Fundamentals of Lead–Acid Batteries

Based on thermodynamic calculations a potential/pH diagram for the Pb/H 2 SO 4 /H 2 O system is plotted. It defines the pH ranges of formation of the different phases and electrode systems, but the system Pb/H 2 SO 4 /H 2 O is kinetically controlled as well.

[1]  E. G. Siwek,et al.  Corrosion of Lead Alloys at High Anodic Potentials , 1976 .

[2]  M. Svatá,et al.  Study of structural factors of lead-acid battery electrodes , 1979 .

[3]  V. H. Dodson.  Some Important Factors That Influence the Composition of the Positive Plate Material in the Lead‐Acid Battery , 1961 .

[4]  J. Gavarri,et al.  Mise en evidence et localisation des protons dans les bioxydes de plomb PbO2α et β chimiques et électrochimiques , 1984 .

[5]  M. A. Dasoyan,et al.  Current theory of lead acid batteries , 1979 .

[6]  D. Pavlov,et al.  The effect of the expander upon the two types of negative active mass structure in lead-acid batteries , 1985 .

[7]  D. Pavlov,et al.  Einfluß von Silber und Thallium auf die anodische Korrosion der Bleilegierungen in Schwefelsäure , 1968 .

[8]  D. Pavlov,et al.  Structural Properties of the PbO2 Active Mass Determining Its Capacity and the “Breathing” of the Positive Plate during Cycling , 1986 .

[9]  A. Maldotti,et al.  Influence of the electrode history and effects of the electrolyte composition and temperature on O2 evolution at β-PbO2 anodes in acid media , 2002 .

[10]  D. Pavlov.  Processes of formation of divalent lead oxide compounds on anodic oxidation of lead in sulphuric acid , 1968 .

[11]  D. Pavlov,et al.  Mechanism of the action of Ag and As on the anodic corrosion of lead and oxygen evolution at the Pb/PbO(2−x)/H2O/O2/H2SO4 electrode system , 1986 .

[12]  R. O'brien.  An Interferometric Study of Low Temperature Charging of the Lead‐Acid Cell , 1977 .

[13]  Jian-qing Zhang,et al.  The influence of F- doping on the activity of PbO2 film electrodes in oxygen evolution reaction , 2007 .

[14]  D. Pavlov,et al.  Hydration and Amorphization of Active Mass PbO2 Particles and Their Influence on the Electrical Properties of the Lead‐Acid Battery Positive Plate , 1989 .

[15]  P. Ruetschi,et al.  Ion Selectivity and Diffusion Potentials in Corrosion Layers Films on Pb in , 1973 .

[16]  D. Kordes.  Charakterisierung von Plusmassen aus Blei-Batterien durch Röntgenstrahlbeugung , 1966 .

[17]  A. P. Roth,et al.  Some photoelectrochemical observations on lead under anodic oxidation in sulphuric acid , 1981 .

[18]  P. Rüetschi,et al.  Surface Coverage during Hydrogen and Oxygen Evolution , 1960 .

[19]  D. Pavlov,et al.  Orthorhombic PbO Formation during the Discharge of Lead Acid Batteries PbO2 Active Mass , 1987 .

[20]  D. Pavlov.  Semiconductor mechanism of the processes during electrochemical oxidation of PbO to PbO2 , 1981 .

[21]  N. A. Hampson,et al.  The differential capacitance of polycrystalline lead in some aqueous electrolytes , 1971 .

[22]  D. Pavlov,et al.  Mechanism of the Elementary Electrochemical Processes Taking Place during Oxygen Evolution on the Lead Dioxide Electrode , 1996 .

[23]  D. Pavlov,et al.  The Lead‐Acid Battery Lead Dioxide Active Mass: A Gel‐Crystal System with Proton and Electron Conductivity , 1992 .

[24]  A. C. Simon,et al.  Thermal Decomposition Mechanism of Formed and Cycled Lead Dioxide Electrodes and Its Relationship to Capacity Loss and Battery Failure , 1974 .

[25]  D. Pavlov,et al.  Growth Processes of the Anodic Crystalline Layer on Potentiostatic Oxidation of Lead in Sulfuric Acid , 1970 .

[26]  D. Pavlov,et al.  Hydrated structures in the anodic layer formed on lead electrodes in H2SO4 solution , 1993 .

[27]  E. Weisberg,et al.  Anodic diffusion of oxygen through lead dioxide , 1964 .

[28]  S. Srinivasan,et al.  Elucidation of the mechanism of electrolytic hydrogen evolution by the use of H-T separation factors , 1964 .

[29]  D. Pavlov,et al.  Dependence of the Composition of the Anodic Layer on the Oxidation Potential of Lead in Sulfuric Acid , 1969 .

[30]  U. Thomas.  The Electrical Conductivity of Lead Dioxide , 1948 .

[31]  K. Bullock.  The electromotive force of the leadacid cell and its half-cell potentials , 1991 .

[32]  D. Pavlov,et al.  The PbO2 Particle: Exchange Reactions Between Ions of the Electrolyte and the PbO2 Particles of the Lead‐Acid Battery Positive Active Mass , 1992 .

[33]  D. Pavlov,et al.  Mechanism of passivation processes of the lead sulphate electrode , 1970 .

[34]  P. Rüetschi,et al.  Electrode Potentials and Thermal Decomposition of Alpha ‐ and Beta ‐ PbO2 , 1962 .

[35]  D. Pavlov,et al.  Dependence of the phase composition of the anodic layer on oxygen evolution and anodic corrosion of lead electrode in lead dioxide potential region , 1978 .

[36]  J. S. Anderson,et al.  The intermediate oxides of lead , 1959 .

[37]  J W Mellor,et al.  A comprehensive treatise on inorganic and theoretical chemistry vol.VIII N, Cl , 1922 .

[38]  N. J. Maskalick.  Accelerated Life Testing of Lead‐Acid Industrial Motive Power Cells , 1975 .

[39]  Jeanne Burbank,et al.  Atlas D-Equilibres Electrochimiques , 1964 .

[40]  W. Mindt,et al.  Electrical Properties of Electrodeposited PbO2 Films , 1969 .

[41]  P. Ruetschi,et al.  Anodic Oxidation of Lead at Constant Potential , 1964 .

[42]  R. L. Clarke,et al.  The preparation of lead dioxide for X‐ray diffraction studies , 1966 .

[43]  W. Wynne-Jones,et al.  The behaviour of the lead dioxide electrode. Part 1.—Thermodynamical analysis of the reaction in the lead accumulator , 1954 .

[44]  S. M. Caulder,et al.  The Hydrogen‐Loss Concept of Battery Failure: The PbO2 Electrode , 1973 .

[45]  An investigation of the structure of the active mass of the negative plate of lead—acid batteries , 1981 .

[46]  J. Gavarri,et al.  Modèle de décomposition thermique des bioxydes de plomb: Rôle des protons, relation avec la structure de l'oxyde pseudocubique PbO1.57☆ , 1984 .

[47]  K. Wiesener,et al.  Zum verlauf der entladereaktion positiver aktivmassen des bleiakkumulators , 1976 .

[48]  G. Butler,et al.  145. The thermal decomposition of lead dioxide in air , 1956 .

[49]  P. Rüetschi,et al.  Oxygen Overvoltage and Electrode Potentials of Alpha ‐ and Beta ‐ PbO2 , 1959 .

[50]  F. Lappé.  Some physical properties of sputtered PbO2 films , 1962 .

[51]  J. A. Harrison,et al.  The electrochemical dissolution of Pb to form PbSO4 by a solution-precipitation mechanism , 1972 .

[52]  G. W. Vinal,et al.  Thermodynamic properties of sulfuric-acid solutions and their relation to the electromotive force and heat of reaction of the lead storage battery , 1940 .

[53]  W. Wynne-Jones,et al.  The behaviour of the lead dioxide electrode. Part 3.—Overvoltage during oxygen evolution in H2SO4 , 1954 .

[54]  K. Bullock,et al.  Corrosion of Lead in Sulfuric Acid at High Potentials , 1986 .

[55]  Y. Kolotyrkin.  Effect of specific adsorption of anions on hydrogen overvoltage , 1959 .

[56]  Walter J. Hamer,et al.  The Thermodynamics of Aqueous Sulfuric Acid Solutions from Electromotive Force Measurements1 , 1935 .

[57]  D. Pavlov.  Processes in solid state at anodic oxidation of a lead electrode in H2SO4 solution and their dependence on the oxide structure and properties , 1978 .

[58]  B. Thompson,et al.  SELF-DIFFUSION OF OXYGEN IN LEAD OXIDE1 , 1963 .

[59]  E. Otto.  Equilibrium Pressures of Oxygen over Oxides of Lead at Various Temperatures , 1966 .

[60]  M. Kazacos.  A Rotating Ring‐Disk Electrode Study of Soluble Lead (IV) Species in Sulfuric Acid Solution , 1981 .

[61]  R. J. Hill,et al.  Structural Parameters of β ‐ PbO2 and Their Relationship to the Hydrogen‐Loss Concept of Lead‐Acid Battery Failure , 1984 .

[62]  Jürgen Garche,et al.  Encyclopedia of electrochemical power sources , 2009 .

[63]  A. Bard,et al.  Semiconductor Electrodes: X . Photoelectrochemical Behavior of Several Polycrystalline Metal Oxide Electrodes in Aqueous Solutions , 1977 .

[64]  D. Berndt.  Maintenance-Free Batteries , 1993 .

[65]  S. J. Vellenga,et al.  The Solubility of Red, Yellow, and Black Lead Oxides (2) and Hydrated Lead Oxide in Alkaline Solutions. The Character of the Lead-Bearing Ion , 1939 .

[66]  S. Fletcher,et al.  Photoelectrochemistry in the lead-sulphuric acid system , 1981 .