WS₂ saturable absorber for dissipative soliton mode locking at 1.06 and 1.55 µm.

Transition-metal dichalcogenides, such as tungsten disulfide (WS2) and molybdenium disulfide (MoS2), are highly anisotropic layered materials and have attracted growing interest from basic research to practical applications due to their exotic physical property that may complement graphene and other semiconductor materials. WS2 nanosheets are found to exhibit broadband nonlinear saturable absorption property, and saturable absorbers (SAs) are fabricated by depositing WS2 nanosheets on side-polished fibers. Attributing to the weak evanescent field and long interaction length, the WS2 nanosheets are not exposed to large optical intensity, which allows the SA to work at the high-power regime. The SAs are used to mode lock erbium- and ytterbium-doped fiber lasers with normal dispersion, producing trains of dissipative soliton at 1.55 and 1.06 µm respectively. Simulations show that the bandgap of WS2 nanosheets decreases from 1.18 to 0.02 and 0.65 eV by introducing W and S defects respectively, which may contribute to the broadband saturable absorption property of the WS2.

[1]  D. Mao,et al.  Pulse-State Switchable Fiber Laser Mode-Locked by Carbon Nanotubes , 2015, IEEE Photonics Technology Letters.

[2]  Jonathan N. Coleman,et al.  Two‐Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials. , 2011 .

[3]  Jianlin Zhao,et al.  WS2 mode-locked ultrafast fiber laser , 2015, Scientific Reports.

[4]  Liangmo Mei,et al.  Broadband Few‐Layer MoS2 Saturable Absorbers , 2014, Advanced materials.

[5]  Lain‐Jong Li,et al.  Synthesis of Large‐Area MoS2 Atomic Layers with Chemical Vapor Deposition , 2012, Advanced materials.

[6]  Dong Wang,et al.  Tunable band gap photoluminescence from atomically thin transition-metal dichalcogenide alloys. , 2013, ACS nano.

[7]  Jianlin Zhao,et al.  Soliton fiber laser mode locked with two types of film-based Bi 2 Te 3 saturable absorbers , 2015 .

[8]  Xueming Liu Dynamic evolution of temporal dissipative-soliton molecules in large normal path-averaged dispersion fiber lasers , 2010 .

[9]  M. Liu,et al.  2 GHz passively harmonic mode-locked fiber laser by a microfiber-based topological insulator saturable absorber. , 2013, Optics letters.

[10]  Wei Zhang,et al.  All-Fiber Dissipative Solitons Evolution in a Compact Passively Yb-Doped Mode-Locked Fiber Laser , 2012, Journal of Lightwave Technology.

[11]  Andreas Klein,et al.  Electronic band structure of single-crystal and single-layer WS 2 : Influence of interlayer van der Waals interactions , 2001 .

[12]  B. Radisavljevic,et al.  Mobility engineering and a metal-insulator transition in monolayer MoS₂. , 2013, Nature materials.

[13]  Kenneth L. Shepard,et al.  Chip-integrated ultrafast graphene photodetector with high responsivity , 2013, Nature Photonics.

[14]  M. Terrones,et al.  Photosensor Device Based on Few‐Layered WS2 Films , 2013 .

[15]  Hongzheng Chen,et al.  Graphene-like two-dimensional materials. , 2013, Chemical reviews.

[16]  D. Basko,et al.  Graphene mode-locked ultrafast laser. , 2009, ACS nano.

[17]  Xueming Liu,et al.  Distributed ultrafast fibre laser , 2015, Scientific Reports.

[18]  Bo Liu,et al.  High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide , 2014, Nature Communications.

[19]  Meng Liu,et al.  Femtosecond pulse erbium-doped fiber laser by a few-layer MoS(2) saturable absorber. , 2014, Optics letters.

[20]  J R Taylor,et al.  Tunable Q-switched fiber laser based on saturable edge-state absorption in few-layer molybdenum disulfide (MoS₂). , 2014, Optics express.

[21]  X. M. Liu,et al.  Partially polarized wave-breaking-free dissipative soliton with super-broad spectrum in a mode-locked fiber laser , 2011 .

[22]  Junsong Yuan,et al.  Exploring atomic defects in molybdenum disulphide monolayers , 2015, Nature Communications.

[23]  Jun Wang,et al.  WS₂ as a saturable absorber for ultrafast photonic applications of mode-locked and Q-switched lasers. , 2015, Optics express.

[24]  D. Late,et al.  MoS2 and WS2 analogues of graphene. , 2010, Angewandte Chemie.

[25]  Z. K. Liu,et al.  Experimental Realization of a Three-Dimensional Topological Insulator , 2010 .

[26]  Litao Sun,et al.  Synthesis and Optical Properties of Large‐Area Single‐Crystalline 2D Semiconductor WS2 Monolayer from Chemical Vapor Deposition , 2014 .

[27]  L. Fu,et al.  Superconducting Proximity Effect and Majorana Fermions at the Surface of a Topological Insulator , 2009 .

[28]  Sergey Kobtsev,et al.  Three key regimes of single pulse generation per round trip of all-normal-dispersion fiber lasers mode-locked with nonlinear polarization rotation. , 2012, Optics express.

[29]  Shuangchun Wen,et al.  Ytterbium-doped fiber laser passively mode locked by few-layer Molybdenum Disulfide (MoS2) saturable absorber functioned with evanescent field interaction , 2014, Scientific Reports.

[30]  Xia Yu,et al.  Switchable multi-wavelength Tm-doped mode-locked fiber laser. , 2015, Optics letters.

[31]  Shuangchen Ruan,et al.  Microfiber-based WS 2 -film saturable absorber for ultra-fast photonics , 2015 .

[32]  Andy Chong,et al.  All-normal-dispersion femtosecond fiber laser. , 2006, Optics express.

[33]  Keliang He,et al.  Control of valley polarization in monolayer MoS2 by optical helicity. , 2012, Nature nanotechnology.

[34]  Wang,et al.  Accurate and simple analytic representation of the electron-gas correlation energy. , 1992, Physical review. B, Condensed matter.

[35]  Haijun Zhang,et al.  Experimental Realization of a Three-Dimensional Topological Insulator, Bi2Te3 , 2009, Science.

[36]  Friedhelm Bechstedt,et al.  Semiempirical van der Waals correction to the density functional description of solids and molecular structures , 2006 .

[37]  R. K. Yadav,et al.  Ultrafast saturable absorption , 2016 .

[38]  A. Geim,et al.  Two-dimensional gas of massless Dirac fermions in graphene , 2005, Nature.

[39]  Kyunghwan Oh,et al.  Mode-locking of Er-doped fiber laser using a multilayer MoS2 thin film as a saturable absorber in both anomalous and normal dispersion regimes. , 2014, Optics express.

[40]  Heping Li,et al.  Ultrafast erbium-doped fiber laser mode-locked by a CVD-grown molybdenum disulfide (MoS2) saturable absorber. , 2014, Optics express.

[41]  S. Wen,et al.  Molybdenum disulfide (MoS₂) as a broadband saturable absorber for ultra-fast photonics. , 2014, Optics express.

[42]  J. Coleman,et al.  Broadband ultrafast nonlinear absorption and nonlinear refraction of layered molybdenum dichalcogenide semiconductors. , 2014, Nanoscale.

[43]  F. Wise,et al.  Generation of ten-cycle pulses from an ytterbium fiber laser with cubic phase compensation. , 2006, Optics letters.

[44]  Matt Probert,et al.  First-principles simulation: ideas, illustrations and the CASTEP code , 2002 .

[45]  H. Zeng,et al.  Atomically thin arsenene and antimonene: semimetal-semiconductor and indirect-direct band-gap transitions. , 2015, Angewandte Chemie.

[46]  Wei Zhao,et al.  Experimental observation of soliton molecule evolution in Yb-doped passively mode-locked fiber lasers , 2014 .

[47]  A. Krasheninnikov,et al.  Structural defects in graphene. , 2011, ACS nano.

[48]  Zhenhua Ni,et al.  Atomic‐Layer Graphene as a Saturable Absorber for Ultrafast Pulsed Lasers , 2009, 0910.5820.

[49]  Hua Zhang,et al.  The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. , 2013, Nature chemistry.

[50]  L. Chu,et al.  Evolution of electronic structure in atomically thin sheets of WS2 and WSe2. , 2012, ACS nano.

[51]  J. Qian,et al.  Nonlinear saturable absorption of vertically stood WS₂ nanoplates. , 2014, Optics letters.

[52]  Huai-jin Zhang,et al.  Topological insulator as an optical modulator for pulsed solid‐state lasers , 2013 .

[53]  Shuangchun Wen,et al.  Ultra-short pulse generation by a topological insulator based saturable absorber , 2012 .

[54]  I. Smurov,et al.  Ion-assisted deposition of MoSx films from laser-generated plume under pulsed electric field , 2001 .

[55]  Xia Yu,et al.  Nonlinear absorption of SWNT film and its effects to the operation state of pulsed fiber laser. , 2014, Optics express.