A new family of multinuclear mixed-ligand copper(II) clusters: Crystal structures, magnetic properties and catecholase-like activity

[1]  M. Vaz,et al.  A single-chain magnet with a very high blocking temperature and a strong coercive field. , 2015, Inorganic chemistry.

[2]  T. D. Stack,et al.  Low temperature syntheses and reactivity of Cu2O2 active-site models. , 2015, Accounts of chemical research.

[3]  M. Costas,et al.  Structural and reactivity models for copper oxygenases: cooperative effects and novel reactivities. , 2015, Accounts of chemical research.

[4]  M. Lutz,et al.  Catalytic catechol oxidation by copper complexes: development of a structure-activity relationship. , 2015, Dalton transactions.

[5]  A. Kirillov,et al.  New tricopper(II) cores self-assembled from aminoalcohol biobuffers and homophthalic acid: synthesis, structural and topological features, magnetic properties and mild catalytic oxidation of cyclic and linear C5–C8 alkanes , 2015 .

[6]  Y. Wang,et al.  Efficient Oxygen Electroreduction: Hierarchical Porous Fe–N-doped Hollow Carbon Nanoshells , 2015 .

[7]  Quan‐Ming Wang,et al.  Role of Anions Associated with the Formation and Properties of Silver Clusters. , 2015, Accounts of chemical research.

[8]  A. Kirillov,et al.  New Tetracopper(II) Cubane Cores Driven by a Diamino Alcohol: Self-assembly Synthesis, Structural and Topological Features, and Magnetic and Catalytic Oxidation Properties. , 2015, Inorganic chemistry.

[9]  A. Pestov,et al.  Copper and nickel chelate complexes with polydentate N,O-ligands: structure and magnetic properties of polynuclear complexes , 2015 .

[10]  E. N. Lebedenko,et al.  Man-made antibodies and immunoconjugates with desired properties: function optimization using structural engineering , 2015 .

[11]  E. Collet,et al.  Ultrafast photoswitching in a copper-nitroxide-based molecular magnet. , 2014, Angewandte Chemie.

[12]  G. Ferreira,et al.  Synthesis, crystal structures and magnetic behaviour of four coordination compounds constructed with a phosphinic amide-TEMPO radical and [M(hfac)2] (M = Cu(II), Co(II) and Mn(II)). , 2014, Dalton transactions.

[13]  Anna M. Wise,et al.  Mass-selected nanoparticles of PtxY as model catalysts for oxygen electroreduction. , 2014, Nature chemistry.

[14]  A. Gewirth,et al.  Multicopper models for the laccase active site: effect of nuclearity on electrocatalytic oxygen reduction. , 2014, Inorganic chemistry.

[15]  B. Żurowska Structural and Magnetic Characterization of Cu-Picolinate and Cu-Quinaldinate and Their Mixed Complexes with Water or Halides , 2014 .

[16]  V. Ferreira,et al.  New families of hetero-tri-spin 2p-3d-4f complexes: synthesis, crystal structures, and magnetic properties. , 2014, Inorganic chemistry.

[17]  C. Limberg,et al.  Molecular Cu(II)-O-Cu(II) complexes: still waters run deep. , 2014, Angewandte Chemie.

[18]  Li Tian,et al.  Copper active sites in biology. , 2014, Chemical reviews.

[19]  P. Rajakannu,et al.  Polymeric and cyclic manganese phosphates and phosphinates: Synthesis, spectral characterization and solid-state structures , 2014 .

[20]  A. Bond,et al.  Solid-state electrochemistry of a semiconducting MMX-type diplatinum iodide chain complex. , 2014, Inorganic chemistry.

[21]  Shuranjan Sarkar,et al.  Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity , 2013 .

[22]  P. Mukherjee,et al.  Versatility of azide in serendipitous assembly of copper(II) magnetic polyclusters. , 2013, Accounts of chemical research.

[23]  Philip J. Ferko and Stephen M. Holmes,et al.  Pyrazolylborate Cyanometalate Single-Molecule Magnets , 2013 .

[24]  U. Ryde,et al.  Theoretical studies of the active-site structure, spectroscopic and thermodynamic properties, and reaction mechanism of multicopper oxidases , 2013 .

[25]  A. Kirillov,et al.  Homogeneous Multicopper Catalysts for Oxidation and Hydrocarboxylation of Alkanes , 2013 .

[26]  A. Kirillov,et al.  Multicopper complexes and coordination polymers for mild oxidative functionalization of alkanes , 2012 .

[27]  Sunney I. Chan,et al.  Efficient Room-Temperature Oxidation of Hydrocarbons Mediated by Tricopper Cluster Complexes with Di , 2012 .

[28]  O. Lavastre,et al.  Rate enhancement of the catechol oxidase activity of a series of biomimetic monocopper(II) complexes by introduction of non-coordinating groups in N-tripodal ligands , 2012 .

[29]  H. Görls,et al.  Oxidation products of calcium and strontium bis(diphenylphosphanide). , 2012, Inorganic chemistry.

[30]  Guohai Xu,et al.  Solvent-Dependent Assemblies of Trinuclear Copper Cluster into Variable Frameworks Based on Mixed Ligands of Polyalcohol Amines and Organic Carboxylates , 2012 .

[31]  A. Powell,et al.  High-nuclearity cobalt coordination clusters: Synthetic, topological and magnetic aspects , 2012 .

[32]  Wei Huang,et al.  Dicyanometalate chemistry: A type of versatile building block for the construction of cyanide-bridged molecular architectures , 2012 .

[33]  S. García‐Granda,et al.  Antisymmetric exchange in triangular tricopper(II) complexes: correlation among structural, magnetic, and electron paramagnetic resonance parameters. , 2012, Inorganic chemistry.

[34]  C. Sangregorio,et al.  Determination of the relevant magnetic interactions in low-dimensional molecular materials: the fundamental role of single crystal high frequency EPR. , 2011, Dalton transactions.

[35]  T. Kanayama,et al.  New semiconducting silicides assembled from transition-metal-encapsulating Si clusters , 2011 .

[36]  Sohini Sarkar,et al.  Heterobridged dinuclear, tetranuclear, dinuclear-based 1-d, and heptanuclear-based 1-D complexes of copper(II) derived from a dinucleating ligand: syntheses, structures, magnetochemistry, spectroscopy, and catecholase activity. , 2011, Inorganic chemistry.

[37]  M. Sathiyendiran,et al.  Copper phosphates and phosphinates with pyridine/pyrazole alcohol co-ligands: Synthesis and structure , 2011 .

[38]  M. Nakano,et al.  Magnetic anisotropies in paramagnetic polynuclear metal complexes. , 2011, Chemical Society reviews.

[39]  Di Sun,et al.  Simultaneous self-assembly of a cage-like silver(I) complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation. , 2011, Chemical communications.

[40]  Tebello Nyokong,et al.  Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions , 2010 .

[41]  D. Scherson,et al.  A hybrid lithium oxalate-phosphinate salt. , 2010, Inorganic chemistry.

[42]  M. W. George,et al.  The electrodeposition of copper from supercritical CO(2)/acetonitrile mixtures and from supercritical trifluoromethane. , 2010, Physical chemistry chemical physics : PCCP.

[43]  R. Bilewicz,et al.  Tetraimine macrocyclic transition metal complexes as building blocks for molecular devices , 2010 .

[44]  N. Aliaga-Alcalde,et al.  Synthesis, crystal structure, spectral and magnetic studies and catecholase activity of copper(II) complexes with di- and tri-podal ligands , 2010 .

[45]  S. Swavey,et al.  Dinuclear and polynuclear lanthanide coordination complexes containing polyazine ligands: Synthesis and luminescent properties , 2009 .

[46]  John R. D. Copley,et al.  DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data , 2009, Journal of research of the National Institute of Standards and Technology.

[47]  C. Stoumpos,et al.  Adventures in the Coordination Chemistry of Di-2-pyridyl Ketone and Related Ligands: From High-Spin Molecules and Single-Molecule Magnets to Coordination Polymers, and from Structural Aesthetics to an Exciting New Reactivity Chemistry of Coordinated Ligands†‡ , 2009 .

[48]  M. Giorgi,et al.  Molecular structure and catechol oxidase activity of a new copper(I) complex with sterically crowded monodentate N-donor ligand. , 2009, Journal of inorganic biochemistry.

[49]  E. C. Sañudo,et al.  Synthesis, structure, and magnetism of hexanuclear copper(II) phosphonates. , 2008, Inorganic chemistry.

[50]  S. Bhattacharya,et al.  Catechol oxidase activity of a series of new dinuclear copper(II) complexes with 3,5-DTBC and TCC as substrates: syntheses, X-ray crystal structures, spectroscopic characterization of the adducts and kinetic studies. , 2008, Inorganic chemistry.

[51]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[52]  K. Hodgson,et al.  The two oxidized forms of the trinuclear Cu cluster in the multicopper oxidases and mechanism for the decay of the native intermediate , 2007, Proceedings of the National Academy of Sciences.

[53]  R. Clérac,et al.  Synthesis, magnetic behaviour, and X-ray structures of dinuclear copper complexes with multiple bridges. Efficient and selective catalysts for polymerization of 2,6-dimethylphenol. , 2007, Dalton transactions.

[54]  E. Solomon,et al.  Electronic structures of exchange coupled trigonal trimeric Cu(II) complexes: Spin frustration, antisymmetric exchange, pseudo-A terms, and their relation to O2 activation in the multicopper oxidases , 2007 .

[55]  A. Rompel,et al.  Altering the Activity of Catechol Oxidase Model Compounds by Electronic Influence on the Copper Core , 2006 .

[56]  N. Dalal,et al.  Magnetism, electron paramagnetic resonance, electrochemistry, and mass spectrometry of the pentacopper(II)-substituted tungstosilicate [Cu5(OH)4(H2O)2(A-alpha-SiW9O33)2]10-, a model five-spin frustrated cluster. , 2005, Inorganic chemistry.

[57]  E. Solomon,et al.  Ground-state electronic and magnetic properties of a mu3-oxo-bridged trinuclear Cu(II) complex: correlation to the native intermediate of the multicopper oxidases. , 2005, Inorganic chemistry.

[58]  M. C. Feiters,et al.  Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals. , 2005, Dalton transactions.

[59]  T. Tokii,et al.  Novel Dinuclear Copper(II) Complexes with syn-syn and syn-anti Coordination Modes of Bis(μ-phosphinato)-bridges : Structures and Magnetic Properties , 2004 .

[60]  T. Rojo,et al.  Pentacoordinate nickel(II) complexes double bridged by phosphate ester or phosphinate ligands: spectroscopic, structural, kinetic, and magnetic studies. , 2004, Chemistry.

[61]  B. Bosnich,et al.  Principles of mononucleating and binucleating ligand design. , 2004, Chemical reviews.

[62]  F. Villamena,et al.  Cyclic voltammetry of metal complexes of nitrones and nitroxides , 2003 .

[63]  K. Hodgson,et al.  Nature of the intermediate formed in the reduction of O(2) to H(2)O at the trinuclear copper cluster active site in native laccase. , 2002, Journal of the American Chemical Society.

[64]  A. Caneschi,et al.  Cobalt(II)-Nitronyl Nitroxide Chains as Molecular Magnetic Nanowires The financial support of Italian MURST and CNR and of Brazilian CNPq and FUJB is acknowledged. The support from the European Community through the TMR program 3MD (contract no ERB4061PL97-0197) is also acknowledged. , 2001, Angewandte Chemie.

[65]  M. Sathiyendiran,et al.  Di-tert-butyl phosphate complexes of cobalt(II) and zinc(II) as precursors for ceramic M(PO3)2 and M2P2O7 materials: synthesis, spectral characterization, structural studies, and role of auxiliary ligands. , 2001, Inorganic chemistry.

[66]  M. Sathiyendiran,et al.  Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials , 2001 .

[67]  L. Rossi,et al.  Synthesis, Structure, Physicochemical Properties and Catecholase-like Activity of a New Dicopper(II) Complex , 2001 .

[68]  David K. Henderson,et al.  Inter-ligand reactions: in situ formation of new polydentate ligands , 2000 .

[69]  M. Mehring,et al.  Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides , 1999 .

[70]  Robert C. Thompson,et al.  Crystal Structure and Magnetic Behavior of Copper(II) Dimethylphosphinate: A Chain Polymer Containing Triangular Trimetallic Bis(&mgr;-dimethylphosphinato)copper(II) Units. , 1997, Inorganic Chemistry.

[71]  E. Solomon,et al.  Multicopper Oxidases and Oxygenases. , 1996, Chemical reviews.

[72]  George M. Sheldrick,et al.  SADABS, Program for Empirical Absorption Correction of Area Detector Data , 1996 .

[73]  Robert C. Thompson,et al.  Synthesis, structure, and magnetic properties of diphenylphosphinates of cobalt(II) and manganese(II). The crystal and molecular structures of the γ forms of poly-bis(μ-diphenylphosphinato)cobalt(II) and manganese(II) , 1991 .

[74]  A. Bino,et al.  A new class of metalphosphinates containing bridging formamide ligands , 1988 .

[75]  P. Betz Crystal structure of poly-bis(-phenylmethylphosphinato)copper(II)(dimethylformamide) , 1988 .

[76]  A. Bino,et al.  Preparation and structure of poly-bis(μ-diphenyl-phosphinato)copper(II) , 1987 .

[77]  O. Kahn,et al.  Copper(II) and nickel(II) trinuclear species with dithiooxamide derivative ligands: structural, magnetic, spectroscopic, and electrochemical properties , 1986 .

[78]  Robert C. Thompson,et al.  Structure and magnetic exchange in poly-bis((μ-dialkylphosphinato)copper(II) compounds , 1984 .

[79]  A. W. Addison,et al.  Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate , 1984 .

[80]  T. Głowiak,et al.  Bis[μ-ammoniomethyl(methyl)phosphinato-O,O']-diaquatetrachlorodicopper(II), Cu2(C2H8NO2P)2Cl4(H2O)2 , 1983 .

[81]  Robert C. Thompson,et al.  Synthesis, structure, and properties of poly-bis(μ-diethylphosphinato)copper(II) , 1982 .

[82]  M. Melnik Study of the relation between the structural data and magnetic interaction in oxo-bridged binuclear copper(II) compounds , 1982 .

[83]  P. R. Newman,et al.  Crystal structure and magnetic studies of bis(.mu.-dibutylphosphinato)-copper(II) , 1977 .

[84]  B. Tsukerblat,et al.  Antisymmetric exchange in the trinuclear clusters of copper (II) , 1975 .

[85]  K. M. Mackay Introduction to modern inorganic chemistry , 1968 .

[86]  T. Moriya Anisotropic Superexchange Interaction and Weak Ferromagnetism , 1960 .

[87]  I. Dzyaloshinsky A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics , 1958 .