Terahertz Scattering and Spectroscopic Characteristics of Polymethacryl Imide Microstructures

The translucency of terahertz wave through many polymer composite materials, particularly foams, makes it a good complement to another nondestructive testing (NDT) methods. Terahertz time-domain spectroscopy (THz-TDS) technology can obtain amplitude and phase information simultaneously. It is a powerful tool for nondestructive testing of foam materials to embody the depth information of defects while acquiring defect location, size, and nature. In the process of NDT, the refractive index is one of the important factors that affect the detection effect. In previous studies, the effective refractive index of polymethacryl imide (PMI), a commonly employed foam material, in the THz band is found to be very close to that of air. However, based on systematic measurements of the THz spectra and scattering parameters of PMI with a variety of thicknesses and densities, it is found that THz attenuation in PMI has a strong frequency dependence and that the size of the particles making up the material has a great influence on the attenuation: the larger the size of the micro particles and the faster the attenuation of the THz wave. This paper attempts to explain this phenomenon through combined experimental study and theoretical analysis, supported by the numerical simulation based on the Mie scattering model.

[1]  H. Cui,et al.  Nondestructive examination of polymethacrylimide composite structures with terahertz time-domain spectroscopy , 2017 .

[2]  Jörg Müssig,et al.  Scatter in tensile properties of flax fibre bundles: influence of determination and calculation of the cross-sectional area , 2016, Journal of Materials Science.

[3]  Pedro Gamboa,et al.  Development and characterization of a natural lightweight composite solution for aircraft structural applications , 2016 .

[4]  Alexey D. Mishin,et al.  Scattering Effects in Terahertz Wave Spectroscopy of Granulated Solids , 2015, IEEE Transactions on Terahertz Science and Technology.

[5]  M. Koch,et al.  Terahertz spectroscopy and imaging – Modern techniques and applications , 2011 .

[6]  Mingji Chen,et al.  Effects of stitch on mechanical and microwave absorption properties of radar absorbing structure , 2018, Composite Structures.

[7]  Dawei Tang,et al.  Thermal Transport in High-Strength Polymethacrylimide (PMI) Foam Insulations , 2015 .

[8]  Alfred Leder,et al.  Simultaneous determination of particle size and refractive index by time-resolved Mie scattering , 2010 .

[9]  Hong-Liang Cui,et al.  Void and crack detection of polymethacrylimide foams based on terahertz time-domain spectroscopic imaging , 2017 .

[10]  Stephanie H. Jones,et al.  Determining the unique refractive index properties of solid polystyrene aerosol using broadband Mie scattering from optically trapped beads. , 2013, Physical chemistry chemical physics : PCCP.

[11]  L. X. Ma,et al.  Investigation of the spectral reflectance and bidirectional reflectance distribution function of sea foam layer by the Monte Carlo method. , 2015, Applied optics.

[12]  S. Asano,et al.  Light scattering properties of spheroidal particles. , 1979, Applied optics.

[13]  G. Maze,et al.  Scattering of an acoustic wave by composite cylindrical shells: Influence of inner and outer layer thicknesses on the circumferential waves , 2018 .

[14]  B. Luo,et al.  Electrodynamic balance measurements of thermodynamic, kinetic, and optical aerosol properties inaccessible to bulk methods , 2015 .

[15]  Yang Wang,et al.  Dependent scattering and absorption by densely packed discrete spherical particles: Effects of complex refractive index , 2017 .

[16]  Don J. Roth,et al.  Signal Processing Approaches for Terahertz Data Obtained from Inspection of the Shuttle External Tank Thermal Protection System Foam , 2007 .

[17]  Giles Davies,et al.  Bridging the terahertz gap , 2004 .

[18]  Yongshun Ling,et al.  Infrared Extinction of Artificial Aerosols and the Effects of Size Distributions , 1998 .

[19]  S. Asano,et al.  Light scattering by a spheroidal particle. , 1975, Applied optics.

[20]  Salim Chaki,et al.  A review of non-destructive techniques used for mechanical damage assessment in polymer composites , 2018, Journal of Materials Science.

[21]  Wei Li,et al.  [Experimental Study of PMI Foam Composite Properties in Terahertz]. , 2015, Guang pu xue yu guang pu fen xi = Guang pu.

[22]  E. Brown,et al.  Attenuation contrast between biomolecular and inorganic materials at terahertz frequencies , 2004 .

[23]  Eric I. Madaras,et al.  Processing Terahertz Ray Data in Space Shuttle Inspection , 2007 .

[24]  A. Jeglic,et al.  Structural analysis of insulating polymer foams with terahertz spectroscopy and imaging , 2013 .

[25]  Jie Wu,et al.  The numerical simulation and goniometric measurements of cells light scattering based on Mie theory , 2015, Applied Optics and Photonics China.

[26]  Nikolay V. Petrov,et al.  Nondestructive monitoring of aircraft composites using terahertz radiation , 2015, Saratov Fall Meeting.

[27]  Patrick Mounaix,et al.  Terahertz dielectric characterisation of polymethacrylimide rigid foam: the perfect sheer plate? , 2004 .