论文信息 - Carbon-13 Variable Temperature NMR Studies of Some Dimethyl-1-oxa-3,4-diazacyclohexanes1

Carbon-13 Variable Temperature NMR Studies of Some Dimethyl-1-oxa-3,4-diazacyclohexanes1

Conformational equilibria are elucidated and rationalised for 3,4-dimethyl-1-oxa-3,4-diazacyclohexane, and a trans-bicyclic analogue. The major conformer has 3ax-NMe, 4eq-NMe: two minor conformations are also significantly populated. Kinetic and thermodynamic parameters are correlated with those for analogous heterocycles.

E. S. Turner | A. Katritzky | Ranjan C. Patel | F. Riddell | F. Brito-Palma

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