Hydrogen from steam reforming of ethanol in low and middle temperature range for fuel cell application

The catalyst, Ni nano-particles supported on Y2O3, which was prepared by three methods, was studied. The structural properties of the catalysts were tested through X-ray diffraction and BET area. The catalyst of Ni/Y2O3 exhibits high activity for ethanol steam reforming with conversion of ethanol of 98% and selectivity of hydrogen of 38% at 300°C, conversion of ethanol of 98% and selectivity of hydrogen of 55% at 380°C. With temperature increasing to and above 500°C, the conversion of ethanol increased to 100%, but the selectivity of hydrogen did not increase so much, it was 58% at 600°C. The catalyst has long-term stability for steam reforming of ethanol and is a good choice for ethanol processors for fuel cell applications.

[1]  L. F. Brown A comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles , 2001 .

[2]  D. Bukur,et al.  Pretreatment effect studies with a precipitated iron Fischer–Tropsch catalyst in a slurry reactor , 1999 .

[3]  T. Nakajima,et al.  Effect of crystallite size on the catalysis of alumina-supported cobalt catalyst for steam reforming of ethanol , 1998 .

[4]  Lars-Gunnar Ekedahl,et al.  Isotopic study of ethanol dehydrogenation over a palladium membrane , 2000 .

[5]  M. A. Laborde,et al.  Hydrogen production by the steam reforming of ethanol: Thermodynamic analysis , 1991 .

[6]  G. Maggio,et al.  Light alcohols/methane fuelled molten carbonate fuel cells: a comparative study , 1998 .

[7]  P. Umasankar,et al.  Steam reforming of ethanol for hydrogen production : thermodynamic analysis , 1996 .

[8]  S. J. Morrison,et al.  The reactions of ethanol over M/CeO2 catalysts: Evidence of carbon–carbon bond dissociation at low temperatures over Rh/CeO2 , 2000 .

[9]  Vidyadhar Sudhir Ranade,et al.  Hydrogenation of crotonaldehyde over Pt based bimetallic catalysts , 1997 .

[10]  S. J. Morrison,et al.  A Study of the Reactions of Ethanol on CeO2 and Pd/CeO2 by Steady State Reactions, Temperature Programmed Desorption, and In Situ FT-IR , 1999 .

[11]  Lars-Gunnar Ekedahl,et al.  Hydrogen permeation through surface modified Pd and PdAg membranes , 2001 .

[12]  S. Cavallaro,et al.  Ethanol steam reforming on Rh/Al2O3 catalysts , 2000 .

[13]  Lars-Gunnar Ekedahl,et al.  Alcohol dehydrogenation over Pd versus PdAg membranes , 2001 .

[14]  J. Llorca,et al.  Direct production of hydrogen from ethanolic aqueous solutions over oxide catalysts , 2001 .

[15]  Xenophon E. Verykios,et al.  Steam reforming of biomass-derived ethanol for the production of hydrogen for fuel cell applications , 2001 .

[16]  H. Idriss,et al.  H2 Production from Ethanol over Rh–Pt/CeO2 Catalysts: The Role of Rh for the Efficient Dissociation of the Carbon–Carbon Bond , 2002 .

[17]  S. Chuang,et al.  Activity and selectivity of Group VIII, alkali-promoted Mn-Ni, and Mo-based catalysts for C2+ oxygenate synthesis from the CO hydrogenation and CO/H2/C2H4 reactions , 2000 .

[18]  S. J. Morrison,et al.  A Study of Ethanol Reactions over Pt/CeO2 by Temperature-Programmed Desorption and in Situ FT-IR Spectroscopy: Evidence of Benzene Formation , 2000 .

[19]  Ilie Fishtik,et al.  A thermodynamic analysis of hydrogen production by steam reforming of ethanol via response reactions , 2000 .

[20]  S. Freni,et al.  Ethanol steam reforming in a molten carbonate fuel cell. A preliminary kinetic investigation , 1996 .

[21]  S. Freni,et al.  Rh based catalysts for indirect internal reforming ethanol applications in molten carbonate fuel cells , 2001 .

[22]  S. Mishima,et al.  Catalytic Properties of Supported Transition Metal Catalysts for Conversion of Ethanol in the Presence of Water Vapor. , 1997 .

[23]  Miguel Laborde,et al.  Hydrogen from steam reforming of ethanol. characterization and performance of copper-nickel supported catalysts , 1998 .

[24]  T. Nakajima,et al.  Catalytic properties of supported cobalt catalysts for steam reforming of ethanol , 1997 .