Solar photovoltaic technology on rough low carbon steel substrates for building integrated photovoltaics: A complete fabrication sequence

Abstract The purpose of this paper is to show an innovative and complete fabrication sequence of thin film photovoltaic modules based on hydrogenated amorphous silicon on non transparent substrates (high roughness low carbon steel). This fabrication sequence is oriented to monolithically interconnected modules with two main challenges (i) the development of surface treatment technology (low cost intermediate inorganic coatings based on sol–gel technology) for the deposition of thin film solar cells on non transparent substrates and (ii) the use of novel laser scribing methods in substrate configuration. After the research carried out in this work, we demonstrate that (i) surface treatment technology has been successfully developed proving its good behavior in 1 cm 2 steel solar cells achieving efficiencies close to 7%, and (ii) laser scribing method has also been succeeded achieving efficiencies higher than 3% in 64 cm 2 modules. Electrical losses due to these processes have been evaluated. It is important to point out that, although silicon based technology has been used, these advances are not directly related to any specific thin film solar technology, being suitable for CIGS and CdTe solar cells.

[1]  Shuo-Jen Lee,et al.  Influence of the molybdenum thickness on the conversion efficiency of thin-film a-Si:H solar cells grown on a 304 stainless steel substrate , 2013 .

[2]  Bernd Rech,et al.  The effect of front ZnO:Al surface texture and optical transparency on efficient light trapping in silicon thin-film solar cells , 2007 .

[3]  Alessandra Scognamiglio,et al.  Photovoltaics and zero energy buildings: a new opportunity and challenge for design , 2013 .

[4]  Yi-Ho Chen,et al.  Improved performance of amorphous Si thin-film solar cells on 430 stainless steel substrate by an electrochemical mechanical polishing process , 2013 .

[5]  Elvira Fortunato,et al.  Silicon thin film solar cells on commercial tiles , 2011 .

[6]  Domenico Caputo,et al.  Silicon Based Thin Film Solar Cells , 2013 .

[7]  X. Deng,et al.  Amorphous silicon and silicon germanium materials for high-efficiency triple-junction solar cells , 2000 .

[8]  Arnulf Jäger-Waldau,et al.  Research, Solar Cell Production and Market Implementation of Photovoltaics , 2005 .

[9]  Yun Sun,et al.  Development of textured back reflector for n–i–p flexible silicon thin film solar cells , 2010 .

[10]  M. Gemmi,et al.  Very high frequency hydrogen plasma treatment of growing surfaces: a study of the p-type amorphous to microcrystalline silicon transition , 2000 .

[11]  H. Kozuka Stress evolution on gel-to-ceramic thin film conversion , 2006 .

[12]  Ying Huang,et al.  Building-integrated photovoltaics (BIPV) in architectural design in China , 2011 .

[13]  Maria Kolokotroni,et al.  ETFE foil cushions in roofs and atria , 2001 .

[14]  J. Loffler,et al.  Roll to roll fabrication process of thin film silicon solar cells on steel foil , 2009, 2009 34th IEEE Photovoltaic Specialists Conference (PVSC).

[15]  I. B. Hagemann,et al.  Perspectives and Challenge of BIPV Product Design , 2011 .

[16]  Rosaria Ciriminna,et al.  Flexible solar cells. , 2008, ChemSusChem.

[17]  C. Ballif,et al.  Development of micromorph tandem solar cells on flexible low cost plastic substrates , 2009 .

[18]  Plinio Innocenzi,et al.  Structure and properties of sol-gel coatings from methyltriethoxysilane and tetraethoxysilane , 1994 .

[19]  Bjørn Petter Jelle,et al.  Building integrated photovoltaic products: A state-of-the-art review and future research opportunities , 2012 .

[20]  Heather Booth,et al.  Laser Processing in Industrial Solar Module Manufacturing , 2010 .

[21]  Miwa Tominaga,et al.  Opportunities for thin film photovoltaics in Building Integrated photovoltaics (BIPV)with a focus on Australia , 2009 .

[22]  M. Takemori Crack formation, exfoliation, and ridge formation in 500 °C annealed sol-gel silica coatings on stainless steel SUS304: Part I. Microscopic observations and elemental analyses , 2009 .

[23]  M. Guglielmi Sol-Gel Coatings on Metals , 1997 .

[24]  E. Centurioni,et al.  Thin-film solar cells on commercial ceramic tiles , 2009 .

[25]  Radial n–i–p structure silicon nanowire‐based solar cells on flexible stainless steel substrates , 2013 .

[26]  W. V. Sark,et al.  Technical potential for photovoltaics on buildings in the EU-27 , 2012 .