Polyoxometalate clusters as building blocks: preparation and structure of bis(hexamolybdate) complexes covalently bridged by organodiimido ligands

Covalently linked polyoxometalate clusters are produced in the reaction of organic diisocyanates with [Bu4N]2[Mo6O19], suggesting the development of extended interconnected networks incorporating polyoxometalate ions.

[1]  R. Thouvenot,et al.  Phenylimido derivatives of [Mo6O19]2−: syntheses, X-ray structures, vibrational, electrochemical, 95Mo and 14N NMR studies , 1994 .

[2]  R. Ostrander,et al.  Ensheathing a Polyoxometalate: Convenient Systematic Introduction of Organoimido Ligands at Terminal Oxo Sites in [Mo6O19]2- , 1994 .

[3]  R. McMahon,et al.  Structure and reactivity of [HFe(CO)3(η3-C3H5)] , 1993 .

[4]  V. Balzani,et al.  Decanuclear homo- and heterometallic polypyridine complexes: syntheses, absorption spectra, luminescence, electrochemical oxidation, and intercomponent energy transfer , 1992 .

[5]  Mong Liang,et al.  (o-phenylenediimido)- and (p-phenylenediimido)ditungsten complexes , 1992 .

[6]  G. Whitesides,et al.  Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures. , 1991, Science.

[7]  N. Edelstein,et al.  [(MeC5H4)3U]2[.mu.-1,4-N2C6H4]: a bimetallic molecule with antiferromagnetic coupling between the uranium centers , 1990 .

[8]  Changmin Kim,et al.  p-Phenylenediimido complexes of rhenium(V) and their coupling reactions: novel multimetallic chains , 1989 .

[9]  Yuhua Du,et al.  Modeling the ammoxidation of propylene to acrylonitrile: the conversion of an allylimido(2-) ligand to an allylideneamido(1-) ligand , 1988 .

[10]  D. Devore,et al.  Coupling Metal Centers with Linearly Bridging, Delocalized, π‐Bonded Ligands: p‐Phenylenediimido Dimolybdenum Complexes , 1988 .

[11]  V. Day,et al.  Synthesis and structure of the [(.eta.5-C5H5)Ti(Mo5O18)]3- and [(.eta.5-C5H5)Ti(W5O18)]3- anions , 1985 .

[12]  H. Allcock,et al.  Crystal and molecular structure of a new hexamolybdate-cyclophosphazene complex , 1973 .

[13]  A. Rheingold,et al.  A polyoxometalate incorporating an organoimido ligand: preparation and structure of [Mo5O18(MoNC6H4CH3)]2- , 1992 .

[14]  R. Errington,et al.  X-ray crystal structure of [{WCl3(PMe2Ph)2}2 {μ-NC6H4N-1,4}]. The first structural characterization of a binuclear complex containing a 1,4-phenylenediimido bridge , 1992 .

[15]  Achim Müller,et al.  Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines , 1991 .