Supply and demand of some critical metals and present status of their recycling in WEEE.

New development and technological innovations make electrical and electronic equipment (EEE) more functional by using an increasing number of metals, particularly the critical metals (e.g. rare and precious metals) with specialized properties. As millions of people in emerging economies adopt a modern lifestyle, the demand for critical metals is soaring. However, the increasing demand causes the crisis of their supply because of their simple deficiency in the Earth's crust or geopolitical constraints which might create political issues for their supply. This paper focuses on the sustainable supply of typical critical metals (indium, rare earth elements (REEs), lithium, cobalt and precious metals) through recycling waste electrical and electronic equipment (WEEE). To illuminate this issue, the production, consumption, expected future demand, current recycling situation of critical metals, WEEE management and their recycling have been reviewed. We find that the demand of indium, REEs, lithium and cobalt in EEE will continuously increasing, while precious metals are decreasing because of new substitutions with less or even without precious metals. Although the generation of WEEE in 2014 was about 41.9 million tons (Mt), just about 15% (6.5 Mt) was treated environmentally. The inefficient collection of WEEE is the main obstacle to relieving the supply risk of critical metals. Furthermore, due to the widespread use in low concentrations, such as indium, their recycling is not just technological problem, but economic feasibility is. Finally, relevant recommendations are point out to address these issues.

[1]  F. Ferella,et al.  Treatment of exhaust fluorescent lamps to recover yttrium: experimental and process analyses. , 2011, Waste management.

[2]  Horst Clauberg,et al.  Copper Wire Bonding: R&D to High Volume Manufacturing , 2012 .

[3]  Jinhui Li,et al.  Rare Earth Elements Recovery from Waste Fluorescent Lamps: A Review , 2015 .

[4]  Ata Akcil WEEE: Booming for sustainable recycling. , 2016, Waste management.

[5]  R. Eggert Minerals go critical. , 2011, Nature chemistry.

[6]  Thomas G. Goonan,et al.  Lithium use in batteries , 2012 .

[7]  Bo Liu,et al.  Challenges in legislation, recycling system and technical system of waste electrical and electronic equipment in China. , 2015, Waste management.

[8]  Jinhui Li,et al.  Recycling Indium from Scraped Glass of Liquid Crystal Display: Process Optimizing and Mechanism Exploring , 2015 .

[9]  T. Graedel,et al.  Challenges in Metal Recycling , 2012, Science.

[10]  Haochen Zhu,et al.  Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl). , 2016, Waste Management.

[11]  Milind Kandlikar,et al.  Assessing extended producer responsibility laws in Japan. , 2007, Environmental science & technology.

[12]  Suthipong Sthiannopkao,et al.  Handling e-waste in developed and developing countries: initiatives, practices, and consequences. , 2013, The Science of the total environment.

[13]  G Prabaharan,et al.  An innovative approach to recover the metal values from spent lithium-ion batteries. , 2016, Waste management.

[14]  Her-Yung Wang,et al.  A study of the effects of LCD glass sand on the properties of concrete. , 2009, Waste management.

[15]  Jack Jeswiet,et al.  A Review of Lithium Supply and Demand and a Preliminary Investigation of a Room Temperature Method to Recycle Lithium Ion Batteries to Recover Lithium and Other Materials , 2014 .

[16]  Li Zeng,et al.  Recovery of indium from used indium–tin oxide (ITO) targets , 2011 .

[17]  F. Renaud,et al.  A review of the environmental fate and effects of hazardous substances released from electrical and electronic equipments during recycling: Examples from China and India , 2010 .

[18]  Marco Evangelisti,et al.  The importance of being exchanged: [Gd(III)4M(II)8(OH)8(L)8(O2CR)8]4+ clusters for magnetic refrigeration. , 2012, Angewandte Chemie.

[19]  Xiuli Yang,et al.  Rare earth element recycling from waste nickel-metal hydride batteries. , 2014, Journal of hazardous materials.

[20]  Satoshi Itoh,et al.  Recoveries of Metallic Indium and Tin from ITO by Means of Pyrometallurgy , 2011 .

[21]  J. Allwood,et al.  What Do We Know About Metal Recycling Rates? , 2011 .

[22]  D. C. Zeng,et al.  Low hysteresis and large room temperature magnetocaloric effect of Gd5Si2.05−xGe1.95−xNi2x (2x = 0.08, 0.1) alloys , 2013 .

[23]  I. O. Ogunniyi,et al.  Chemical composition and liberation characterization of printed circuit board comminution fines for beneficiation investigations. , 2009, Waste management.

[24]  T. Graedel,et al.  Global Rare Earth In‐Use Stocks in NdFeB Permanent Magnets , 2011 .

[25]  Xianlai Zeng,et al.  Uncovering the Recycling Potential of "New" WEEE in China. , 2016, Environmental science & technology.

[26]  C. Searcy,et al.  A literature review and a case study of sustainable supply chains with a focus on metrics , 2012 .

[27]  Nobuaki Sato,et al.  Recovering Indium from the Liquid Crystal Display of Discarded Cellular Phones by Means of Chloride-Induced Vaporization at Relatively Low Temperature , 2009 .

[28]  B. Moyer,et al.  Challenges to achievement of metal sustainability in our high-tech society. , 2014, Chemical Society reviews.

[29]  Marco Evangelisti,et al.  A Dense Metal–Organic Framework for Enhanced Magnetic Refrigeration , 2013, Advanced materials.

[30]  R. Ramanujan,et al.  Low hysteresis and large room temperature magnetocaloric effect of Gd5Si2.05−xGe1.95−xNi2x (2x = 0.08, 0.1) alloys , 2013 .

[31]  D. Apelian,et al.  Rare-Earth Economics: The Balance Problem , 2013 .

[32]  Koen Binnemans,et al.  Selective extraction of metals using ionic liquids for nickel metal hydride battery recycling , 2014 .

[33]  Sumohan Misra,et al.  Structural and magnetic characteristics of Gd5Ga(x)Si(4-x). , 2010, Inorganic chemistry.

[34]  C. Ekberg,et al.  Indium recovery from discarded LCD panel glass by solvent extraction , 2013 .

[35]  Tedd E. Lister,et al.  Recovery of critical and value metals from mobile electronics enabled by electrochemical processing , 2014 .

[36]  Jinhui Li,et al.  Regional or global WEEE recycling. Where to go? , 2013, Waste management.

[37]  XiaoZhi Lim,et al.  Chemistry: Degrees of separation , 2015, Nature.

[38]  Keqiang Qiu,et al.  Vacuum pyrolysis and hydrometallurgical process for the recovery of valuable metals from spent lithium-ion batteries. , 2011, Journal of hazardous materials.

[39]  Jun Sadaki,et al.  Separation of Rare Earth Fluorescent Powders by Two-Liquid Flotation using Organic Solvents , 2008, Japanese Journal of Applied Physics.

[40]  V. S. Rotter,et al.  Assessment of Precious Metal Flows During Preprocessing of Waste Electrical and Electronic Equipment , 2009 .

[41]  John Baxter,et al.  Critical metals in discarded electronics , 2016 .

[42]  N. Menad,et al.  New characterisation method of electrical and electronic equipment wastes (WEEE). , 2013, Waste management.

[43]  A. Volinsky,et al.  Rare earth elements recycling from waste phosphor by dual hydrochloric acid dissolution. , 2014, Journal of hazardous materials.

[44]  Jon J. Kellar,et al.  Opportunities and challenges for treating rare-earth elements , 2014 .

[45]  Ata Akcil,et al.  Precious metal recovery from waste printed circuit boards using cyanide and non-cyanide lixiviants--A review. , 2015, Waste management.

[46]  Richard Roth,et al.  Evaluating rare earth element availability: a case with revolutionary demand from clean technologies. , 2012, Environmental science & technology.

[47]  Jan Kosmol,et al.  Present and potential future recycling of critical metals in WEEE , 2014 .

[48]  Zhenming Xu,et al.  Recycling indium from waste liquid crystal display panel by vacuum carbon-reduction. , 2014, Journal of hazardous materials.

[49]  B. D. Pandey,et al.  Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone. , 2013, Waste management.

[50]  P. Sommer,et al.  Battery related cobalt and REE flows in WEEE treatment. , 2015, Waste management.

[51]  Mathias Schluep,et al.  Where are WEEE in Africa? , 2012, 2012 Electronics Goes Green 2012+.

[52]  Sunil Herat,et al.  E-waste: a problem or an opportunity? Review of issues, challenges and solutions in African countries , 2016 .

[53]  F.O. Ongondo,et al.  How are WEEE doing? A global review of the management of electrical and electronic wastes. , 2011, Waste management.

[54]  B. Ślusarek,et al.  Study of the magnetic interaction in nanocrystalline Pr-Fe-Co-Nb-B permanent magnets , 2012 .

[55]  E. Tanabe,et al.  Recovery of indium from LCD screens of discarded cell phones. , 2015, Waste management.

[56]  Martin Streicher-Porte,et al.  Informal electronic waste recycling: a sector review with special focus on China. , 2011, Waste management.

[57]  Wei Wang,et al.  An evaluation of the potential yield of indium recycled from end-of-life LCDs: A case study in China. , 2015, Waste management.

[58]  Daniel Riedel,et al.  Polymer-based scattering layers for internal light extraction from organic light emitting diodes , 2016 .

[59]  Zhenming Xu,et al.  Precious metals recovery from waste printed circuit boards: A review for current status and perspective , 2016 .

[60]  Takahiro Higuchi,et al.  High-efficiency organic light-emitting diodes with fluorescent emitters , 2014, Nature Communications.

[61]  Shengen Zhang,et al.  Recovery of waste rare earth fluorescent powders by two steps acid leaching , 2013, Rare Metals.

[62]  Sheng-Jen Hsieh,et al.  Process for recovery of indium from ITO scraps and metallurgic microstructures , 2009 .

[63]  V. S. Rotter,et al.  Challenges for the recovery of critical metals from waste electronic equipment - A case study of indium in LCD panels , 2012, 2012 Electronics Goes Green 2012+.

[64]  C. Hagelüken,et al.  Recycling of gold from electronics: Cost-effective use through ‘Design for Recycling’ , 2010 .

[65]  M. Zientek,et al.  Platinum-group elements: so many excellent properties , 2014 .

[66]  E. Gidarakos,et al.  Leaching capacity of metals-metalloids and recovery of valuable materials from waste LCDs. , 2015, Waste management.

[67]  R. Kleijn,et al.  Recycling as a strategy against rare earth element criticality: a systemic evaluation of the potential yield of NdFeB magnet recycling. , 2013, Environmental science & technology.

[68]  Tom Van Gerven,et al.  Recycling of rare earths: a critical review , 2013 .

[69]  C Ninlawan,et al.  The Implementation of Green Supply Chain Management Practices in Electronics Industry , 2022 .

[70]  L. Delmau,et al.  Selective Extraction of Rare Earth Elements from Permanent Magnet Scraps with Membrane Solvent Extraction. , 2015, Environmental science & technology.

[71]  F. Ferella,et al.  Separation and recovery of glass, plastic and indium from spent LCD panels. , 2017, Waste management.

[72]  A. Bloodworth Resources: Track flows to manage technology-metal supply , 2013, Nature.

[73]  Koen Binnemans,et al.  Rare-earth recycling using a functionalized ionic liquid for the selective dissolution and revalorization of Y2O3:Eu3+ from lamp phosphor waste , 2015 .

[74]  Jinhui Li,et al.  Recycling of Spent Lithium-Ion Battery: A Critical Review , 2014 .

[75]  Yasuhiko Hotta,et al.  EPR-based Electronic Home Appliance Recycling System under Home Appliance Recycling Act of Japan , 2014 .

[76]  Jeong-Gon Kim,et al.  Material flow and industrial demand for palladium in Korea , 2013 .

[77]  M. Alsheyab,et al.  Potential recovery of precious metals from waste laptops in Jordan , 2015, Rare Metals.

[78]  Fengxia Hu,et al.  Permanent magnetic properties of rapidly quenched (La,Ce)2Fe14B nanomaterials based on La–Ce mischmetal , 2015 .

[79]  Ruediger Kuehr,et al.  The Global E-waste Monitor 2017: Quantities, Flows and Resources , 2015 .

[80]  Hitoshi Yamaguchi,et al.  Separation and concentration of indium from a liquid crystal display via homogeneous liquid–liquid extraction , 2013 .

[81]  Bernd Kopacek,et al.  Environmental impact assessment of hydrometallurgical processes for metal recovery from WEEE residues using a portable prototype plant. , 2013, Environmental science & technology.