Current Perspectives in Arsenic Environmental and Biological Research

Environmental Context. Arsenic occurs in rock, fresh water and seawater. Organic arsenic compounds are found as natural constituents of many organisms and, because some, e.g. seafood, are consumed by humans, there is ongoing health interest in their arsenic content. Thio-arsenicals, a newly discovered group of arsenic compounds, may be integral to understanding the environmental behaviour of arsenic. This paper reviews recent research in arsenic environmental chemistry and discusses ideas intended to stimulate future research in this area. Abstract. Recent results in the field of arsenic environmental and biological chemistry are presented, in particular the relevance of the discoveries to issues of human health are discussed.

[1]  W. Goessler,et al.  Two Novel Thio-Arsenosugars in Scallops Identified with HPLC–ICPMS and HPLC–ESMS , 2005 .

[2]  W. Goessler,et al.  Thio arsenosugars in freshwater mussels from the Danube in Hungary. , 2005, Journal of environmental monitoring : JEM.

[3]  M. Mead,et al.  Arsenic: In Search of an Antidote to a Global Poison , 2005, Environmental health perspectives.

[4]  W. Goessler,et al.  Direct measurement of lipid-soluble arsenic species in biological samples with HPLC-ICPMS. , 2005, The Analyst.

[5]  Kazuo T. Suzuki Metabolomics of arsenic based on speciation studies , 2005 .

[6]  Mohammad Sohel Rahman,et al.  Ineffectiveness and poor reliability of arsenic removal plants in West Bengal, India. , 2005, Environmental science & technology.

[7]  M. Tallman,et al.  Arsenic trioxide: new clinical experience with an old medication in hematologic malignancies. , 2005, Journal of clinical oncology : official journal of the American Society of Clinical Oncology.

[8]  J. Creed,et al.  Extraction and detection of a new arsine sulfide containing arsenosugar in molluscs by IC-ICP-MS and IC-ESI-MS/MS , 2004 .

[9]  W. Goessler,et al.  Thio arsenosugars identified as natural constituents of mussels by liquid chromatography-mass spectrometry. , 2004, Chemical communications.

[10]  L. Ma,et al.  Arsenic complexes in the arsenic hyperaccumulator Pteris vittata (Chinese brake fern). , 2004, Journal of chromatography. A.

[11]  Kevin A Francesconi,et al.  Determination of arsenic species: a critical review of methods and applications, 2000-2003. , 2004, The Analyst.

[12]  J. Feldmann,et al.  The Nature of Arsenic-Phytochelatin Complexes in Holcus lanatus and Pteris cretica1 , 2004, Plant Physiology.

[13]  Jian Zheng,et al.  Hyphenation of high performance liquid chromatography with sector field inductively coupled plasma mass spectrometry for the determination of ultra-trace level anionic and cationic arsenic compounds in freshwater fish , 2004 .

[14]  J. Thomas-Oates,et al.  2-Dimethylarsinothioyl acetic acid identified in a biological sample: the first occurrence of a mammalian arsinothioyl metabolite. , 2004, Angewandte Chemie.

[15]  V. Lallemand-Breitenbach,et al.  How acute promyelocytic leukaemia revived arsenic , 2002, Nature Reviews Cancer.

[16]  P. Craig Organometallic Compounds in the Environment , 2002 .

[17]  D. Nordstrom Worldwide Occurrences of Arsenic in Ground Water , 2002, Science.

[18]  W. Goessler,et al.  Arsenic species in an arsenic hyperaccumulating fern, Pityrogramma calomelanos: a potential phytoremediator of arsenic-contaminated soils. , 2002, The Science of the total environment.

[19]  W. Frankenberger Environmental chemistry of arsenic , 2002 .

[20]  Kazuo T. Suzuki,et al.  Identification of dimethylarsinous and monomethylarsonous acids in human urine of the arsenic-affected areas in West Bengal, India. , 2001, Chemical research in toxicology.

[21]  E. Kenyon,et al.  A concise review of the toxicity and carcinogenicity of dimethylarsinic acid. , 2001, Toxicology.

[22]  W. Cullen,et al.  Methylated trivalent arsenic species are genotoxic. , 2001, Chemical research in toxicology.

[23]  Yong Cai,et al.  A fern that hyperaccumulates arsenic , 2001, Nature.

[24]  W. Goessler,et al.  Determination of Arsenic Compounds in Earthworms , 1998 .

[25]  J. Edmonds,et al.  Arsenic and Marine Organisms , 1996 .

[26]  A. R. Byrne,et al.  Arsenobetaine and other arsenic species in mushrooms , 1995 .

[27]  K. Reimer,et al.  Arsenic speciation in the environment , 1989 .

[28]  M. Morita,et al.  Isolation and identification of arsenic-containing ribofuranosides and inorganic arsenic from Japanese edible seaweed Hizikia fusiforme , 1987 .

[29]  T. Kaise,et al.  The acute toxicity of arsenobetaine , 1985 .

[30]  M. Andreae Distribution and speciation of arsenic in natural waters and some marine algae , 1978 .

[31]  C. Raston,et al.  Isolation, crystal structure and synthesis of arsenobetaine, the arsenical constituent of the western rock lobster panulirus longipes cygnus George , 1977 .

[32]  P. J. Peterson,et al.  Arsenic accumulation by plants on mine waste (United Kingdom) , 1975 .