Energy, temporal and spectral characteristics of HF-laser pumped by non-chain chemical reaction initiated by radially converging e-beam, planar e-beam and non-self-sustained discharge have been investigated. The major channels of vibrationally excited HF molecules formation have been analysed. It has been confirmed that the high efficiency (~ 10 %) of non-chain HF laser can be reached only by simultaneous atomic and molecular fluorine formation under the action of e-beam and molecular fluorine participation in the inversion releasing process. It is shown that the laser pulse has a complex spectral-temporal structure caused by consecutive generation of the P-lines P2?P1?P3?P4?P5?P6 and overlapping of the rotary lines of the same oscillatory band and separate oscillatory lines during a pulse of radiation. With e-beam pumping of a 30 1 active volume laser, the output energy as high as 115 J and efficiency with respect to e-beam energy deposited into gas mixture up to 8 % were demonstrated. The optimal gas mixture SF6 : H2 =8 : 1 under pressure of 0.45 atm has been obtained. At pressure 1 .1 atm and non-uniform output distribution, total laser energy and efficiency with respect to e-beam energy deposited into gas were found to be up to 200 J and 1 1 %, respectively. Use of e-beam initiated low pressure pulsed discharge for excitation HF molecules leads to increase of radiation energy in 2.8 times. Also investigations on zeolite-based different absorbents influence on energy stability of HF-laser are presented and radiation energy decay after 103 shoots not more than 15-20 % is gained.