Atomic layer deposition of tin dioxide sensing film in microhotplate gas sensors

We report the use of atomic layer deposition (ALD) to produce the gas-sensitive tin dioxide film in a microhotplate gas sensor. The performance of the device was demonstrated using ethanol, acetone and acrylonitrile as model analytes. Fast response times and low drift rates of the output signal were measured, indicating a structurally stable tin dioxide film and reflecting the capabilities of ALD in gas sensor applications. Fabrication of the microhotplate using tungsten metallization and plasma deposited silicon dioxide dielectrics is also detailed.

[1]  Thomas J. McAvoy,et al.  Surface state trapping models for SnO2-based microhotplate sensors , 2001 .

[2]  Steven M. George,et al.  Surface Chemistry for Atomic Layer Growth , 1996 .

[3]  Danick Briand,et al.  Design and fabrication of high-temperature micro-hotplates for drop-coated gas sensors , 2000 .

[4]  Libor Gajdošík The concentration measurement with SnO2 gas sensor operated in the dynamic regime , 2005 .

[5]  T. Uustare,et al.  Atomic-layer chemical vapor deposition of SnO2 for gas-sensing applications , 2001 .

[6]  A. Hårsta,et al.  Growth of SnO2 thin films by atomic layer deposition and chemical vapour deposition: A comparative study , 2006 .

[7]  D. Cameron,et al.  Influence of oxygen depletion layer on the properties of tin oxide gas-sensing films fabricated by atomic layer deposition , 2009 .

[8]  N. Bârsan,et al.  Micromachined metal oxide gas sensors: opportunities to improve sensor performance , 2001 .

[9]  C. Ghanshyam,et al.  Alcohol sensing of tin oxide thin film prepared by sol-gel process , 2002 .

[10]  Dieter Kohl,et al.  Function and applications of gas sensors , 2001 .

[11]  U. Diebold,et al.  The surface and materials science of tin oxide , 2005 .

[12]  N. Bârsan,et al.  Conduction Model of Metal Oxide Gas Sensors , 2001 .

[13]  Steven M. George,et al.  Thickness dependence of sensor response for CO gas sensing by tin oxide films grown using atomic layer deposition , 2008 .

[14]  R. P. Gupta,et al.  Oxide Materials for Development of Integrated Gas Sensors—A Comprehensive Review , 2004 .

[15]  Kengo Shimanoe,et al.  Diffusion equation-based study of thin film semiconductor gas sensor-response transient , 2002 .

[16]  Sheikh A. Akbar,et al.  Ceramics for chemical sensing , 2003 .

[17]  Ada Fort,et al.  Simplified models for SnO2 sensors during chemical and thermal transients in mixtures of inert, oxidizing and reducing gases , 2007 .