The Tomb of the Diver and the frescoed tombs in Paestum (southern Italy): New insights from a comparative archaeometric study

The Tomb of the Diver has been subject for many decades of fierce debate among archaeologists and classicists. Since its discovery in 1968, some scholars have considered it a unique example of the lost tradition of Greek painting, others have emphasized Etruscan or Italic parallels. More recently, a possible local production has been suggested. With the aim of trying to solve the archaeological question, an archaeometric comparison among this well-known artwork and several frescoed tombs coming from Hellenistic and Lucan necropolis was carried out. The multi-analytical study was focused on the identification of peculiar features of executive techniques and raw materials since the first period of the archaeological site. The analytical investigation has been preliminary based on a non-destructive approach, performed in-situ by portable equipment including imaging diagnostics and compositional spectroscopic techniques for identifying pigments and the conservation state of original painted surface; subsequently, a further deepening by using destructive techniques was performed in-lab for the mortar-based supports characterization. Archaeometric study suggested that technological choices slightly changed in a time span of about two centuries, highlighting important markers that allow clustering the contemporary artistic productions. Moreover, a comparison with mortars from temples decorations was provided to better understand the whole artistic context. The archaeometric data showed that the Tomb of the Diver could be traced back to a local artisanal tradition and therefore is neither Etruscan nor Greek, but the first and foremost an expression of the local elite culture of Paestum.

[1]  Thomas J. Tague, Jr.,et al.  Evaluation and optimization of the potential of a handheld Raman spectrometer: in situ, noninvasive materials characterization in artworks , 2019, Journal of Raman Spectroscopy.

[2]  S. Ruffolo,et al.  An archaeometric approach of historical mortars taken from Foligno City (Umbria, Italy): news insight of Roman Empire in Italy , 2018, Archaeological and Anthropological Sciences.

[3]  Francesco Izzo,et al.  Production technology of mortar-based building materials from the Arch of Trajan and the Roman Theatre in Benevento, Italy , 2018, The European Physical Journal Plus.

[4]  D. Sali,et al.  Multi-analytical and non-invasive characterization of the polychromy of wall paintings at the Domus of Octavius Quartio in Pompeii , 2018, The European Physical Journal Plus.

[5]  P. Baraldi,et al.  Images and colors from the tombs of Paestum: a multidisciplinary study of the pigments in the flora and fauna iconography , 2018, Journal of Archaeological Science: Reports.

[6]  D. Magrini,et al.  Results of diagnostic campaign promoted by AIAr in the deposits of the Archaeological Museum of Paestum , 2018, IOP Conference Series: Materials Science and Engineering.

[7]  J. Madariaga,et al.  In situ non-invasive characterization of the composition of Pompeian pigments preserved in their original bowls , 2018, Microchemical Journal.

[8]  R. Siddall Mineral Pigments in Archaeology: Their Analysis and the Range of Available Materials , 2018 .

[9]  A. Vergara,et al.  The characterization of natural gemstones using non-invasive FT-IR spectroscopy: New data on tourmalines. , 2018, Talanta.

[10]  A. Langella,et al.  Radiocarbon dating of mortars: Contamination effects and sample characterisation. The case-study of Andalusian medieval castles (Jaén, Spain) , 2017 .

[11]  Marie D. Jackson,et al.  Phillipsite and Al-tobermorite mineral cements produced through low-temperature water-rock reactions in Roman marine concrete , 2017 .

[12]  J. Mevellec,et al.  The use of vibrational spectroscopy techniques as a tool for the discrimination and identification of the natural and synthetic organic compounds used in conservation , 2016 .

[13]  Francesco Izzo,et al.  Beyond Vitruvius: New Insight in the Technology of Egyptian Blue and Green Frits , 2016 .

[14]  Francesco Izzo,et al.  The art of building in the Roman period (89 B.C. – 79 A.D.): Mortars, plasters and mosaic floors from ancient Stabiae (Naples, Italy) , 2016 .

[15]  C. Colombo,et al.  Portable Sequentially Shifted Excitation Raman spectroscopy as an innovative tool for in situ chemical interrogation of painted surfaces. , 2016, The Analyst.

[16]  Ryota Watanabe,et al.  Precipitation of manganese oxides on the surface of construction materials in the Khmer temples, Cambodia , 2016, Heritage Science.

[17]  G. Xanthopoulou,et al.  Ancient Egyptian Blue (CaCuSi4O10) Pigment by Modern Solution Combustion Synthesis Method , 2016 .

[18]  S. Ruffolo,et al.  A multi-analytical approach applied to the archaeometric study of mortars from the Forty Martyrs rupestrian complex in Cappadocia (Turkey) , 2016 .

[19]  Costanza Miliani,et al.  Interpretation of mid and near-infrared reflection properties of synthetic polymer paints for the non-invasive assessment of binding media in twentieth-century pictorial artworks , 2016 .

[20]  Eugenia P. Tomasini,et al.  Micro‐Raman spectroscopy of carbon‐based black pigments , 2012 .

[21]  Costanza Miliani,et al.  Reflection infrared spectroscopy for the non-invasive in situ study of artists’ pigments , 2012 .

[22]  Koenraad Van Balen,et al.  Hydraulicity in Historic Lime Mortars: A Review , 2012 .

[23]  C. Mazzoli,et al.  The Temple of Venus (Pompeii): a study of the pigments and painting techniques , 2011 .

[24]  D. Benavente,et al.  Mechanical Evolution of Lime Mortars during the Carbonation Process , 2011 .

[25]  Danilo Bersani,et al.  Pigments used in Roman wall paintings in the Vesuvian area , 2010 .

[26]  Costanza Miliani,et al.  An integrated spectroscopic approach for the non-invasive study of modern art materials and techniques , 2010 .

[27]  Costanza Miliani,et al.  In situ noninvasive study of artworks: the MOLAB multitechnique approach. , 2010, Accounts of chemical research.

[28]  E. Castellucci,et al.  Metal oxalates in paints: a Raman investigation on the relative reactivities of different pigments to oxalic acid solutions , 2010, Analytical and bioanalytical chemistry.

[29]  M. Cipriani Sistemi decorativi e officine a Paestum , 2010 .

[30]  Danilo Bersani,et al.  Green pigments of the Pompeian artists' palette. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[31]  S. Gunasekaran,et al.  Infrared, optical absorption, and EPR spectroscopic studies on natural gypsum , 2009 .

[32]  Costanza Miliani,et al.  The exceptional near-infrared luminescence properties of cuprorivaite (Egyptian blue). , 2009, Chemical communications.

[33]  C. Rodriguez-Navarro,et al.  Sulfation of calcitic and dolomitic lime mortars in the presence of diesel particulate matter , 2008 .

[34]  P. P. Lottici,et al.  ‘Green earths’: vibrational and elemental characterization of glauconites, celadonites and historical pigments , 2008 .

[35]  Nicholas Eastaugh,et al.  The pigment compendium , 2004 .

[36]  C. Fernández-Lorenzo,et al.  Spectroscopic analysis of roman wall paintings from Casa del Mitreo in Emerita Augusta, Mérida, Spain. , 2003, Talanta.

[37]  A. Doménech‐Carbó,et al.  Identification of Synthetic Resins Used in Works of Art by Fourier Transform Infrared Spectroscopy , 2001 .

[38]  Domenico Calcaterra,et al.  Building stone and related weathering in the architecture of the ancient city of Naples , 2000 .

[39]  E. Pavlidou,et al.  Ochre-differentiation through micro-Raman and micro-FTIR spectroscopies: application on wall paintings at Meteora and Mount Athos, Greece. , 2000, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[40]  Mauro Bacci,et al.  A Color Analysis of the Brancacci Chapel Frescoes , 1991 .