Bridging the academic and industrial metrics for next-generation practical batteries

Batteries have shaped much of our modern world. This success is the result of intense collaboration between academia and industry over the past several decades, culminating with the advent of and improvements in rechargeable lithium-ion batteries. As applications become more demanding, there is the risk that stunted growth in the performance of commercial batteries will slow the adoption of important technologies such as electric vehicles. Yet the scientific literature includes many reports describing material designs with allegedly superior performance. A considerable gap needs to be filled if we wish these laboratory-based achievements to reach commercialization. In this Perspective, we discuss some of the most relevant testing parameters that are often overlooked in academic literature but are critical for practical applicability outside the laboratory. We explain metrics such as anode energy density, voltage hysteresis, mass of non-active cell components and anode/cathode mass ratio, and we make recommendations for future reporting. We hope that this Perspective, together with other similar guiding principles that have recently started to emerge, will aid the transition from lab-scale research to next-generation practical batteries.This Perspective discussed the best practices for reporting lab-scale performance metrics in battery papers.

[1]  Tao Gao,et al.  An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes , 2018, Nature Chemistry.

[2]  Guangyuan Zheng,et al.  Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries , 2013, Nature Communications.

[3]  Ji-Guang Zhang,et al.  Tailored Reaction Route by Micropore Confinement for Li–S Batteries Operating under Lean Electrolyte Conditions , 2018 .

[4]  Jie Gao,et al.  Mechanistic insights into operational lithium–sulfur batteries by in situ X-ray diffraction and absorption spectroscopy , 2014 .

[5]  C. Liang,et al.  Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery , 2009 .

[6]  Stefan A. Freunberger,et al.  True performance metrics in beyond-intercalation batteries , 2017, Nature Energy.

[7]  Kevin G. Gallagher,et al.  Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes , 2013 .

[8]  B. Chowdari,et al.  Metal oxides and oxysalts as anode materials for Li ion batteries. , 2013, Chemical reviews.

[9]  Doron Aurbach,et al.  The study of electrolyte solutions based on solvents from the “glyme” family (linear polyethers) for secondary Li battery systems , 1997 .

[10]  Li Li,et al.  Aprotic and aqueous Li-O₂ batteries. , 2014, Chemical reviews.

[11]  Lide M. Rodriguez-Martinez,et al.  Review—Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries: Promises and Challenges , 2018 .

[12]  Tao Zheng,et al.  Mechanisms for Lithium Insertion in Carbonaceous Materials , 1995, Science.

[13]  Meng Liu,et al.  Li2O-Reinforced Cu Nanoclusters as Porous Structure for Dendrite-Free and Long-Lifespan Lithium Metal Anode. , 2016, ACS applied materials & interfaces.

[14]  Feng Li,et al.  More Reliable Lithium‐Sulfur Batteries: Status, Solutions and Prospects , 2017, Advanced materials.

[15]  Jian Jiang,et al.  Recent Advances in Metal Oxide-Based Electrode Architecture Design for Electrochemical Energy Storage , 2012 .

[16]  Young-Geun Lim,et al.  Effect of carbon types on the electrochemical properties of negative electrodes for Li-ion capacitor , 2011 .

[17]  Deyan Luan,et al.  α-Fe2O3 nanotubes with superior lithium storage capability. , 2011, Chemical communications.

[18]  Y. Gogotsi,et al.  True Performance Metrics in Electrochemical Energy Storage , 2011, Science.

[19]  Hyun-Wook Lee,et al.  High-capacity battery cathode prelithiation to offset initial lithium loss , 2016, Nature Energy.

[20]  Wen Lei,et al.  3D Porous Carbon Sheets with Multidirectional Ion Pathways for Fast and Durable Lithium–Sulfur Batteries , 2018 .

[21]  Ali Elkamel,et al.  Tailoring the chemistry of blend copolymers boosting the electrochemical performance of Si-based anodes for lithium ion batteries , 2017 .

[22]  Jiangtao Hu,et al.  A Metal–Organic‐Framework‐Based Electrolyte with Nanowetted Interfaces for High‐Energy‐Density Solid‐State Lithium Battery , 2018, Advanced materials.

[23]  Donghai Wang,et al.  Nitrogen‐Doped Mesoporous Carbon Promoted Chemical Adsorption of Sulfur and Fabrication of High‐Areal‐Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium‐Sulfur Batteries , 2014 .

[24]  E. W. Washburn The Dynamics of Capillary Flow , 1921 .

[25]  Yi Cui,et al.  Carbon-silicon core-shell nanowires as high capacity electrode for lithium ion batteries. , 2009, Nano letters.

[26]  Michael J Sailor,et al.  Mesoporous silicon sponge as an anti-pulverization structure for high-performance lithium-ion battery anodes , 2014, Nature Communications.

[27]  Kun Feng,et al.  Gas Pickering Emulsion Templated Hollow Carbon for High Rate Performance Lithium Sulfur Batteries , 2016 .

[28]  Wei Zhang,et al.  Visualizing the chemistry and structure dynamics in lithium-ion batteries by in-situ neutron diffraction , 2012, Scientific Reports.

[29]  Candace K. Chan,et al.  Crystalline-amorphous core-shell silicon nanowires for high capacity and high current battery electrodes. , 2009, Nano letters.

[30]  Chunsheng Wang,et al.  Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells , 2007 .

[31]  Guangyuan Zheng,et al.  Interconnected hollow carbon nanospheres for stable lithium metal anodes. , 2014, Nature nanotechnology.

[32]  A. Cadenato,et al.  Effects of experimental sample mass on the calorimetric study of thermoset resins , 1992 .

[33]  Jintao Zhang,et al.  Necklace‐Like Structures Composed of Fe3N@C Yolk–Shell Particles as an Advanced Anode for Sodium‐Ion Batteries , 2018, Advanced materials.

[34]  E. Yoo,et al.  Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries. , 2008, Nano letters.

[35]  Kevin G. Gallagher,et al.  Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density , 2013 .

[36]  Jianming Zheng,et al.  Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries , 2018 .

[37]  Jun Lu,et al.  A Lithium–Sulfur Battery using a 2D Current Collector Architecture with a Large‐Sized Sulfur Host Operated under High Areal Loading and Low E/S Ratio , 2018, Advanced materials.

[38]  Zhigang Zak Fang,et al.  A lithium–oxygen battery based on lithium superoxide , 2016, Nature.

[39]  Arumugam Manthiram,et al.  Designing Lithium-Sulfur Cells with Practically Necessary Parameters , 2018 .

[40]  Sergiy Kalnaus,et al.  Solid electrolytes for high energy density batteries , 2015 .

[41]  Yangping Sheng,et al.  Effect of Calendering on Electrode Wettability in Lithium-Ion Batteries , 2014, Front. Energy Res..

[42]  B. McCloskey,et al.  Lithium−Air Battery: Promise and Challenges , 2010 .

[43]  J. Dahn,et al.  Li-insertion in hard carbon anode materials for Li-ion batteries , 1999 .

[44]  Qiang Zhang,et al.  Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries , 2017 .

[45]  Kevin G. Gallagher,et al.  Critical Link between Materials Chemistry and Cell-Level Design for High Energy Density and Low Cost Lithium-Sulfur Transportation Battery , 2015 .

[46]  Xueliang Sun,et al.  Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application , 2018, Electrochemical Energy Reviews.

[47]  Arumugam Manthiram,et al.  Rational Design of Statically and Dynamically Stable Lithium–Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio , 2018, Advanced materials.

[48]  Candace K. Chan,et al.  High-performance lithium battery anodes using silicon nanowires. , 2008, Nature nanotechnology.

[49]  Jianming Zheng,et al.  Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material , 2015 .

[50]  Haihui Wang,et al.  Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries , 2010 .

[51]  Kevin G. Gallagher,et al.  Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries , 2016 .

[52]  Yet-Ming Chiang,et al.  Electrodeposition Kinetics in Li-S Batteries: Effects of Low Electrolyte/Sulfur Ratios and Deposition Surface Composition , 2017 .

[53]  Guangyuan Zheng,et al.  Nanostructured sulfur cathodes. , 2013, Chemical Society reviews.

[54]  Jun Lu,et al.  Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy , 2017, Nature Communications.

[55]  Yu. L. Shishkin The effect of sample mass and heating rate on DSC results when studying the fractional composition and oxidative stability of lube base oils , 2006 .

[56]  Stephen J. Harris,et al.  Simultaneous Operando Measurements of the Local Temperature, State of Charge, and Strain inside a Commercial Lithium-Ion Battery Pouch Cell , 2018 .

[57]  Jun Liu,et al.  Improving Lithium-Sulfur Battery Performance under Lean Electrolyte through Nanoscale Confinement in Soft Swellable Gels. , 2017, Nano letters.

[58]  Kun Feng,et al.  Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications. , 2018, Small.

[59]  Yi Cui,et al.  Promises and challenges of nanomaterials for lithium-based rechargeable batteries , 2016, Nature Energy.

[60]  Doron Aurbach,et al.  The behaviour of lithium electrodes in propylene and ethylene carbonate: Te major factors that influence Li cycling efficiency , 1992 .

[61]  Li Yang,et al.  Recent progress in conversion reaction metal oxide anodes for Li-ion batteries , 2017 .

[62]  Matthew Li,et al.  Compact high volumetric and areal capacity lithium sulfur batteries through rock salt induced nano-architectured sulfur hosts , 2017 .

[63]  Jens Tübke,et al.  Lithium–Sulfur Cells: The Gap between the State‐of‐the‐Art and the Requirements for High Energy Battery Cells , 2015 .

[64]  Qingsong Wang,et al.  Thermal runaway caused fire and explosion of lithium ion battery , 2012 .

[65]  Yang-Kook Sun,et al.  Effect of the size-selective silver clusters on lithium peroxide morphology in lithium–oxygen batteries , 2014, Nature Communications.

[66]  Yang Ren,et al.  Synchrotron X‐Ray and Neutron Diffraction, Total Scattering, and Small‐Angle Scattering Techniques for Rechargeable Battery Research , 2018, Small Methods.

[67]  Fei Wei,et al.  Porous graphene networks as high performance anode materials for lithium ion batteries , 2013 .

[68]  Stefano Passerini,et al.  Critical Insight into the Relentless Progression Toward Graphene and Graphene‐Containing Materials for Lithium‐Ion Battery Anodes , 2017, Advanced materials.

[69]  Jun Lu,et al.  30 Years of Lithium‐Ion Batteries , 2018, Advanced materials.

[70]  M. Winter,et al.  Performance and cost of materials for lithium-based rechargeable automotive batteries , 2018 .

[71]  Arumugam Manthiram,et al.  Progress on the Critical Parameters for Lithium–Sulfur Batteries to be Practically Viable , 2018, Advanced Functional Materials.

[72]  Ryne P. Raffaelle,et al.  Carbon nanotubes for lithium ion batteries , 2009 .

[73]  Jianming Zheng,et al.  High Energy Density Lithium–Sulfur Batteries: Challenges of Thick Sulfur Cathodes , 2015 .

[74]  G. Shi,et al.  Graphene based new energy materials , 2011 .

[75]  Young Jin Nam,et al.  Toward practical all-solid-state lithium-ion batteries with high energy density and safety: Comparative study for electrodes fabricated by dry- and slurry-mixing processes , 2018 .

[76]  Jean-Marie Tarascon,et al.  Li-O2 and Li-S batteries with high energy storage. , 2011, Nature materials.

[77]  Jie Xiao,et al.  Understanding the Lithium Sulfur Battery System at Relevant Scales , 2015 .

[78]  Jin-Song Hu,et al.  Carbon Coated Fe3O4 Nanospindles as a Superior Anode Material for Lithium‐Ion Batteries , 2008 .

[79]  Yet-Ming Chiang,et al.  Compliant Yet Brittle Mechanical Behavior of Li2S–P2S5 Lithium‐Ion‐Conducting Solid Electrolyte , 2017 .

[80]  Sarmimala Hore,et al.  Synthesis of Hierarchically Porous Carbon Monoliths with Highly Ordered Microstructure and Their Application in Rechargeable Lithium Batteries with High‐Rate Capability , 2007 .

[81]  Wen Lei,et al.  Stringed “tube on cube” nanohybrids as compact cathode matrix for high-loading and lean-electrolyte lithium–sulfur batteries , 2018 .

[82]  Emmanuel C. Alozie,et al.  Promises and Challenges , 2015 .

[83]  Said Al-Hallaj,et al.  Design and simulation of a lithium-ion battery with a phase change material thermal management system for an electric scooter , 2004 .

[84]  Petr Novák,et al.  Progress Towards Commercially Viable Li–S Battery Cells , 2015 .

[85]  Jun Lu,et al.  State-of-the-art characterization techniques for advanced lithium-ion batteries , 2017, Nature Energy.