Selective Oxidation of Glycerol by Highly Active Bimetallic Catalysts at Ambient Temperature under Base-Free Conditions

Au–Pt alloy nanoparticles deposited on Mg(OH)2 (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions.

[1]  A. Villa,et al.  Selective oxidation of glycerol under acidic conditions using gold catalysts. , 2010, Angewandte Chemie.

[2]  G. Hutchings,et al.  Direct synthesis of hydrogen peroxide and benzyl alcohol oxidation using Au-Pd catalysts prepared by sol immobilization. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[3]  C. Kiely Electron microscopy: New views of catalysts. , 2010, Nature materials.

[4]  G. Hutchings,et al.  Oxidation of glycerol using gold-palladium alloy-supported nanocrystals. , 2009, Physical chemistry chemical physics : PCCP.

[5]  L. Allard,et al.  Atomic structure of three-layer Au/Pd nanoparticles revealed by aberration-corrected scanning transmission electron microscopy , 2008 .

[6]  Avelino Corma,et al.  Synergies between bio- and oil refineries for the production of fuels from biomass. , 2007, Angewandte Chemie.

[7]  George W. Huber,et al.  Synergien zwischen Bio- und Ölraffinerien bei der Herstellung von Biomassetreibstoffen , 2007 .

[8]  Robert J. Davis,et al.  Selective oxidation of glycerol over carbon-supported AuPd catalysts , 2007 .

[9]  Robert J. Davis,et al.  Influence of gold particle size on the aqueous-phase oxidation of carbon monoxide and glycerol , 2007 .

[10]  S. Sepúlveda-Guzmán,et al.  Three-layer core/shell structure in Au-Pd bimetallic nanoparticles. , 2007, Nano letters.

[11]  A. Corma,et al.  Unique gold chemoselectivity for the aerobic oxidation of allylic alcohols. , 2006, Chemical communications.

[12]  A. Villa,et al.  Effect of Particle Size on Monometallic and Bimetallic (Au,Pd)/C on the Liquid Phase Oxidation of Glycerol , 2006 .

[13]  G. Hutchings,et al.  Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO2 Catalysts , 2006, Science.

[14]  F. Porta,et al.  Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst: an insight into reaction selectivity , 2004 .

[15]  G. Hutchings,et al.  Oxidation of Glycerol Using Supported Gold Catalysts , 2004 .

[16]  G. Hutchings,et al.  Oxidation of glycerol using supported Pt, Pd and Au catalysts , 2003 .

[17]  G. Hutchings,et al.  Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide. , 2002, Chemical communications.

[18]  L. Prati,et al.  Selective Oxidation of D-Glucose on Gold Catalyst , 2002 .

[19]  L. Prati,et al.  Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols , 1998 .

[20]  Bm. Thaddeus,et al.  Binary Alloy Phase Diagrams Second Edition , 1990 .