论文信息 - X-ray diffraction and Mössbauer spectroscopy studies of a mechanosynthesized Fe75B25 alloy

X-ray diffraction and Mössbauer spectroscopy studies of a mechanosynthesized Fe75B25 alloy

Abstract In this work, the process of formation of metastable phases was investigated for the Fe75B25 composition. Mechanical synthesis was performed in a MAPF-2M high-energy planetary ball mill under an argon atmosphere. X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Mössbauer spectroscopy (MS) were applied to recognize the phases. After 6 h of milling, the material consisted of two phases, that is, metastable tetragonal t-Fe2B and amorphous phases. During further thermal processing, the metastable phase was transformed into the stable Fe2B phase.

E. Jartych | L. M. Kubalova | Victoria I. Fadeeva

[1] A. Hernando,et al. GRAIN-BOUNDARY STRUCTURE AND MAGNETIC BEHAVIOR IN NANOCRYSTALLINE BALL-MILLED IRON , 1997 .

[2] F. H. Sanchez,et al. On the microstructure and thermal stability of rapidly quenched Fe–B alloys in the intermediate composition range between the crystalline and amorphous states , 1995 .

[3] G. Rixecker,et al. Study of nanocrystalline and amorphous powders prepared by mechanical alloying , 1994 .

[4] B. Fultz,et al. Phases and phase stabilities of Fe3X alloys (X=Al, As, Ge, In, Sb, Si, Sn, Zn) prepared by mechanical alloying , 1994 .

[5] Zhang,et al. Mössbauer study of the local atomic environments in metastable crystalline Fe-B alloys. , 1986, Physical review. B, Condensed matter.