Quick monitoring of pozzolanic reactivity of waste ashes.

This article proposes a quick method of monitoring for pozzolanic reactivity of waste ashes by investigating the electrical conductivity of the suspension at an elevated temperature. This suspension is obtained by mixing tested pozzolan with an ordinary Portland cement (OPC) solution produced by mixing ordinary Portland cement with water. For comparison, silica fume, metakaolin, rice husk ash and river sand - whose pozzolanic reactivities range from reactive to inert - were used in the experimental investigation. The electrical conductivity of the suspension was continually recorded by using an electrical conductivity meter and stored by using a personal computer for a period of slightly over 1day. The indicative parameters that can be related to pozzolanic reactivity were discussed and analyzed in detail. It was found that it is possible to determine the pozzolanic reactivity of fly ash within 28h by using the proposed technique, as compared to 7 or 28 days for the determination of strength activity index according to ASTM. This technique would help concrete technologists to speedily investigate the quality of fly ash for use as a cement replacement in order to alleviate pollution caused by cement production and solve disposal problems of waste ashes.

[1]  Chai Jaturapitakkul,et al.  A study of disposed fly ash from landfill to replace Portland cement. , 2004, Waste management.

[2]  W. McCarter,et al.  Monitoring the early hydration mechanisms of hydraulic cement , 1988 .

[3]  Du Tran,et al.  Monitoring pozzolanic activity by direct activation with calcium hydroxide , 1996 .

[4]  Arnon Bentur,et al.  The influence of microfillers on enhancement of concrete strength , 1993 .

[5]  L. Ottosen,et al.  Possible applications for municipal solid waste fly ash. , 2003, Journal of hazardous materials.

[6]  Chai Jaturapitakkul,et al.  Use of waste ash from palm oil industry in concrete. , 2007, Waste management.

[7]  A. Neville Properties of Concrete , 1968 .

[8]  Ramasubramania Iyer The surface chemistry of leaching coal fly ash. , 2002, Journal of hazardous materials.

[9]  C. Shi,et al.  Comparison of different methods for enhancing reactivity of pozzolans , 2001 .

[10]  Jordi Payá,et al.  Enhanced conductivity measurement techniques for evaluation of fly ash pozzolanic activity , 2001 .

[11]  C. Jaturapitakkul,et al.  A STUDY OF GROUND COARSE FLY ASHES WITH DIFFERENT FINENESSES FROM VARIOUS SOURCES AS POZZOLANIC MATERIALS , 2001 .

[12]  Andrew J. Weaver The Science of Climate Change , 2003 .

[13]  E. Peris Mora,et al.  Influence of different sized fractions of a fly ash on workability of mortars , 1993 .

[14]  C. Jaturapitakkul,et al.  Effect of insoluble residue on properties of Portland cement , 2000 .

[15]  Qijun Yu,et al.  The reaction between rice husk ash and Ca(OH)2 solution and the nature of its product , 1999 .

[16]  C. Jaturapitakkul,et al.  Packing effect and pozzolanic reaction of fly ash in mortar , 2005 .

[17]  M. P. Luxán,et al.  Rapid evaluation of pozzolanic activity of natural products by conductivity measurement , 1989 .

[18]  J. Houghton,et al.  Climate change 1995: the science of climate change. , 1996 .

[19]  Jordi Payá,et al.  Mechanical treatment of fly ashes. Part I: Physico-chemical characterization of ground fly ashes , 1995 .