Advanced Micro- and Nano-Gas Sensor Technology: A Review

Micro- and nano-sensors lie at the heart of critical innovation in fields ranging from medical to environmental sciences. In recent years, there has been a significant improvement in sensor design along with the advances in micro- and nano-fabrication technology and the use of newly designed materials, leading to the development of high-performance gas sensors. Advanced micro- and nano-fabrication technology enables miniaturization of these sensors into micro-sized gas sensor arrays while maintaining the sensing performance. These capabilities facilitate the development of miniaturized integrated gas sensor arrays that enhance both sensor sensitivity and selectivity towards various analytes. In the past, several micro- and nano-gas sensors have been proposed and investigated where each type of sensor exhibits various advantages and limitations in sensing resolution, operating power, response, and recovery time. This paper presents an overview of the recent progress made in a wide range of gas-sensing technology. The sensing functionalizing materials, the advanced micro-machining fabrication methods, as well as their constraints on the sensor design, are discussed. The sensors’ working mechanisms and their structures and configurations are reviewed. Finally, the future development outlook and the potential applications made feasible by each category of the sensors are discussed.

[1]  Junbin Fang,et al.  All-fiber-optic VOC gas sensor based on side-polished fiber wavelength selectively coupled with cholesteric liquid crystal film , 2018, Sensors and Actuators B: Chemical.

[2]  Bishnu P. Pal,et al.  Optical Fiber Sensors: A Versatile Technology Platform for Sensing , 2014 .

[3]  Elecirodes Piezoelectric,et al.  HIGH Q MICROWAVE ACOUSTIC RESONATORS AND FILTERS , 1993 .

[4]  Eduard Llobet,et al.  Boron- and nitrogen-doped multi-wall carbon nanotubes for gas detection , 2014 .

[5]  Dongyuan Zhao,et al.  Ordered porous metal oxide semiconductors for gas sensing , 2017 .

[6]  Zhongze Gu,et al.  Photonic crystal for gas sensing , 2013 .

[7]  Ayushi Paliwal,et al.  Carbon monoxide (CO) optical gas sensor based on ZnO thin films , 2017 .

[8]  Dong Xiang,et al.  Metal Oxide Gas Sensors: Sensitivity and Influencing Factors , 2010, Sensors.

[9]  S. Ecks Gas , 2017 .

[10]  Jing Li,et al.  Detection of mixed volatile organic compounds and lung cancer breaths using chemiresistor arrays with crosslinked nanoparticle thin films , 2016 .

[11]  J. H. Lee,et al.  Highly sensitive and selective gas sensors using p-type oxide semiconductors: Overview , 2014 .

[12]  Douglas A. Buchanan,et al.  Design and Fabrication of a Novel MEMS Capacitive Transducer With Multiple Moving Membrane, ${\rm M}^{3}$-CMUT , 2014, IEEE Transactions on Electron Devices.

[13]  Russell Binions,et al.  Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring , 2010, Sensors.

[14]  Shin-Won Kang,et al.  A High Sensitivity and Wide Dynamic Range Fiber-Optic Sensor for Low-Concentration VOC Gas Detection , 2014, Sensors.

[15]  Stefan L. Schweizer,et al.  Photonic crystal gas sensors , 2004, SPIE Optics + Photonics.

[16]  Saurabh Chopra,et al.  Selective gas detection using a carbon nanotube sensor , 2003 .

[17]  B. Xing,et al.  Adsorption mechanisms of organic chemicals on carbon nanotubes. , 2008, Environmental science & technology.

[18]  Ghenadii Korotcenkov,et al.  Handbook of Gas Sensor Materials: Properties, Advantages and Shortcomings for Applications Volume 2: New Trends and Technologies , 2013 .

[19]  B. Adhikari,et al.  Polymers in sensor applications , 2004 .

[20]  Ananya Dey,et al.  Semiconductor metal oxide gas sensors: A review , 2018 .

[21]  Michael J Sailor,et al.  Identification and quantification of organic vapors by time-resolved diffusion in stacked mesoporous photonic crystals. , 2011, Nano letters.

[22]  Luca Ottaviano,et al.  2D Materials for Gas Sensing Applications: A Review on Graphene Oxide, MoS2, WS2 and Phosphorene , 2018, Sensors.

[23]  B. Reedy,et al.  Temperature modulation in semiconductor gas sensing , 1999 .

[24]  Daqiang Zhang,et al.  A Survey on Gas Sensing Technology , 2012, Sensors.

[25]  Kwan Kyu Park,et al.  Functionalization layers for CO2 sensing using capacitive micromachined ultrasonic transducers , 2012 .

[26]  G. Sauerbrey Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung , 1959 .

[27]  D. J. Thomson,et al.  Polymer-Based Chemicapacitor Sensor for 1-Octanol and Relative Humidity Detections at Different Temperatures and Frequencies , 2013, IEEE Sensors Journal.

[28]  Jacek Gębicki,et al.  Currently Commercially Available Chemical Sensors Employed for Detection of Volatile Organic Compounds in Outdoor and Indoor Air , 2017 .

[29]  Stephen J. Martin,et al.  Dynamics and Response of Polymer-Coated Surface Acoustic Wave Devices: Effect of Viscoelastic Properties and Film Resonance , 1994 .

[30]  O. Oralkan,et al.  Capacitive micromachined ultrasonic transducers: fabrication technology , 2005, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[31]  David S. Ballantine,et al.  Acoustic wave sensors : theory, design, and physico-chemical applications , 1997 .

[32]  Tadeusz Pustelny,et al.  The Application of Surface Acoustic Waves in Surface Semiconductor Investigations and Gas Sensors , 2013 .

[33]  Robert Rohling,et al.  Fabrication and testing of polymer-based capacitive micromachined ultrasound transducers for medical imaging , 2018, Microsystems & Nanoengineering.

[34]  Yongfeng Gao,et al.  Polymer-Based Technologies for Sensing Applications. , 2018, Analytical chemistry.

[35]  Simon X. Yang,et al.  A Real-Time De-Noising Algorithm for E-Noses in a Wireless Sensor Network , 2009, Sensors.

[36]  Butrus T. Khuri-Yakub,et al.  Capacitive Micromachined Ultrasonic Transducers: Theory and Technology , 2003 .

[37]  Yong Zhao,et al.  Research advances of photonic crystal gas and liquid sensors , 2011 .

[38]  Naader Alizadeh,et al.  Ultrasensitive and selective QCM sensor for detection of trace amounts of nitroexplosive vapors in ambient air based on polypyrrole—Bromophenol blue nanostructure , 2019, Sensors and Actuators B: Chemical.

[39]  R. Vijaya,et al.  Photonic crystal sensors: An overview , 2010 .

[40]  Omar K Farha,et al.  Fabrication of Metal‐Organic Framework‐Containing Silica‐Colloidal Crystals for Vapor Sensing , 2011, Advanced materials.

[41]  Yong Zhao,et al.  A review for optical sensors based on photonic crystal cavities , 2015 .

[42]  Hongtao Lin,et al.  Double resonance 1-D glass-on-silicon photonic crystal cavities for single-molecule mid-infrared photothermal spectroscopy: Theory and design , 2012, The 9th International Conference on Group IV Photonics (GFP).

[43]  Zachariah C. Alex,et al.  ZnO nanoparticles based fiber optic gas sensor , 2016 .

[44]  Giovanni Fanchini,et al.  Self-assembled metallic nanoparticle superlattices on large-area graphene thin films: growth and evanescent waveguiding properties , 2015 .

[45]  Naader Alizadeh,et al.  Chemiresistor gas sensor based on sulfonated dye-doped modified conducting polypyrrole film for high sensitive detection of 2,4,6-trinitrotoluene in air , 2018 .

[46]  G. Sergeev,et al.  Preparation and chemiresistive properties of nanostructured materials. , 2005, Advances in colloid and interface science.

[47]  Syariena Arshad,et al.  QUARTZ CRYSTAL MICROBALANCE GAS SENSOR FOR DETECTION OF VOLATILE ORGANIC COMPOUNDS USING TITANIUM DIOXIDE COATED WITH DYE-PORPHYRIN , 2008 .

[48]  G. Sauerbrey,et al.  Use of quartz vibration for weighing thin films on a microbalance , 1959 .

[49]  Masayoshi Esashi,et al.  High-frequency one-chip multichannel quartz crystal microbalance fabricated by deep RIE , 2003 .

[50]  A. Schutze,et al.  Detecting trace-level concentrations of volatile organic compounds with metal oxide gas sensors , 2013, 2013 IEEE SENSORS.

[51]  Nathan S. Lewis,et al.  Array-based vapor sensing using chemically sensitive carbon black-polymer resistors , 1997, Defense, Security, and Sensing.

[52]  Kwan Kyu Park,et al.  CMUT as a chemical sensor for DMMP detection , 2008, 2008 IEEE International Frequency Control Symposium.

[53]  Bingchu Cai,et al.  Ionization gas sensing in a microelectrode system with carbon nanotubes , 2006 .

[54]  Farabi Temel,et al.  Calix[4]arene coated QCM sensors for detection of VOC emissions: Methylene chloride sensing studies. , 2016, Talanta.

[55]  Benjamin Chu,et al.  Nanofabrication in polymer matrices , 2003 .

[56]  René Kizek,et al.  Methods for carbon nanotubes synthesis—review , 2011 .

[57]  A. MacDiarmid,et al.  "Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture). , 2001, Angewandte Chemie.

[58]  OXDE SEMCONDUCTOR Study on a Detector for Gaseous Components Using Semiconductive Thin Films , 2017 .

[59]  O. Oralkan,et al.  Highly sensitive detection of DMMP using a CMUT-based chemical sensor , 2010, 2010 IEEE Sensors.

[60]  Tamer F. Refaat,et al.  Backscatter 2-$\mu\hbox{m}$ Lidar Validation for Atmospheric $\hbox{CO}_{2}$ Differential Absorption Lidar Applications , 2011, IEEE Transactions on Geoscience and Remote Sensing.

[61]  Vittorio M. N. Passaro,et al.  Photonic Crystals for Optical Sensing: A Review , 2013 .

[62]  Franz L. Dickert,et al.  Surface Acoustic Wave (SAW) for Chemical Sensing Applications of Recognition Layers † , 2017, Sensors.

[63]  Byoung-Ho Kang,et al.  Fiber-optic multi-sensor array for detection of low concentration volatile organic compounds. , 2013, Optics express.

[64]  Neil M. White,et al.  Fabrication of high temperature surface acoustic wave devices for sensor applications , 2005 .

[65]  Hua Bai,et al.  Gas Sensors Based on Conducting Polymers , 2007, Sensors (Basel, Switzerland).

[66]  B. Khuri-Yakub,et al.  Fabrication of Capacitive Micromachined Ultrasonic Transducers via Local Oxidation and Direct Wafer Bonding , 2011, Journal of Microelectromechanical Systems.

[67]  I. Zaporotskova,et al.  Carbon nanotubes: Sensor properties. A review , 2016 .

[68]  Dongyuan Zhao,et al.  An overview of the synthesis of ordered mesoporous materials. , 2013, Chemical communications.

[69]  Robert C. Haddon,et al.  Chemically Functionalized Single-Walled Carbon Nanotubes as Ammonia Sensors† , 2004 .

[70]  Kwan Kyu Park,et al.  Chemical vapor detection using a capacitive micromachined ultrasonic transducer. , 2011, Analytical chemistry.

[71]  Noorhana Yahya,et al.  Synthesis of Carbon Nanostructures by CVD Method , 2010 .

[72]  Noel D.G. White,et al.  Polymer-based gas sensor on a thermally stable micro-cantilever , 2010 .

[73]  Yun-Tai Hsueh,et al.  A microfabricated, electrochemiluminescence cell for the detection of amplified DNA , 1996 .