Niobium in modern steels

Abstract It is well known that niobium is added to a wide range of steels for improving processing, microstructure, properties and performance. Over the past 20 years, the use of niobium has also permitted new steels with attractive properties to be developed. Furthermore, the addition of niobium to existing steels such as ferritic stainless steels has also led to improvement. The goal of this paper is to review the basic behaviour of niobium in a wide range of steels, including not only the traditional steels but also some of the newer versions. Particular emphasis has been placed on the basic metallurgical principles that apply to these steels, for it is the application of these principles that allows the composition- processing-microstructure-mechanical property relationships to be rationalised and exploited. The application of basic metallurgical principles has resulted in a predictive capability that has led to alterations in composition and processing for the purpose of producing steels with superior mechanical properties and improved overall performance.

[1]  E. Palmiere,et al.  Compositional and microstructural changes which attend reheating and grain coarsening in steels containing niobium , 1994 .

[2]  L. Brossard,et al.  Precipitation in microalloyed high-strength low-alloy steels , 1975 .

[3]  John B. Ballance,et al.  The Hot deformation of austenite , 1977 .

[4]  E. Palmiere,et al.  The influence of niobium supersaturation in austenite on the static recrystallization behavior of low carbon microalloyed steels , 1996 .

[5]  W. Smith,et al.  Structure and properties of engineering alloys , 1981 .

[6]  J. Kirkaldy,et al.  Solubility product for niobium carbide in austenite , 1984 .

[7]  M. Tokizane,et al.  Behavior of Niobium Carbides and Nitrides in Steel , 1964 .

[8]  J. Z. Zhao,et al.  Formation of the cottrell atmosphere during strain aging of bake-hardenable steels , 2001 .

[9]  I. Lifshitz,et al.  The kinetics of precipitation from supersaturated solid solutions , 1961 .

[10]  K. Narita Physical Chemistry of the Groups IVa (Ti, Zr), Va (V, Nb, Ta) and the Rare Earth Elements in Steel , 1975 .

[11]  R. Honeycombe,et al.  Effect of manganese on microstructure of an isothermally transformed Fe–Nb–C alloy , 1985 .

[12]  A. J. deArdo,et al.  Metallurgical basis for thermomechanical processing of microalloyed steels , 2001 .

[13]  T. Gladman The Physical Metallurgy of Microalloyed Steels , 1997 .

[14]  J. B. Sande,et al.  Niobium carbonitride precipitation and austenite recrystallization in hot-rolled microalloyed steels , 1980 .

[15]  John J. Jonas,et al.  Effect of molybdenum, niobium, and vanadium on static recovery and recrystallization and on solute strengthening in microalloyed steels , 1983 .

[16]  C. Garcia,et al.  Precipitation behavior in ultra-low-carbon steels containing titanium and niobium , 1997 .

[17]  T. N. Baker Yield, flow and fracture of polycrystals , 1983 .

[18]  M. Tokizane,et al.  Thermodynamic Properties of Niobium Carbides and Nitrides in Steels , 1968 .

[19]  J. Kirkaldy,et al.  Solubility of niobium carbide and niobium carbonitride in alloyed austenite and ferrite , 1984 .

[20]  R. F. Mehl,et al.  Transformation from austenite in alloy steels , 1976 .

[21]  宮田 昇 Chemical Thermodynamics of materials, C.H.P. Lupis (著), 1983年, North-Holland/Elsevier Science Publishing Co., Inc. 発刊, 175×255mm, 582ページ, Dfl. 120.00 , 1984 .

[22]  W. B. Pearson,et al.  A handbook of lattice spacings and structures of metals and alloys , 1958 .

[23]  P. Hodgson,et al.  Retained austenite characteristics in thermomechanically processed Si-Mn transformation-induced plasticity steels , 1997 .

[24]  D. Welch Introduction to Metallurgical Thermodynamics , 1983 .