Observation of coupled plasmon-polariton modes in Au nanoparticle chain waveguides of different lengths: Estimation of waveguide loss

Near-field interactions between closely spaced Au nanoparticles were characterized by studying the spectral position of the extinction bands corresponding to longitudinal (L) and transverse (T) plasmon-polariton modes of Au nanoparticle chains. Far-field spectroscopy and finite-difference time-domain simulations on arrays of 50 nm diameter Au spheres with an interparticle spacing of 75 nm both show a splitting DeltaE between the L and T modes that increases with chain length and saturates at a length of seven particles at DeltaE = 65 meV. We show that the measured splitting will result in a propagation loss of 3 dB/15 nm for energy transport. Calculations indicate that this loss can be reduced by at least one order of magnitude by modifying the shape of the constituent particles.