Combustion Characteristics and Soot Distributions of Neat Butanol and Neat Soybean Biodiesel

The combustion characteristics and soot distributions of neat butanol and neat soybean biodiesel were explored in an optical constant-volume combustion chamber using natural flame luminosity and forward illumination light extinction methods under various ambient temperatures (800 and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results demonstrated that butanol had a higher normalized peak pressure compared with the biodiesel. Soybean biodiesel autoignited earlier than butanol at 21% and 16% oxygen, while a reverse trend was found at 10.5% oxygen. The oxygen concentration had little effect on the autoignition timing for butanol when it was between 16% and 10.5% at 800–1000 K. The natural flame luminosity reduced with lowered oxygen concentration and the flame distribution was notably increased at 10.5% oxygen. At 800 K ambient temperature, there was no soot formation detected for butanol, while the net soot release for soybean biodiesel was reduced with the decrease of oxygen concentration. At 100...

[1]  S. D. Stasio Observation of restructuring of nanoparticle soot aggregates in a diffusion flame by static light scattering , 2001 .

[2]  Artur Braun,et al.  Size-range analysis of diesel soot with ultra-small angle X-ray scattering , 2004 .

[3]  Qin Zhang,et al.  Ethanol-diesel fuel blends -- a review. , 2005, Bioresource technology.

[4]  C. McEnally,et al.  Fuel decomposition and hydrocarbon growth processes for oxygenated hydrocarbons: butyl alcohols , 2005 .

[5]  Lyle M. Pickett,et al.  Diagnostic considerations for optical laser-extinction measurements of soot in high-pressure transient combustion environments , 2005 .

[6]  Thomas A. Litzinger,et al.  EFFECTS OF DIMETHYOXYMETHANE BLENDING INTO DIESEL FUEL ON SOOT IN AN OPTICALLY ACCESSIBLE DI DIESEL ENGINE , 2006 .

[7]  A. Hansen,et al.  DIESEL ENGINE PERFORMANCE AND NOX EMISSIONS FROM OXYGENATED BIOFUELS AND BLENDS WITH DIESEL FUEL , 2006 .

[8]  Dimitrios C. Rakopoulos,et al.  Comparative performance and emissions study of a direct injection Diesel engine using blends of Diesel fuel with vegetable oils or bio-diesels of various origins , 2006 .

[9]  Forward-illumination light-extinction technique for soot measurement. , 2006, Applied optics.

[10]  Jing Wang,et al.  Identification of combustion intermediates in isomeric fuel-rich premixed butanol-oxygen flames at low pressure , 2007 .

[11]  Cherian A. Idicheria,et al.  Effect of EGR on diesel premixed-burn equivalence ratio , 2007 .

[12]  Jeffrey T Moss,et al.  An experimental and kinetic modeling study of the oxidation of the four isomers of butanol. , 2008, The journal of physical chemistry. A.

[13]  Octavio Armas,et al.  Effect of biodiesel fuels on diesel engine emissions , 2008 .

[14]  Mingfa Yao,et al.  Experimental and Numerical Study of Methanol/Dimethyl Ether Dual-Fuel Compound Combustion , 2009 .

[15]  Hao Chen,et al.  Combustion and performance evaluation of a diesel engine fueled with biodiesel produced from soybean crude oil , 2009 .

[16]  A. Murugesan,et al.  Bio-diesel as an alternative fuel for diesel engines—A review , 2009 .

[17]  S. M. Sarathy,et al.  An experimental and kinetic modeling study of n-butanol combustion , 2009 .

[18]  Tiegang Fang,et al.  Biodiesel combustion in an optical HSDI diesel engine under low load premixed combustion conditions , 2009 .

[19]  Tiegang Fang,et al.  Bio-diesel effects on combustion processes in an HSDI diesel engine using advanced injection strategies , 2009 .

[20]  Mingfa Yao,et al.  Progress and recent trends in homogeneous charge compression ignition (HCCI) engines , 2009 .

[21]  C. Lee,et al.  Effect of Spray and EGR Rate on the Combustion and Emission Characteristics of Biodiesel Fuel in a Compression Ignition Engine , 2009 .

[22]  S. M. Sarathy,et al.  A chemical kinetic study of n-butanol oxidation at elevated pressure in a jet stirred reactor , 2009 .

[23]  Hua Chen,et al.  Performance and combustion characteristics of biodiesel-diesel-methanol blend fuelled engine , 2010 .

[24]  C. D. Rakopoulos,et al.  Investigation of the performance and emissions of bus engine operating on butanol/diesel fuel blends , 2010 .

[25]  John M. Simmie,et al.  Bio-butanol: Combustion properties and detailed chemical kinetic model , 2010 .

[26]  Zunqing Zheng,et al.  Experimental study of n-butanol additive and multi-injection on HD diesel engine performance and emissions , 2010 .

[27]  Ronald D Matthews,et al.  Combustion and emission characteristics of ethanol–biodiesel–water micro-emulsions used in a direct injection compression ignition engine , 2010 .

[28]  Liu Shenghua,et al.  Diesehol CI Engine Performances, Regulated and Nonregulated Emissions Characteristics , 2010 .

[29]  C. D. Rakopoulos,et al.  Effects of butanol–diesel fuel blends on the performance and emissions of a high-speed DI diesel engine , 2010 .

[30]  Su Han Park,et al.  Effects of Bioethanol-Blended Diesel Fuel on Combustion and Emission Reduction Characteristics in a Direct-Injection Diesel Engine with Exhaust Gas Recirculation (EGR) , 2010 .

[31]  Mingfa Yao,et al.  Comparison of Ethanol and Butanol as Additives in Soybean Biodiesel Using a Constant Volume Combustion Chamber , 2011 .