Viscoplastic Matrix Materials for Embedded 3D Printing.

Embedded three-dimensional (EMB3D) printing is an emerging technique that enables free-form fabrication of complex architectures. In this approach, a nozzle is translated omnidirectionally within a soft matrix that surrounds and supports the patterned material. To optimize print fidelity, we have investigated the effects of matrix viscoplasticity on the EMB3D printing process. Specifically, we determine how matrix composition, print path and speed, and nozzle diameter affect the yielded region within the matrix. By characterizing the velocity and strain fields and analyzing the dimensions of the yielded regions, we determine that scaling relationships based on the Oldroyd number, Od, exist between these dimensions and the rheological properties of the matrix materials and printing parameters. Finally, we use EMB3D printing to create complex architectures within an elastomeric silicone matrix. Our methods and findings will both facilitate future characterization of viscoplastic matrices and motivate the development of new materials for EMB3D printing.

[1]  J. Lewis,et al.  Omnidirectional Printing of 3D Microvascular Networks , 2011, Advanced materials.

[2]  Flow induced by a sphere settling in an aging yield-stress fluid , 2006, cond-mat/0605608.

[3]  D. Beebe,et al.  A particle image velocimetry system for microfluidics , 1998 .

[4]  Gareth H. McKinley,et al.  An experimental investigation of negative wakes behind spheres settling in a shear-thinning viscoelastic fluid , 1998 .

[5]  Curtis R. Taylor,et al.  Three-dimensional printing with sacrificial materials for soft matter manufacturing , 2017 .

[6]  Yihu Song,et al.  Rheology of fumed silica/polydimethylsiloxane suspensions , 2017 .

[7]  Hyoungsoo Kim,et al.  Spontaneous Marangoni Mixing of Miscible Liquids at a Liquid-Liquid-Air Contact Line. , 2015, Langmuir : the ACS journal of surfaces and colloids.

[8]  Tapomoy Bhattacharjee,et al.  Writing in the granular gel medium , 2015, Science Advances.

[9]  Daniel M. Vogt,et al.  Embedded 3D Printing of Strain Sensors within Highly Stretchable Elastomers , 2014, Advanced materials.

[10]  Thomas J. Hinton,et al.  3D Printing PDMS Elastomer in a Hydrophilic Support Bath via Freeform Reversible Embedding , 2016, ACS biomaterials science & engineering.

[11]  Evan Mitsoulis,et al.  FLOWS OF VISCOPLASTIC MATERIALS: MODELS AND COMPUTATIONS , 2007 .

[12]  A. Putz,et al.  Settling of an isolated spherical particle in a yield stress shear thinning fluid , 2008 .

[13]  Albert Magnin,et al.  Viscoplastic flow around a cylinder in an infinite medium , 2003 .

[14]  John Tsamopoulos,et al.  Creeping motion of a sphere through a Bingham plastic , 1985, Journal of Fluid Mechanics.

[15]  D. Bonn,et al.  “Everything flows?”: elastic effects on startup flows of yield-stress fluids , 2017, Rheologica Acta.

[16]  Albert Magnin,et al.  Very slow flow of Bingham viscoplastic fluid around a circular cylinder , 2008 .

[17]  Robert J. Wood,et al.  An integrated design and fabrication strategy for entirely soft, autonomous robots , 2016, Nature.

[18]  J. Lewis,et al.  Printing soft matter in three dimensions , 2016, Nature.