Imine is an important intermediate in drug synthesis. Photocatalytic aerobic oxidative coupling of amines has been considered as a clean and promising way to produce imine and attracted great attentions. Herein, we designed and synthesized a novel two-dimensional porphyrin-based COF (Por-BC-COF) which adopts an AA stacking mode with excellent crystallinity, high Brunauer-Emmett-Teller surface areas (1200 m 2 g -1 ), wide light absorption range (200-1300 nm) and good stability in a variety of organic solvents. Por-BC-COF can be used as a metal-free heterogeneous photocatalyst for the photocatalytic oxidation of amines to imines under visible light and red light with a high yield (97%). This work presents a novel and efficient COF photocatalyst in the application of light-driven organic synthesis.