Syntheses of Diarylethenes by Perylene-catalyzed Photodesulfonylation from Ethenyl Sulfones

Diarylethenes were obtained from the corresponding ethenyl sulfones by photocatalyzed desulfonylation using UV or blue LEDs. When perylene and i-Pr2NEt were used as a photocatalyst and a sacrificin...

[1]  T. Ikoma,et al.  Visible Light and Hydroxynaphthylbenzimidazoline Promoted Transition-Metal-Catalyst-Free Desulfonylation of N-Sulfonylamides and N-Sulfonylamines. , 2018, The Journal of organic chemistry.

[2]  Shin‐ya Takizawa,et al.  Benzimidazolium Naphthoxide Betaine Is a Visible Light Promoted Organic Photoredox Catalyst. , 2018, The Journal of organic chemistry.

[3]  A. Sudo,et al.  Organic Photoredox Catalyst with Substrate-capture Ability: A Perylene Derivative Bearing Urethane Moiety for Reductive Coupling of Ketones and Aldehydes under Visible Light , 2018 .

[4]  D. Gueyrard.  Extension of the Modified Julia Olefination on Carboxylic Acid Derivatives: Scope and Applications , 2017, Synlett.

[5]  A. Orita,et al.  Trimethylsilyl Group Assisted Stimuli Response: Self-Assembly of 1,3,6,8-Tetrakis((trimethysilyl)ethynyl)pyrene , 2017 .

[6]  K. Kakiuchi,et al.  Utilization of microflow reactors to carry out synthetically useful organic photochemical reactions , 2016 .

[7]  Xiaomin Xie,et al.  Visible Light-Induced Radical Rearrangement to Construct C-C Bonds via an Intramolecular Aryl Migration/Desulfonylation Process. , 2016, The Journal of organic chemistry.

[8]  Volker Hessel,et al.  Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment. , 2016, Chemical reviews.

[9]  C. Yang,et al.  Difunctionalization of Alkenes via the Visible-Light-Induced Trifluoromethylarylation/1,4-Aryl Shift/Desulfonylation Cascade Reactions. , 2015, The Journal of organic chemistry.

[10]  Michael Oelgemoeller,et al.  Highlights of Photochemical Reactions in Microflow Reactors , 2012 .

[11]  C. Adachi,et al.  Fluoro-substituted Phenyleneethynylenes: Acetylenic n-Type Organic Semiconductors , 2010 .

[12]  C. Adachi,et al.  Blue emitting fluorophores of phenyleneethynylenes substituted by diphenylethenyl terminal groups for organic light-emitting diodes , 2009 .

[13]  Toshiaki Murata,et al.  Recent progress on photoreactions in microreactors , 2007 .

[14]  A. Orita,et al.  One-shot double elimination process: a practical and concise protocol for diaryl acetylenes. , 2006, Chemistry, an Asian journal.

[15]  J. Pospíšil,et al.  Sulfoxides in Julia-Lythgoe olefination: efficient and stereoselective preparation of di-, tri-, and tetrasubstituted olefins. , 2005, Organic letters.

[16]  P. R. Blakemore,et al.  The modified Julia olefination: alkene synthesis via the condensation of metallated heteroarylalkylsulfones with carbonyl compounds , 2002 .

[17]  K. Savin,et al.  USE OF SAMARIUM DIIODIDE AS AN ALTERNATIVE TO SODIUM/MERCURY AMALGAM IN THE JULIA-LYTHGOE OLEFINATION , 1995 .

[18]  M. Fujii,et al.  NAD(P)+–NAD(P)H Models. 65. Photochemical Reductive Desulfonylation of β-Keto Sulfones with Hantzsch Ester , 1988 .

[19]  J. T. Gordon,et al.  Photochemistry of Stilbenes. III. Some Aspects of the Mechanism of Photocyclization to Phenanthrenes , 1964 .