A review analyzing the industrial biodiesel production practice starting from vegetable oil refining

One of the most promising renewable fuels proposed as an alternative to fossil diesel is biodiesel. The competitive potential of biodiesel is limited by the price of vegetable oils, which strongly influences the final price of this biofuel. On the other hand, extensive use of vegetable oils may cause other significant problems such as starvation in developing countries. Appropriately planning and designing the whole production process, from the seed to the biodiesel end-product, is essential to contain the influence of energy inefficiencies on the high price of the end-product. The present study reviews the technologies currently used in the production of biodiesel. We first discuss the technologies for extracting the vegetable oil from the seed, and its subsequent refining and conversion into biodiesel. This study focuses on the characteristics of the production processes currently used in the sector, illustrating the technological options and emphasizing the drawbacks of certain practices and the best choices available. The vegetable oils tend to be processed using procedures that are well established, but oriented more towards obtaining products suitable for the foodstuffs industry, and that consequently use technologies that are sometimes excessive for energetic purposes. The processes for extracting the vegetable oil from the seed generally include a set of steps, the complexity of which depends on the raw material. Basically, the two extraction technologies involved rely on the use of pressure or solvents. In practice, the two systems are often combined. Using the vegetable oils as a source of energy makes some of these steps superfluous and enables technologies to be used that would be unsuitable for foodstuffs production. This study focuses on feasible technological improvements that would give rise to oil that is still suitable for use as a source of energy, but at a lower cost. The refined vegetable oil can subsequently be converted into biodiesel by means of a great variety of technologies, many of which are still not suitable for applications on an industrial scale. The solution that has met with the greatest favor is homogeneous alkaline transesterification with KOH and methanol. Even when dealing with this type of conversion alone, it is impossible to establish a universal schema to describe the conversion or purification stages because there are numerous possible different solutions. When we then look more closely at the state of the art in industrial biodiesel production plants, we encounter the potential problems introduced by the type and characteristics of the original raw material. Comparing some of the reference solutions that have inspired numerous installations, a sensitivity analysis is conducted on the main elements involved in the process, focusing on their behavior in different working conditions to obtain products with the characteristics required by the international standards (EN 14214:2008, ASTM D 6751 07b).

[1]  Kevin Kendall,et al.  Steam reforming of biodiesel by-product to make renewable hydrogen. , 2008, Bioresource technology.

[2]  Jeanette G. Grasselli,et al.  CRC Handbook of Data on Organic Compounds , 1985 .

[3]  M. Zheng,et al.  Biodiesel Reaction Screening Using Oscillatory Flow Meso Reactors , 2007 .

[4]  Veera Gnaneswar Gude,et al.  Biodiesel from waste cooking oils via direct sonication , 2013 .

[5]  Robert O. Dunn,et al.  Effect of antioxidants on the oxidative stability of methyl soyate (biodiesel) , 2005 .

[6]  G. Vicente,et al.  Application of the factorial design of experiments and response surface methodology to optimize biodiesel production , 1998 .

[7]  Ayhan Demirbas,et al.  Biodiesel: A Realistic Fuel Alternative for Diesel Engines , 2007 .

[8]  S. O. Jekayinfa,et al.  Alkali-catalysed laboratory production and testing of biodiesel fuel from Nigerian palm kernel oil. , 2007 .

[9]  Jeffrey Philip Obbard,et al.  Recovery and pre-treatment of fats, oil and grease from grease interceptors for biodiesel production , 2010 .

[10]  C. Su.  Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production , 2013 .

[11]  Ioannis K. Kookos,et al.  Techno-economic analysis of a biodiesel production process from vegetable oils , 2009 .

[12]  M. Berrios,et al.  A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil , 2007 .

[13]  M. Mbarawa,et al.  Alkaline catalyzed biodiesel production from moringa oleifera oil with optimized production parameters , 2010 .

[14]  P. V. Danckwerts.  Continuous flow systems , 1953 .

[15]  J. Sevilla,et al.  Mixotrophic growth of the microalga Phaeodactylum tricornutum: Influence of different nitrogen and organic carbon sources on productivity and biomass composition , 2005 .

[16]  E. Frankel,et al.  Limited extraction of soybeans with hexane , 1986 .

[17]  Mohamed Kheireddine Aroua,et al.  Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil , 2013 .

[18]  Lin Lin,et al.  Opportunities and challenges for biodiesel fuel , 2011 .

[19]  Kahraman Bozbas,et al.  Biodiesel as an alternative motor fuel: Production and policies in the European Union , 2008 .

[20]  D. Firestone,et al.  Official methods and recommended practices of the AOCS , 2009 .

[21]  W. Luyben.  Distillation Design and Control Using Aspen Simulation , 2006 .

[22]  Ram Prasad,et al.  TRIGLYCERIDES-BASED DIESEL FUELS , 2000 .

[23]  A. Demirbas,et al.  Importance of biodiesel as transportation fuel , 2007 .

[24]  Chen Guo,et al.  Microalgal biodiesel in China: Opportunities and challenges , 2011 .

[25]  Nor Aishah Saidina Amin,et al.  A review on novel processes of biodiesel production from waste cooking oil , 2013 .

[26]  E. Lutton,et al.  X-Ray Diffraction Analyses of Synthetic Unsaturated Monacid Diglycerides1 , 1947 .

[27]  Juan C. Yori,et al.  Influence of the Axial Dispersion on the Performance of Tubular Reactors during the Noncatalytic Supercritical Transesterification of Triglycerides , 2006 .

[28]  C. Sorrentino,et al.  OECD Factbook 2005: Economic, Environmental and Social Statistics , 2005 .

[29]  K. Kobe.  The properties of gases and liquids , 1959 .

[30]  J. M. Marchetti,et al.  Technoeconomic study of supercritical biodiesel production plant , 2008 .

[31]  M. Dubé,et al.  Acid-Catalyzed Transesterification of Canola Oil to Biodiesel under Single- and Two-Phase Reaction Conditions , 2007 .

[32]  de Ab André Haan,et al.  Hydraulic pressing of oilseeds: Experimental determination and modeling of yield and pressing rates , 2008 .

[33]  H. Noureddini,et al.  Kinetics of transesterification of soybean oil , 1997 .

[34]  P. Pontalier,et al.  Extraction of sunflower oil by twin screw extruder: screw configuration and operating condition effects. , 2006, Bioresource technology.

[35]  Weiyang Zhou,et al.  Phase distributions of alcohol, glycerol, and catalyst in the transesterification of soybean oil , 2006 .

[36]  Samia Ashraf,et al.  Production of sunflower oil methyl esters by optimized alkali-catalyzed methanolysis. , 2008 .

[37]  D. Julian McClements,et al.  Physical properties of liquid edible oils , 1997 .

[38]  E. H. Pryde,et al.  Transesterification kinetics of soybean oil 1 , 1986 .

[39]  M. P. Dorado,et al.  KINETIC PARAMETERS AFFECTING THE ALKALI-CATALYZED TRANSESTERIFICATION PROCESS OF USED OLIVE OIL , 2004 .

[40]  A. Kondo,et al.  Biodiesel fuel production by transesterification of oils. , 2001, Journal of bioscience and bioengineering.

[41]  Naoko Ellis,et al.  Assessment of four biodiesel production processes using HYSYS.Plant. , 2008, Bioresource technology.

[42]  Don-Hee Park,et al.  Batch (one- and two-stage) production of biodiesel fuel from rapeseed oil , 1996, Applied biochemistry and biotechnology.

[43]  R. Gonzalez,et al.  Anaerobic fermentation of glycerol: a path to economic viability for the biofuels industry. , 2007, Current opinion in biotechnology.

[44]  Catherine Xuereb,et al.  3-D hydrodynamics in a tank stirred by a double-propeller system and filled with a liquid having evolving rheological properties , 1996 .

[45]  Gurutze Arzamendi,et al.  Alkaline and alkaline-earth metals compounds as catalysts for the methanolysis of sunflower oil , 2008 .

[46]  E. Weidner,et al.  Biodiesel-Transesterification of Biological Oils with Liquid Catalysts: Thermodynamic Properties of Oil−Methanol−Amine Mixtures , 2005 .

[47]  K. Westerterp,et al.  Chemical reactor design and operation , 1983 .

[48]  A. J. Angelo,et al.  Lipid oxidation in food , 1996 .

[49]  Aage Fredenslund,et al.  UNIFAC parameter table for prediction of liquid-liquid equilibriums , 1981 .

[50]  Gerhard Knothe,et al.  SOME ASPECTS OF BIODIESEL OXIDATIVE STABILITY , 2007 .

[51]  F. Skopal,et al.  Treatment of glycerol phase formed by biodiesel production. , 2010, Bioresource technology.

[52]  Choo Yuen May,et al.  KINETICS STUDY ON TRANSESTERIFICATION OF PALM OIL , 2004 .

[53]  M. Martínez,et al.  PILOT PLANT STUDIES OF BIODIESEL PRODUCTION USING BRASSICA CARINATA AS RAW MATERIAL , 2005 .

[54]  Pierre-Yves Pontalier,et al.  Oil extraction of oleic sunflower seeds by twin screw extruder: influence of screw configuration and operating conditions , 2005 .

[55]  Maialen Sánchez,et al.  Synthesis of biodiesel with heterogeneous NaOH/alumina catalysts: Comparison with homogeneous NaOH , 2007 .

[56]  Y. Yeşiloğlu.  Immobilized lipase-catalyzed ethanolysis of sunflower oil , 2004 .

[57]  B. Singh,et al.  Advancements in development and characterization of biodiesel: A review , 2008 .

[58]  H. J. Wright,et al.  A report on ester interchange , 1944 .

[59]  J. Kinsella.  Handbook of Food Additives , 1973 .

[60]  Shabbir H. Gheewala,et al.  Full chain energy analysis of biodiesel production from palm oil in Thailand , 2009 .

[61]  Elio Santacesaria,et al.  Kinetics of Oleic Acid Esterification with Methanol in the Presence of Triglycerides , 2005 .

[62]  R. C. Weast.  CRC Handbook of Chemistry and Physics , 1973 .

[63]  A. J. Angelo.  Lipid oxidation in food , 1992 .

[64]  H. Noureddini,et al.  Improved conversion of plant oils and animal fats into biodiesel and co-product , 1996 .

[65]  Dong Ying,et al.  Biodiesel production from crude rice bran oil and properties as fuel , 2009 .

[66]  G. Vicente,et al.  Integrated biodiesel production: a comparison of different homogeneous catalysts systems. , 2004, Bioresource technology.

[67]  Esteban A. Brignole,et al.  Phase equilibria in ternary mixtures of methyl oleate, glycerol, and methanol , 2008 .

[68]  Keat-Teong Lee,et al.  Ultrasound-assisted transesterification of crude Jatropha oil using alumina-supported heteropolyacid catalyst , 2013 .

[69]  Ayhan Demirbas,et al.  Competitive liquid biofuels from biomass , 2011 .

[70]  M. Dubé,et al.  Single-Phase and Two-Phase Base-Catalyzed Transesterification of Canola Oil to Fatty Acid Methyl Esters at Ambient Conditions , 2006 .

[71]  A. Demirbas,et al.  Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods , 2005 .

[72]  M. Matsumura,et al.  Kinetics of hydroxide‐catalyzed methanolysis of crude sunflower oil for the production of fuel‐grade methyl esters , 2007 .

[73]  M. Martínez,et al.  A comparative study of the production of ethyl esters from vegetable oils as a biodiesel fuel optimization by factorial design , 2007 .

[74]  D. Leung,et al.  A review on biodiesel production using catalyzed transesterification , 2010 .

[75]  Bhaskar Singh,et al.  Towards a sustainable approach for development of biodiesel from plant and microalgae , 2014 .

[76]  P. V. Danckwerts.  Continuous flow systems. Distribution of residence times , 1995 .

[77]  Pinaki S. Bhadury,et al.  A facile and feasible method to evaluate and control the quality of Jatropha curcus L. seed oil for biodiesel feedstock: Gas chromatographic fingerprint , 2011 .

[78]  T Leevijit,et al.  Performance test of a 6-stage continuous reactor for palm methyl ester production. , 2008, Bioresource technology.

[79]  S. Pereda,et al.  Gas–liquid reactions under supercritical conditions—phase equilibria and thermodynamic modeling , 2002 .

[80]  Ralf Dohrn,et al.  High-pressure fluid-phase equilibria: Experimental methods and systems investigated (1988–1993) , 1995 .

[81]  Linda S. Heath,et al.  The greenhouse gas and energy impacts of using wood instead of alternatives in residential construction in the United States , 2008 .

[82]  Olivera S. Stamenković,et al.  Kinetics of the base-catalyzed sunflower oil ethanolysis , 2010 .

[83]  Kazuo Miyashita,et al.  Study on the oxidative rate and prooxidant activity of free fatty acids , 1986 .

[84]  E. H. Pryde,et al.  Variables affecting the yields of fatty esters from transesterified vegetable oils , 1984 .

[85]  A. Ajanovic.  Biofuels versus food production: Does biofuels production increase food prices? , 2011 .

[86]  J. Hagemann,et al.  Differential scanning calorimetry of single acid triglycerides: Effect of chain length and unsaturation , 1972 .

[87]  M. Bockisch,et al.  Fats and Oils Handbook , 1998 .

[88]  Karen Wilson,et al.  Evaluation of the activity and stability of alkali-doped metal oxide catalysts for application to an intensified method of biodiesel production , 2008 .

[89]  Peter J. Ashman,et al.  Harvesting of marine microalgae by electroflocculation: The energetics, plant design, and economics , 2013 .

[90]  Russell Finex.  Biodiesel production : Going green to improve productivity , 2008 .

[91]  Christopher J. Brown,et al.  Simulation of pressure swing adsorption in fuel ethanol production process , 2008, Comput. Chem. Eng..

[92]  Aijie Wang,et al.  The valorization of glycerol: Economic assessment of an innovative process for the bioconversion of crude glycerol into ethanol and hydrogen , 2013 .

[93]  R. Feuge,et al.  Modification of vegetable oils. VII. Alkali catalyzed interesterification of peanut oil with ethanol , 1949 .

[94]  J. V. Gerpen,et al.  Biodiesel processing and production , 2005 .

[95]  G. Vicente,et al.  Kinetics of Sunflower Oil Methanolysis , 2005 .

[96]  Ramkrishna Sen,et al.  Biocatalytic production of biodiesel from cottonseed oil: Standardization of process parameters and comparison of fuel characteristics , 2011 .

[97]  Mercedes Martínez,et al.  Optimisation of integrated biodiesel production. Part II: a study of the material balance. , 2007, Bioresource technology.

[98]  F. Polonara,et al.  Development and optimization of a method for analyzing biodiesel mixtures with non-aqueous reversed phase liquid chromatography. , 2008, Journal of chromatography. A.

[99]  Meisam Tabatabaei,et al.  Upstream and downstream strategies to economize biodiesel production. , 2011, Bioresource technology.

[100]  Pen-Chi Chiang,et al.  Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants , 2011 .

[101]  G. Vicente,et al.  Optimisation of integrated biodiesel production. Part I. A study of the biodiesel purity and yield. , 2007, Bioresource technology.

[102]  Ayhan Demirbas,et al.  Progress and recent trends in biofuels , 2007 .

[103]  J. Nielsen,et al.  Metabolic engineering of Saccharomyces cerevisiae for production of fatty acid ethyl esters, an advanced biofuel, by eliminating non-essential fatty acid utilization pathways , 2014 .

[104]  Martin Mittelbach,et al.  The influence of antioxidants on the oxidation stability of biodiesel , 2003 .

[105]  A. Demirbas,et al.  Relationships derived from physical properties of vegetable oil and biodiesel fuels , 2008 .

[106]  J. V. Gerpen,et al.  The effect of biodiesel oxidation on engine performance and emissions , 2001 .

[107]  Robert C. Weast Jeanette G Grasselli David R. Lide,et al.  Handbook of data on organic compounds , 1994 .

[108]  C. Posten,et al.  Second Generation Biofuels: High-Efficiency Microalgae for Biodiesel Production , 2008, BioEnergy Research.

[109]  M. Holčapek,et al.  Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods. , 1999, Journal of chromatography. A.

[110]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[111]  Tyler B. Coplen,et al.  Atomic Weights of the Elements 1999 , 2001 .

[112]  R. Reid,et al.  The Properties of Gases and Liquids , 1977 .

[113]  Sunderasan Srinivasan,et al.  The food v. fuel debate: A nuanced view of incentive structures , 2009 .

[114]  G. Shama,et al.  A New Solubility Model to Describe Biodiesel Formation Kinetics , 2007 .

[115]  M. Blank,et al.  A method for the structural analysis of triglycerides and lecithins , 1963 .

[116]  D. Darnoko,et al.  Kinetics of palm oil transesterification in a batch reactor , 2000 .

[117]  Francesco Vegliò,et al.  Optimization of the transesterification reaction in biodiesel production , 2010 .

[118]  R. Scheithauer,et al.  Economics of vegetable oil processing , 1988 .

[119]  Günter Wozny,et al.  Liquid−Liquid Phase Equilibrium in Glycerol−Methanol−Methyl Oleate and Glycerol−Monoolein−Methyl Oleate Ternary Systems , 2006 .

[120]  F. Gunstone,et al.  Polymorphism in single-acid triglycerides of positional and geometric isomers of octadecenoic acid , 1975 .

[121]  Galen J. Suppes,et al.  Distribution of methanol and catalysts between biodiesel and glycerin phases , 2005 .

[122]  Tyler B. Coplen,et al.  Atomic weights of the elements 1999 (IUPAC Technical Report) , 2001 .

[123]  A. F. Errazu,et al.  Techno-economic study of different alternatives for biodiesel production , 2008 .

[124]  Cherng-Yuan Lin,et al.  Effects of emulsification variables on fuel properties of two- and three-phase biodiesel emulsions , 2007 .

[125]  Michal Holcapek,et al.  Triacylglycerols profiling in plant oils important in food industry, dietetics and cosmetics using high-performance liquid chromatography-atmospheric pressure chemical ionization mass spectrometry. , 2008, Journal of chromatography. A.

[126]  G. Prateepchaikul,et al.  A Second Order Kinetics of Palm Oil Transesterification , 2004 .

[127]  Bin Liang,et al.  Solubility of Multicomponent Systems in the Biodiesel Production by Transesterification of Jatropha curcas L. Oil with Methanol , 2006 .

[128]  S. Adhikari,et al.  Hydrogen production from glycerin by steam reforming over nickel catalysts , 2008 .

[129]  A. McAloon,et al.  A process model to estimate biodiesel production costs. , 2006, Bioresource technology.

[130]  Paolo Cabras,et al.  Lipochromes, vitamins, aromas and other components of virgin olive oil are affected by processing technology , 2001 .

[131]  Lilian L. N. Guarieiro,et al.  The Role of Additives for Diesel and Diesel Blended (Ethanol or Biodiesel) Fuels: A Review , 2007 .

[132]  Narendra,et al.  Transesterification process to manufacture ethyl ester of rape oil , 1993 .

[133]  P. Westh,et al.  Novel investigation of enzymatic biodiesel reaction by isothermal calorimetry , 2010 .

[134]  U. Rashid,et al.  Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil , 2008 .

[135]  A. Arteconi,et al.  Quantitation of Compounds in Biodiesel Mixtures with Reversed-Phase Liquid Chromatography , 2009 .

[136]  Soon Huat Tan,et al.  Cytocompatibility and Mechanical Properties of Hydroxyapatite Composite Reinforced with Multi-Walled Carbon Nanotubes and Bovine Serum Albumin , 2013 .

[137]  R. Feuge,et al.  Physical properties of aceto- and butyro-oleins, mono-olein, and diolein , 1957 .

[138]  L. C. Meher,et al.  Technical aspects of biodiesel production by transesterification—a review , 2006 .

[139]  Jürgen Krahl,et al.  The Biodiesel Handbook , 2005 .

[140]  K. J. Harrington,et al.  Transesterification in situ of sunflower seed oil , 1985 .

[141]  Farid Chemat,et al.  Green procedure with a green solvent for fats and oils' determination. Microwave-integrated Soxhlet using limonene followed by microwave Clevenger distillation. , 2008, Journal of chromatography. A.

[142]  Havva Balat,et al.  Progress in biodiesel processing , 2010 .

[143]  Jerry D. Murphy,et al.  A critical review of the applicability of biodiesel and grass biomethane as biofuels to satisfy both biofuel targets and sustainability criteria , 2011 .

[144]  L. Baldi,et al.  Vegetable oil market and biofuel policy: An asymmetric cointegration approach , 2010 .

[145]  M. Sharma,et al.  Stability of biodiesel and its blends: A review , 2010 .

[146]  R. Lal.  World crop residues production and implications of its use as a biofuel. , 2005, Environment international.

[147]  Sam Behzadi,et al.  Production of biodiesel using a continuous gas-liquid reactor. , 2009, Bioresource technology.

[148]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 1. Process design and technological assessment. , 2003, Bioresource technology.

[149]  Y. Chisti.  Biodiesel from microalgae beats bioethanol. , 2008, Trends in biotechnology.

[150]  Nghi Nguyen,et al.  Retrofit of distillation columns in biodiesel production plants , 2010 .

[151]  Zhenhong Yuan,et al.  Biodiesel from different oil using fixed-bed and plug-flow reactors , 2010 .

[152]  C. Baroi,et al.  Biodiesel Production from Jatropha curcas Oil Using Potassium Carbonate as an Unsupported Catalyst , 2009 .

[153]  Ralf Dohrn,et al.  High-pressure fluid phase equilibria , 2002 .

[154]  J. Tait,et al.  Ethical Framework for Biofuels , 2011, Science.

[155]  M. Sharma,et al.  Biodiesel production from Jatropha curcas oil , 2010 .

[156]  O. A. Odejobi,et al.  Mathematical modelling and simulation of the hydraulic expression of oil from oil palm fruit , 2008 .

[157]  Ján Cvengroš,et al.  Study of FAME Stability , 2008 .

[158]  J. Marchetti,et al.  Possible methods for biodiesel production , 2007 .

[159]  Elio Santacesaria,et al.  Heterogeneous catalysts for biodiesel production , 2008 .

[160]  A. Fröhlich,et al.  The Influence of Tocopherols on the Oxidation Stability of Methyl Esters , 2007 .

[161]  M. E. D. Silva,et al.  Minimization of peroxide formation rate in soybean oil by antioxidant combinations , 2004 .

[162]  Giulio Santori,et al.  Bioenergy II: Modeling and Multi-Objective Optimization of Different Biodiesel Production Processes , 2010 .

[163]  E. D. Cyan.  Handbook of Chemistry and Physics , 1970 .

[164]  Olivera S. Stamenković,et al.  The effect of agitation intensity on alkali-catalyzed methanolysis of sunflower oil. , 2007, Bioresource technology.

[165]  G. Knothe.  Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters , 2005 .