Recent Advances in Luminescent Annulated Borepins, Silepins, and Phosphepins

This review summarizes recent research on the molecular design, optical, and electronic properties of annulated borepins, silepins, and phosphepins, with emphasis on their structure–property relationships at the molecular level. 1 Introduction 2 Borepins 3 Silepins 4 Phosphepins 5 Summary and Outlook

[1]  K. Hirano,et al.  Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents. , 2020, Organic letters.

[2]  E. Regulska,et al.  Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles. , 2019, The Journal of organic chemistry.

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[4]  Milan Kivala,et al.  Isomeric Dithienophosphepines: The Impact of Ring Fusion on Electronic and Structural Properties , 2019, Chemistry.

[5]  L. Qiu,et al.  Iodocarbocyclization to Access Six- and Seven-Membered Phosphacycles from Phosphoryl-Linked Alkynes , 2019, European Journal of Organic Chemistry.

[6]  Robert J. Gilliard,et al.  Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic "Switch" Based on Boron-Oxygen Interactions. , 2019, Chemistry.

[7]  Suning Wang,et al.  Reversible Photoisomerization from Borepin to Boratanorcaradiene and Double Aryl Migration from Boron to Carbon. , 2019, Angewandte Chemie.

[8]  M. Hissler,et al.  π-Extended Phosphepines: Redox and Optically Active P-Heterocycles with Nonplanar Framework. , 2019, Organic letters.

[9]  M. Carda,et al.  Synthesis and biological evaluation of cyclic derivatives of combretastatin A-4 containing group 14 elements. , 2018, Organic & biomolecular chemistry.

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[11]  T. Shibata,et al.  Ir-Catalyzed Synthesis of Substituted Tribenzosilepins by Dehydrogenative C-H/Si-H Coupling. , 2018, The Journal of organic chemistry.

[12]  J. Ohshita,et al.  Synthesis and Properties of Benzo[d]dithieno[b,f]borepins , 2018 .

[13]  J. Tovar,et al.  Ring fusion isomers of dithienoborepins: perturbations of electronic structure, aromaticity, and reactivity in boron-containing polycyclic heteroaromatics , 2017 .

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[16]  J. Tovar,et al.  Thiophene-fused borepins as directly functionalizable boron-containing π-electron systems. , 2014, Journal of the American Chemical Society.

[17]  T. Sasamori,et al.  Borylated dibenzoborepin: synthesis by skeletal rearrangement and photochromism based on bora-Nazarov cyclization. , 2013, Angewandte Chemie.

[18]  K. Lammertsma,et al.  Dibenzo[b,f]phosphepines: Novel Phosphane–Olefin Ligands for Transition Metals , 2013 .

[19]  J. Tovar,et al.  Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings. , 2012, Chemical communications.

[20]  S. Yamaguchi,et al.  Polycyclic π-electron system with boron at its center. , 2012, Journal of the American Chemical Society.

[21]  J. Tovar,et al.  Synthesis of functionalizable boron-containing pi-electron materials that incorporate formally aromatic fused borepin rings. , 2010, Angewandte Chemie.

[22]  W. Piers,et al.  Benzo- and naphthoborepins: blue-emitting boron analogues of higher acenes. , 2009, Angewandte Chemie.

[23]  T. Kawashima,et al.  Crucial role of N...Si interactions in the solid-state coloration of disilylazobenzenes. , 2008, The Journal of organic chemistry.

[24]  T. Janosik,et al.  Synthesis of Fused 1-Sila-, 1-Germa-, and 1-Selenacyclohepta-2,4,6-trienes , 2008 .

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