An Innovative Agro-Forestry Supply Chain for Residual Biomass: Physicochemical Characterisation of Biochar from Olive and Hazelnut Pellets

Concerns about climate change and food productivity have spurred interest in biochar, a form of charred organic material typically used in agriculture to improve soil productivity and as a means of carbon sequestration. An innovative approach in agriculture is the use of agro-forestry waste for the production of soil fertilisers for agricultural purposes and as a source of energy. A common agricultural practice is to burn crop residues in the field to produce ashes that can be used as soil fertilisers. This approach is able to supply plants with certain nutrients, such as Ca, K, Mg, Na, B, S, and Mo. However, the low concentration of N and P in the ashes, together with the occasional presence of heavy metals (Ni, Pb, Cd, Se, Al, etc.), has a negative effect on soil and, therefore, crop productivity. This work describes the opportunity to create an innovative supply chain from agricultural waste biomass. Olive (Olea europaea) and hazelnut (Corylus avellana) pruning residues represent a major component of biomass waste in the area of Viterbo (Italy). In this study, we evaluated the production of biochar from these residues. Furthermore, a physicochemical characterisation of the produced biochar was performed to assess the quality of the two biochars according to the standards of the European Biochar Certificate (EBC). The results of this study indicate the cost-effective production of high-quality biochar from olive and hazelnut biomass residues.

[1]  D. Laird,et al.  Review of the pyrolysis platform for coproducing bio‐oil and biochar , 2009 .

[2]  William A. Telliard,et al.  PRIORITY POLLUTANTS I-A PERSPECTIVES VIEW , 1979 .

[3]  A. Peressotti,et al.  Application of biochar on mine tailings: effects and perspectives for land reclamation. , 2011, Chemosphere.

[4]  Markus Antonietti,et al.  Effect of biochar amendment on soil carbon balance and soil microbial activity , 2009 .

[5]  J. Manyà,et al.  Pyrolysis for biochar purposes: a review to establish current knowledge gaps and research needs. , 2012, Environmental science & technology.

[6]  Wim Turkenburg,et al.  Exploration of the ranges of the global potential of biomass for energy , 2003 .

[7]  L. Beesley,et al.  A review of biochars' potential role in the remediation, revegetation and restoration of contaminated soils. , 2011, Environmental pollution.

[8]  Zhengang Liu,et al.  Production of solid biochar fuel from waste biomass by hydrothermal carbonization , 2013 .

[9]  J. Skjemstad,et al.  Synthesis and characterisation of laboratory-charred grass straw (Oryza sativa) and chestnut wood (Castanea sativa) as reference materials for black carbon quantification , 2006 .

[10]  M. Ahmedna,et al.  CHARACTERIZATION OF DESIGNER BIOCHAR PRODUCED AT DIFFERENT TEMPERATURES AND THEIR EFFECTS ON A LOAMY SAND , 2009 .

[11]  S. Polasky,et al.  Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. , 2006, Proceedings of the National Academy of Sciences of the United States of America.

[12]  G. Wright,et al.  Biochar and biochar-compost as soil amendments: effects on peanut yield, soil properties and greenhouse gas emissions in tropical North Queensland, Australia , 2015 .

[13]  Zhihong Xu,et al.  Biochar: Nutrient Properties and Their Enhancement , 2012 .

[14]  C. Blasi,et al.  Effects of Particle Size and Density on the Packed-Bed Pyrolysis of Wood , 2013 .

[15]  J. Laine,et al.  Effect of the preparation method on the pore size distribution of activated carbon from coconut shell , 1992 .

[16]  J. Satrio,et al.  Characterization of biochar from fast pyrolysis and gasification systems , 2009 .

[17]  M. Schwanninger,et al.  Characterization of slow pyrolysis biochars: effects of feedstocks and pyrolysis temperature on biochar properties. , 2012, Journal of environmental quality.

[18]  Johannes Lehmann,et al.  A handful of carbon , 2007, Nature.

[19]  D. Laird,et al.  Impact of biochar amendments on the quality of a typical Midwestern agricultural soil , 2010 .

[20]  M. García-Pérez The Formation of Polyaromatic Hydrocarbons and Dioxins During Pyrolysis: A Review of the Literature with Descriptions of Biomass Composition, Fast Pyrolysis Technologies and Thermochemical Reactions June 2008 , 2008 .

[21]  T. Mattila,et al.  Biochar addition to agricultural soil increased CH4 uptake and water holding capacity – Results from a short-term pilot field study , 2011 .

[22]  Kunio Yoshikawa,et al.  Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy , 2015 .

[23]  O. Martínez,et al.  Pyrolysis of agricultural residues from rape and sunflowers: Production and characterization of bio-fuels and biochar soil management , 2009 .

[24]  F. Gallucci,et al.  Use of hazelnut’s pruning to produce biochar by gasifier small scale plant , 2015 .

[25]  J.B-son Bredenberg,et al.  Hydrogenolysis and hydrocracking of the carbon-oxygen bond. 2. Thermal cleavage of the carbon-oxygen bond in guaiacol , 1982 .

[26]  C. Kruger,et al.  Influence of Contrasting Biochar Types on Five Soils at Increasing Rates of Application , 2011 .

[27]  P. Nico,et al.  Dynamic molecular structure of plant biomass-derived black carbon (biochar). , 2010, Environmental science & technology.

[28]  Ram Chandra,et al.  Hydrothermal pretreatment of rice straw biomass: A potential and promising method for enhanced methane production , 2012 .

[29]  Jan Mumme,et al.  Hydrothermal Carbonization of Biomass for Energy and Crop Production , 2014 .

[30]  R. Kothari,et al.  Thermo chemical conversion of biomass – Eco friendly energy routes , 2012 .

[31]  S. Dutta,et al.  Preparation, characterization and optimization for upgrading Leucaena leucocephala bark to biochar fuel with high energy yielding , 2016 .

[32]  P. Crutzen,et al.  Toward a global estimate of black carbon in residues of vegetation fires representing a sink of atmospheric CO2 and a source of O2 , 1995 .

[33]  Bruno Glaser,et al.  One step forward toward characterization: some important material properties to distinguish biochars. , 2012, Journal of environmental quality.

[35]  Julia W. Gaskin,et al.  Effect of Low-Temperature Pyrolysis Conditions on Biochar for Agricultural Use , 2008 .

[36]  Mohammad. Rasul,et al.  Biofuels Production through Biomass Pyrolysis —A Technological Review , 2012 .

[37]  Ayhan Demirbas,et al.  Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues , 2004 .

[38]  N. Marsh,et al.  Global Kinetic Rate Parameters for the Formation of Polycyclic Aromatic Hydrocarbons from the Pyrolyis of Catechol, A Model Compound Representative of Solid Fuel Moieties , 2002 .

[39]  J. Lehmann,et al.  Biochar for Environmental Management: Science and Technology , 2009 .

[40]  Raffaele Spinelli,et al.  Open-Air Drying of Cut and Windrowed Short-Rotation Poplar Stems , 2015, BioEnergy Research.

[41]  Ayhan Demirbas,et al.  Partly chemical analysis of liquid fraction of flash pyrolysis products from biomass in the presence of sodium carbonate , 2002 .

[42]  B. Xing,et al.  Compositions and sorptive properties of crop residue-derived chars. , 2004, Environmental science & technology.

[43]  Michael W. I. Schmidt,et al.  Black (pyrogenic) carbon: a synthesis of current knowledge and uncertainties with special consideration of boreal regions , 2006 .

[44]  S. Sohi BIOCHAR, CLIMATE CHANGE AND SOIL: A REVIEW TO GUIDE FUTURE RESEARCH , 2009 .

[45]  G. Giacomo,et al.  Renewable energy benefits with conversion of woody residues to pellets , 2009 .

[46]  J. O H N L G A U N T,et al.  Energy Balance and Emissions Associated with Biochar Sequestration and Pyrolysis Bioenergy Production , 2008 .