Heat-induced formation of one-dimensional coordination polymers on Au(111): an STM study.

The formation of one-dimensional coordination polymers of cyano-substituted porphyrin derivatives on Au(111) induced by thermal annealing is demonstrated by means of scanning tunnelling microscopy. The polymer is stabilised by an unusual threefold coordination motif mediated between an Au atom and the cyano groups of the porphyrin derivatives.

[1]  B. Hammer,et al.  A surface coordination network based on copper adatom trimers. , 2014, Angewandte Chemie.

[2]  P. Bäuerle,et al.  Orbital redistribution in molecular nanostructures mediated by metal-organic bonds. , 2014, ACS nano.

[3]  A. Ciesielski,et al.  Molecular tectonics based nanopatterning of interfaces with 2D metal-organic frameworks (MOFs). , 2014, Chemical communications.

[4]  M. Persson,et al.  On-surface synthesis of a two-dimensional porous coordination network: Unraveling adsorbate interactions , 2014 .

[5]  M. Wörle,et al.  Gram-scale synthesis of two-dimensional polymer crystals and their structure analysis by X-ray diffraction. , 2014, Nature chemistry.

[6]  T. Jung,et al.  Controlling the dimensionality of on-surface coordination polymers via endo- or exoligation. , 2014, Journal of the American Chemical Society.

[7]  H. Fuchs,et al.  Surface supported gold-organic hybrids: on-surface synthesis and surface directed orientation. , 2014, Small.

[8]  Zhengbang Wang,et al.  Nanoporous designer solids with huge lattice constant gradients: multiheteroepitaxy of metal-organic frameworks. , 2014, Nano letters.

[9]  U. Meinhardt,et al.  Cyano‐Functionalized Triarylamines on Au(111): Competing Intermolecular versus Molecule/Substrate Interactions , 2014 .

[10]  A. Gourdon,et al.  Manipulating the Conformation of Single Organometallic Chains on Au(111) , 2014 .

[11]  P. Liu,et al.  Coordination self-assembly of bromo-phenyl and pyridyl functionalized porphyrins with Fe on an Au(111) surface. , 2013, Physical chemistry chemical physics : PCCP.

[12]  P. Szabelski,et al.  Understanding Pattern Formation in 2D Metal–Organic Coordination Systems on Solid Surfaces , 2013 .

[13]  P. Liu,et al.  Steering on-surface polymerization with metal-directed template. , 2013, Journal of the American Chemical Society.

[14]  M. Ward,et al.  Functional behaviour from controlled self-assembly: challenges and prospects. , 2013, Chemical Society reviews.

[15]  A. Arnau,et al.  Bonding and Charge Transfer in Metal–Organic Coordination Networks on Au(111) with Strong Acceptor Molecules , 2012 .

[16]  H. Freund,et al.  Effect of lattice-gas atoms on the adsorption behaviour of thioether molecules. , 2012, Physical chemistry chemical physics : PCCP.

[17]  E. W. Meijer,et al.  Functional Supramolecular Polymers , 2012, Science.

[18]  Kalpataru Das,et al.  Extended two-dimensional metal-organic frameworks based on thiolate-copper coordination bonds. , 2011, Journal of the American Chemical Society.

[19]  M. Persson,et al.  STM fingerprint of molecule-adatom interactions in a self-assembled metal-organic surface coordination network on Cu(111). , 2010, Physical chemistry chemical physics : PCCP.

[20]  L. Bartels.  Tailoring molecular layers at metal surfaces. , 2010, Nature chemistry.

[21]  F. Diederich,et al.  Modification of supramolecular binding motifs induced by substrate registry: formation of self-assembled macrocycles and chain-like patterns. , 2009, Chemistry.

[22]  S. De Feyter,et al.  Molecular and supramolecular networks on surfaces: from two-dimensional crystal engineering to reactivity. , 2009, Angewandte Chemie.

[23]  J. Barth.  Fresh perspectives for surface coordination chemistry , 2009 .

[24]  N. Lin,et al.  Porphyrin-based two-dimensional coordination Kagome lattice self-assembled on a Au(111) surface. , 2009, Journal of the American Chemical Society.

[25]  J. Barth,et al.  High-quality 2D metal-organic coordination network providing giant cavities within mesoscale domains. , 2009, Journal of the American Chemical Society.

[26]  J. Barth,et al.  Surface-confined supramolecular coordination chemistry. , 2009, Topics in current chemistry.

[27]  Talat S. Rahman,et al.  A surface coordination network based on substrate-derived metal adatoms with local charge excess. , 2008, Angewandte Chemie.

[28]  Yeliang Wang,et al.  Metal-organic coordination interactions in Fe-terephthalic acid networks on Cu(100). , 2008, Journal of the American Chemical Society.

[29]  A. Arnau,et al.  Metal-organic honeycomb nanomeshes with tunable cavity size. , 2007, Nano letters.

[30]  K. Kern,et al.  Hierarchical assembly of two-dimensional homochiral nanocavity arrays. , 2003, Journal of the American Chemical Society.

[31]  R. Berndt,et al.  Self-assembly of 1-nitronaphthalene on Au(111) , 2000 .

[32]  Wilson,et al.  Nucleation of ordered Ni island arrays on Au(111) by surface-lattice dislocations. , 1991, Physical review letters.

[33]  Jaklevic,et al.  Scanning-tunneling-microscope observation of surface diffusion on an atomic scale: Au on Au(111). , 1988, Physical review letters.