论文信息 - Electrospray ionization tandem mass spectrometric characteristics and fragmentation mechanisms of distamycin analogues.

Electrospray ionization tandem mass spectrometric characteristics and fragmentation mechanisms of distamycin analogues.

The electrospray ionization tandem mass spectrometric (ESI-MS/MS) characteristics and fragmentation mechanisms of eight distamycin analogues containing N-methylpyrrole and N-methylimidazole were investigated. The members of two isomeric groups of distamycin analogues with the same elemental composition can be distinguished by MS/MS spectra of protonated molecules and of significant fragment ions.

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