A mixed conducting electrode for the Alkali Metal Thermal to Electric Converter (AMTEC) has been made and tested. The electrode is made from a slurry of metal and TiO2 powders which is applied to the electrolyte and fired to sinter the electrode material. During the first 48–72 hours of operation in a SETC, the electrode takes up Na from low pressure sodium vapor to make a metal-Na-Ti-O compound. This compound is electronically conducting and ionically conducting to sodium; electronic conduction is also provided by the metal in the electrode. With a mixed conducting electrode made from robust, low vapor pressure materials, the promise for improved performance and lifetime is high.