Behaviour of plutonium in the environment

Plutonium is one of the most toxic components of spent nuclear fuel and of nuclear wastes, which is characterized by very complex chemical behaviour both in engineering processes and under environmental conditions. As a result of the human activities, plutonium is released to the environment and its speciation depends, to a large extent, on the source and release scenario and also on the geochemical conditions. The most recent data about various sources of plutonium in the environment and its speciation are reviewed. The recent trends in the description of one of the most important processes in plutonium migration, i.e., its sorption onto components of soils, rocks, colloidal particles of various origin, natural organic matter, etc., are discussed. The bibliography includes 98 references.

[1]  U. Schwertmann,et al.  Iron Oxides , 2003, SSSA Book Series.

[2]  E. V. Zakharova,et al.  Partitioning and speciation of Pu in the sedimentary rocks aquifer from the deep liquid nuclear waste disposal , 2015 .

[3]  P. Fenter,et al.  Surface-mediated formation of Pu(IV) nanoparticles at the muscovite-electrolyte interface. , 2013, Environmental science & technology.

[4]  S. Conradson,et al.  Formation of crystalline PuO2+x·nH2O nanoparticles upon sorption of Pu(V,VI) onto hematite , 2013 .

[5]  B. Powell,et al.  Pu(V) and Pu(IV) sorption to montmorillonite. , 2013, Environmental science & technology.

[6]  A. Aldahan,et al.  127I and 129I species and transformation in the Baltic proper, Kattegat, and Skagerrak basins. , 2012, Environmental science & technology.

[7]  B. Powell,et al.  Np(V) and Pu(v) ion exchange and surface-mediated reduction mechanisms on montmorillonite. , 2012, Environmental science & technology.

[8]  L. Weng,et al.  The effects of humic substances on the transport of radionuclides: Recent improvements in the prediction of behaviour and the understanding of mechanisms , 2012 .

[9]  T. Tyliszczak,et al.  Impact of natural organic matter on uranium transport through saturated geologic materials: from molecular to column scale. , 2011, Environmental science & technology.

[10]  C. Poinssot,et al.  Radionuclide behaviour in the natural environment: an overview , 2012 .

[11]  M. Singleton,et al.  Mobilization of actinides by dissolved organic compounds at the Nevada Test Site , 2011 .

[12]  Z. Dai,et al.  Stabilization of plutonium nano-colloids by epitaxial distortion on mineral surfaces. , 2011, Environmental science & technology.

[13]  M. Denecke,et al.  Actinide Nanoparticle Research , 2011 .

[14]  R. Kukkadapu,et al.  Influence of iron redox transformations on plutonium sorption to sediments , 2010 .

[15]  P. Worsfold,et al.  Plutonium isotopes as tracers for ocean processes: a review. , 2010, Marine environmental research.

[16]  Yu. A. Sapozhnikov,et al.  Alpha track analysis and fission track analysis for localizing actinide-bearing micro-particles in the Yenisey River bottom sediments , 2008 .

[17]  X. Tan,et al.  Sorption of Eu(III) on humic acid or fulvic acid bound to hydrous alumina studied by SEM-EDS, XPS, TRLFS, and batch techniques. , 2008, Environmental science & technology.

[18]  Lester R. Morss,et al.  The chemistry of the actinide and transactinide elements , 2006 .

[19]  J. T. Coates,et al.  Pu(V)O2+ adsorption and reduction by synthetic hematite and goethite. , 2005, Environmental science & technology.

[20]  D. Schild,et al.  The redox behaviour of plutonium in humic rich groundwater , 2004 .

[21]  J. T. Coates,et al.  Pu(V)O2+ adsorption and reduction by synthetic magnetite (Fe3O4). , 2004, Environmental science & technology.

[22]  B. Taylor,et al.  Solid-solution partitioning of plutonium in surface waters at the Atomic Weapons Establishment Aldermaston (UK). , 2004, The Science of the total environment.

[23]  N. Priest,et al.  Source-term characterisation and solid speciation of plutonium at the Semipalatinsk NTS, Kazakhstan. , 2004, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[24]  P. Mitchell,et al.  Geochemical fractionation of plutonium in anoxic Irish Sea sediments using an optimised sequential extraction protocol. , 2004, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[25]  G. Waychunas,et al.  Molecular interfacial reactions between Pu(VI) and manganese oxide minerals manganite and hausmannite. , 2003, Environmental science & technology.

[26]  F. C. Benedict,et al.  Colloid-Facilitated Transport of Low-Solubility Radionuclides: A Field, Experimental, and Modeling Investigation , 2003 .

[27]  E. Voice The radiological consequences of the Chernobyl accident , 1997 .

[28]  G. Kelly,et al.  Proceedings of the first international conference 'The radiological consequences of the Chernobyl accident' , 1996 .

[29]  L. León Vintró,et al.  Recent observations on the physico-chemical speciation of plutonium in the Irish Sea and the western Mediterranean , 1995 .

[30]  J. Brainard,et al.  Solubilization of plutonium hydrous oxide by iron-reducing bacteria. , 1994, Environmental science & technology.