论文信息 - The photodissociation of water by doped iron oxides: The unblased p/n assembly

The photodissociation of water by doped iron oxides: The unblased p/n assembly

Abstract Mott-Schottky capacitance measurements are used to locate semiconductor band edges for a short-circuited p-type/n-type α-Fe 2 O 3 assembly in aqueous solution. The thermodynamic feasibility of the catalytic photodiscussion of water without external bias is verified for this assembly from an energy level diagram obtained for the electrode/electrolyte interfaces. Photocurrent stability and Auger analysis of the electrode show no evidence of electrode dissolution. Oxygen evolution is monitored from an assembly using mass spectrometry and H 2 18 O enriched water.

Gabor A. Somorjai | J. E. Turner | M. Hendewerk

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