MicroRaman and Infrared spectroscopic characterization of ancient cosmetics

Abstract By FT-IR and microRaman spectrometry a large number of black to gray powders have been analysed. The studied remains were found inside Pompeiian unguentaries situated in depository of “Casa Bacco”. By the analytical results it has been possible to understand the different nature and composition of the materials employed in preparation of ancient cosmetic powders. Dark black powders were essentially composed of amorphous carbon probably due to the carbonisation of vegetal or animal tissues. By using different starting materials or by adding different powders to the black carbon other hues could be also obtained. Particularly, this study enabled to gain a complete and unambiguous composition characterization of these old cosmetics.

[1]  S. Pagés-Camagna,et al.  Study of Gustave Moreau's black drawings: identification of the graphic materials by Raman microspectrometry and PIXE , 2004 .

[2]  C. Giordano,et al.  Profumi Unguenti E Acconciature in Pompei Antica , 1992 .

[3]  P. Baraldi,et al.  Aragonite in Roman wall paintings of the VIII(a) Regio, Aemilia, and X(a) Regio, Venetia et Histria. , 2006, Annali di chimica.

[4]  G. Jones,et al.  The Roman Mines at Riotinto , 1980, Journal of Roman Studies.

[5]  E. Dooryhee,et al.  Making make-up in Ancient Egypt , 1999, Nature.

[6]  H. Edwards,et al.  Fourier-transform Raman spectroscopic study of natural waxes and resins. I , 1996 .

[7]  A. Lucas Ancient Egyptian Materials and Industries , 1935 .

[8]  P. Walter,et al.  Revealing the powdering methods of black makeup in Ancient Egypt by fitting microstructure based Fourier coefficients to the whole x-ray diffraction profiles of galena , 2002 .

[9]  A. Wallert Unusual pigments on a Greek marble basin , 1995 .

[10]  A. Chapman,et al.  CCCXLII.—Examination of an ancient Egyptian (Tutankh-Amen) cosmetic , 2022 .

[11]  R. DeGeest,et al.  Assessing the relationship between form and use of different kinds of pottery from the archaeological site Sagalassos (southwest Turkey) with lipid analysis , 2004 .

[12]  R. J. Forbes,et al.  Studies in ancient technology , 1955 .

[13]  R. Evershed,et al.  Archaeology: Formulation of a Roman cosmetic , 2004, Nature.

[14]  R. Frost,et al.  A Raman spectroscopic study of selected natural jarosites. , 2006, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[15]  M. Regert,et al.  Chemical alteration and use of beeswax through time: accelerated ageing tests and analysis of archaeological samples from various environmental contexts , 2001 .