chull Ahn,et al.  Development of high efficiency nanofilters made of nanofibers , 2006 .

[37]  R. Brown,et al.  Glass-fibre filters with bimodal fibre size distributions , 2001 .

[38]  Tianxi Liu,et al.  High performance polyimide composite films prepared by homogeneity reinforcement of electrospun nanofibers , 2011 .

[39]  Jianmao Yang,et al.  Hierarchically structured polysulfone/titania fibrous membranes with enhanced air filtration performance. , 2014, Journal of colloid and interface science.

[40]  S. S. Madaeni,et al.  Fabrication of PES nanofiltration membrane by simultaneous use of multi-walled carbon nanotube and surface graft polymerization method: Comparison of MWCNT and PAA modified MWCNT , 2013 .

[41]  K. Nitta,et al.  Mechanical degradation of filter polymer materials: Polyphenylene sulfide , 2006 .

[42]  S. H. Kim,et al.  Fabrication of nickel filter made by uniaxial pressing process for gas purification : Fabrication pressure effect , 2007 .

[43]  A. Güngör,et al.  Preparation and characterization of flame retardant and proton conducting boron phosphate/polyimide composites , 2013 .