Photovoltaic systems can strengthen the energy matrix aiming at energy sustainability, however, their intermittence, the availability time frame and seasonality effects are complicating aspects for the operation of these systems. To mitigate such problems, a possible measure is the operation of hybrid systems (HS) associated with storage systems to meet the energy demand. This study presents real operational scenarios for the management of a hybrid mini-grid installed in the Amazon region in Brazil, capable of managing energy supply and demand, changing the generation curve, reducing fossil fuel consumption and energy costs, in addition to providing flexibility and operational safety to the electrical operating under on-grid or off-grid conditions. Through technical and economic analyses, the objective of this study is to show that hybrid systems can be implemented in small and medium consumers, in addition to generating a new market option for utilities. This research evaluates the operation of HS concurrently with the electrical grid and the results show that the system meets the technical requirements, in addition to bringing financial and ecological benefits. This information can support the decisions of consumers, utilities and energy operators for the development of the national market for on-grid and off-grid HS.