An investigation of electrical and structural properties of Ni-germanosilicided Schottky diode

Abstract Ni-germanosilicided Schottky barrier diode has been fabricated by annealing the deposited Ni film on strained-Si and characterized electrically in the temperature range of 125 K–300 K. The chemical phases and morphology of the germanosilicided films were studied by using scanning electron microscopy (SEM), cross-sectional transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS). The Schottky barrier height (ϕb), ideality factor (n) and interface state density (Dit) have been determined from the current–voltage (I–V) and capacitance–voltage (C–V) characteristics. The current–voltage characteristics have also been simulated using SEMICAD device simulator to model the Schottky junction. An interfacial layer and a series resistance were included in the diode model to achieve a better agreement with the experimental data. It has been found that the barrier height values extracted from the I–V and C–V characteristics are different, indicating the existence of an in-homogeneous Schottky interface. Results are also compared with bulk-Si Schottky diode processed in the same run. The variation of electrical properties between the strained- and bulk-Si Schottky diodes has been attributed to the presence of out-diffused Ge at the interface.

[1]  R. Stratton,et al.  Field and thermionic-field emission in Schottky barriers , 1966 .

[2]  Tung,et al.  Electron transport at metal-semiconductor interfaces: General theory. , 1992, Physical review. B, Condensed matter.

[3]  Sang Ho Oh,et al.  Improved thermal stability of Ni silicide on Si (100) through reactive deposition of Ni , 2003 .

[4]  Dimitri A. Antoniadis,et al.  Stability and composition of Ni–germanosilicided Si1−xGex films , 2004 .

[5]  Hiroshi Iwai,et al.  NiSi salicide technology for scaled CMOS , 2002 .

[6]  E. H. Rhoderick,et al.  Metal–Semiconductor Contacts , 1979 .

[7]  O. Noblanc,et al.  Barrier inhomogeneities and electrical characteristics of Ti/4H-SiC Schottky rectifiers , 1999 .

[8]  J. Shewchun,et al.  Minority carrier effects upon the small signal and steady-state properties of Schottky diodes , 1973 .

[9]  Dimitri A. Antoniadis,et al.  Interfacial reactions of Ni on Si1−xGex (x=0.2, 0.3) at low temperature by rapid thermal annealing , 2002 .

[10]  J. Sullivan,et al.  Electron transport of inhomogeneous Schottky barriers: A numerical study , 1991 .

[11]  Bantval J. Baliga,et al.  Effect of surface inhomogeneities on the electrical characteristics of SiC Schottky contacts , 1996 .

[12]  C. K. Maiti,et al.  Determination of interface state density of PtSi/strained-Si1-xGex/Si Schottky diodes , 1998 .

[13]  S. M. Sze,et al.  Physics of semiconductor devices , 1969 .

[14]  D. K. Nayak,et al.  Low‐field hole mobility of strained Si on (100) Si1−xGex substrate , 1994 .

[15]  Bing-Zong Li,et al.  Effects of the annealing temperature on Ni silicide/n-Si(100) Schottky contacts , 2004 .

[16]  C. K. Maiti,et al.  Electrical characterization of Si/Si1-xGex/Si quantum well heterostructures using a MOS capacitor , 2000 .

[17]  P. Dobson Physics of Semiconductor Devices (2nd edn) , 1982 .

[18]  T. Vogelsang,et al.  Electron transport in strained Si layers on Si1−xGex substrates , 1993 .

[19]  Shi-Li Zhang,et al.  Morphological and phase stability of nickel–germanosilicide on Si1−xGex under thermal stress , 2002 .