Electronic structure of intermetallic compounds with CsCl structure: NMR relaxation times

NMR relaxation times T1 and T2 at the Sc and La sites have been measured in a series of intermetallic compounds ScB (B=Cu, Ag, Pd, Rh, Ir, Ru) and LaAg. The product (T1T) is constant for temperatures between 30K and 300K. Below 30K an influence of magnetic impurities on the susceptibility and spin-lattice relaxation time measurements has been found. The analysis for the electronic structure is given in terms of local susceptibilities based on these T1 measurements and in terms of a two-band model.

[1]  J. Kubler Electronic structure of ScRu, ScRh, ScPd, and ScAg , 1978 .

[2]  S. Hüfner,et al.  Ultraviolet photoemission from intermetallic compounds with CsCl structure: ScAg, ScPd, ScIr and ScRu , 1978 .

[3]  H. E. Hoenig,et al.  Electronic structure of intermetallic compounds with CsCl structure , 1977 .

[4]  B. Elschner,et al.  Exchange interaction between localized (4f)-electrons of Gd and conduction electrons in CsCl intermetallic compounds☆ , 1977 .

[5]  D. K. Ray,et al.  Theoretical study of the electronic structure of some cubic intermetallic compounds of dysprosium using the augmented plane wave method , 1975 .

[6]  B. Elschner,et al.  Electron spin resonance of Gd in intermetallic compounds with CsCl structure , 1975 .

[7]  K. Buschow,et al.  On the electronic structure of LaAg and LaZn (magnetic susceptibility and Knight shift) , 1975 .

[8]  E. V. Meerwall,et al.  NMR in CsCl-ordered non-magnetic LaAg and YCu , 1975 .

[9]  T. H. Brown,et al.  New reference compounds for the knight shifts in 55Mn and 103Rh , 1970 .

[10]  L. Isaacs,et al.  Magnetic and Nuclear-Resonance Properties of Single-Crystal Scandium , 1969 .

[11]  I. Campbell Hyperfine fields on impurities in ferromagnetic metals , 1969 .

[12]  B. Giovannini,et al.  Relaxation des spins nucleaires dans les alliages dilues , 1969 .

[13]  A. Narath NUCLEAR MAGNETIC RESONANCE IN HEXAGONAL LANTHANUM METAL: KNIGHT SHIFTS, SPIN RELAXATION RATES, AND QUADRUPOLE COUPLING CONSTANTS. , 1969 .

[14]  D. W. Alderman,et al.  Nuclear Spin Relaxation in Molybdenum Metal , 1966 .

[15]  J. Seitchik,et al.  Knight Shift Studies of Transition Metals: Rhodium and Rhodium Intermetallic Compounds , 1965 .

[16]  W. E. Gardner,et al.  THE MAGNETIC SUSCEPTIBILITY OF SCANDIUM , 1965 .

[17]  W. Clark Pulsed Nuclear Resonance Apparatus , 1964 .

[18]  J. Korringa Nuclear magnetic relaxation and resonnance line shift in metals , 1950 .