White‐Light‐Emitting Diodes with Quantum Dot Color Converters for Display Backlights

Quantum dots (QDs) have attracted great attention as good candidate for the next generation displays due to their narrow emission, and high luminescence efficiency, and tunable emission covering all visible range. However, QDs easily lost their initial optical properties during the process for a device fabrication and practical operation. We synthesized well passivated green and red light emitting QDs that show almost 100% of QE. When the highly luminescent green and red light emitting QDs were applied as color converters in InGaN blue LEDs, resulting cool white QD-LEDs showed 41lm/W and more than 100% of color reproducibility compared to NTSC standard in CIE1931 and maintained their optical properties for a long time operation. We also demonstrated a 46-inch LCD panel using the white QDLED backlight was successfully demonstrated (Figure).

[1]  S. Jun,et al.  Synthesis of multi-shell nanocrystals by a single step coating process , 2006 .

[2]  Hilmi Volkan Demir,et al.  Color-converting combinations of nanocrystal emitters for warm-white light generation with high color rendering index , 2008 .

[3]  Xiaogang Peng,et al.  Control of photoluminescence properties of CdSe nanocrystals in growth. , 2002, Journal of the American Chemical Society.

[4]  D. Jeon,et al.  White Light‐Emitting Diodes with Excellent Color Rendering Based on Organically Capped CdSe Quantum Dots and Sr3SiO5:Ce3+,Li+ Phosphors , 2008, Advanced materials.

[5]  Xiaogang Peng,et al.  Experimental Determination of the Extinction Coefficient of CdTe, CdSe, and CdS Nanocrystals , 2003 .

[6]  M. Haase,et al.  Strongly luminescent InP/ZnS core-shell nanoparticles. , 2001, ChemPhysChem.

[7]  J. Y. Han,et al.  High-performance crosslinked colloidal quantum-dot light-emitting diodes , 2009 .

[8]  M. Bawendi,et al.  (CdSe)ZnS Core-Shell Quantum Dots - Synthesis and Characterization of a Size Series of Highly Luminescent Nanocrystallites , 1997 .

[9]  Hilmi Volkan Demir,et al.  White light generation using CdSe/ZnS core–shell nanocrystals hybridized with InGaN/GaN light emitting diodes , 2007 .

[10]  Andreas Kornowski,et al.  CdSe/CdS/ZnS and CdSe/ZnSe/ZnS Core−Shell−Shell Nanocrystals , 2004 .

[11]  D. Sarma,et al.  White-light emission from a blend of CdSeS nanocrystals of different Se:S ratio , 2007, Nanotechnology.

[12]  R. Berns Billmeyer and Saltzman's Principles of Color Technology , 2000 .

[13]  Huang-Yao Hong,et al.  InGaN-CdSe-ZnSe quantum dots white LEDs , 2006 .

[14]  Xiaogang Peng,et al.  Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility , 1997 .

[15]  Miroslaw Batentschuk,et al.  Silica‐Coated InP/ZnS Nanocrystals as Converter Material in White LEDs , 2008 .

[16]  Qiang Wang,et al.  Synthesis of Extremely Small CdSe and Highly Luminescent CdSe/CdS Core–Shell Nanocrystals via a Novel Two‐Phase Thermal Approach , 2005 .

[17]  V. Bulović,et al.  Electroluminescence from single monolayers of nanocrystals in molecular organic devices , 2002, Nature.

[18]  E. Jang,et al.  Interfused semiconductor nanocrystals: brilliant blue photoluminescence and electroluminescence. , 2005, Chemical communications.

[19]  J. Ryu,et al.  Luminescent properties of β-SiAlON:Eu2+ green phosphors synthesized by gas pressured sintering , 2008 .

[20]  David Battaglia,et al.  Colloidal InP nanocrystals as efficient emitters covering blue to near-infrared. , 2007, Journal of the American Chemical Society.

[21]  V. Bulović,et al.  Quantum dot light-emitting devices with electroluminescence tunable over the entire visible spectrum. , 2009, Nano letters.

[22]  A. P. Alivisatos,et al.  Epitaxial growth and photochemical annealing of graded CdS/ZnS shells on colloidal CdSe nanorods. , 2002, Journal of the American Chemical Society.

[23]  Klavs F. Jensen,et al.  Full Color Emission from II–VI Semiconductor Quantum Dot–Polymer Composites , 2000 .

[24]  Jagjit Nanda,et al.  Effect of the thiol-thiolate equilibrium on the photophysical properties of aqueous CdSe/ZnS nanocrystal quantum dots. , 2005, Journal of the American Chemical Society.

[25]  V. Bulović,et al.  Color-saturated green-emitting QD-LEDs. , 2006, Angewandte Chemie.

[26]  William W. Yu,et al.  Environmental Effects on Photoluminescence of Highly Luminescent CdSe and CdSe/ZnS Core/Shell Nanocrystals in Polymer Thin Films , 2004 .

[27]  N. Kijima,et al.  First‐principles study of nitridoaluminosilicate CaAlSiN3 , 2006 .

[28]  S. Neeraj,et al.  Novel red phosphors for solid-state lighting: the system NaM(WO4)2−x(MoO4)x:Eu3+ (MGd, Y, Bi) , 2004 .

[29]  P. Guyot-Sionnest,et al.  Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals , 1996 .

[30]  V. Bulović,et al.  Blue luminescence from (CdS)ZnS core-shell nanocrystals. , 2004, Angewandte Chemie.

[31]  Jaehee Cho,et al.  Preparation of Highly Luminescent Nanocrystals and Their Application to Light‐Emitting Diodes , 2007 .