Long-term stability of gasochromic effect in TiO2:(W, Cr, Mo) thin film

Gasochromic thin films are used in the fields of gas sensing, smart windows and display industries. In this paper wettability and long-term stability of gasochromic effect of TiO2:(W, Cr, Mo) thin films have been investigated. Samples were deposited using high energy reactive magnetron sputtering process on Corning 7059 glass substrates. Contact angle, critical surface tension and surface free energy were determined using Theta Lite tensiometer. Thin films revealed hydrophilic properties. Gasochromic effect was observed in ethanol vapor atmosphere in temperature of at least 200 °C. Bleaching of the thin films was obtained in an ambient atmosphere at 350 °C. Also, the coloration of the samples was entirely reversible.

[1]  N. Xu,et al.  Study of Physical and Chemical Processes of H2 Sensing of Pt-Coated WO3 Nanowire Films , 2010 .

[2]  Xingguo Li,et al.  Improved hydrogen storage properties in Mg-based thin films by tailoring structures , 2010 .

[3]  Chung-Chieh Chang,et al.  Preparation and characterization of gasochromic Pt/WO3 hydrogen sensor by using the Taguchi design method , 2010 .

[4]  Roghayeh Ghasempour,et al.  Pd doped WO3 films prepared by sol–gel process for hydrogen sensing , 2010 .

[5]  Jaroslaw Domaradzki,et al.  Gasochromic Effect in Nanocrystalline TiO_{2} Thin Films Doped with Ta and Pd , 2009 .

[6]  R. Ghosh,et al.  Optical properties and aging of gasochromic WO3 , 2010 .

[7]  S. Mahdavi,et al.  Electroless plating of palladium on WO3 films for gasochromic applications , 2010 .

[8]  Tzu-Wen Huang,et al.  Pulsed laser deposition of (MoO3)1 − x(V2O5)x thin films: Preparation, characterization and gasochromic studies , 2010 .

[9]  S. Yamamoto,et al.  Effects of composition and structure on gasochromic coloration of tungsten oxide films investigated with XRD and RBS , 2007 .

[10]  Jin Huang,et al.  Synthesis of monoclinic WO3 nanosphere hydrogen gasochromic film via a sol-gel approach using PS-b-PAA diblock copolymer as template , 2010 .

[11]  Daniel Y. Kwok,et al.  Contact angle measurement and contact angle interpretation , 1999 .

[12]  G. Neri,et al.  Gasochromic response of nanocrystalline vanadium pentoxide films deposited from ethanol dispersions , 2010 .

[13]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[14]  D. Kaczmarek,et al.  X-ray, optical and electrical characterization of doped nanocrystalline titanium oxide thin films , 2004 .