Tropospheric ozone from IASI: comparison of different inversion algorithms and validation with ozone sondes in the northern middle latitudes

Abstract. This paper presents a first statistical validation of tropospheric ozone products derived from measurements of the IASI satellite instrument. Since the end of 2006, IASI (Infrared Atmospheric Sounding Interferometer) aboard the polar orbiter Metop-A measures infrared spectra of the Earth's atmosphere in nadir geometry. This validation covers the northern mid-latitudes and the period from July 2007 to August 2008. Retrieval results from four different sources are presented: three are from scientific products (LATMOS, LISA, LPMAA) and the fourth one is the pre-operational product distributed by EUMETSAT (version 4.2). The different products are derived from different algorithms with different approaches. The difference and their implications for the retrieved products are discussed. In order to evaluate the quality and the performance of each product, comparisons with the vertical ozone concentration profiles measured by balloon sondes are performed and lead to estimates of the systematic and random errors in the IASI ozone products (profiles and partial columns). A first comparison is performed on the given profiles; a second comparison takes into account the altitude dependent sensitivity of the retrievals. Tropospheric columnar amounts are compared to the sonde for a lower tropospheric column (surface to about 6 km) and a "total" tropospheric column (surface to about 11 km). On average both tropospheric columns have small biases for the scientific products, less than 2 Dobson Units (DU) for the lower troposphere and less than 1 DU for the total troposphere. The comparison of the still pre-operational EUMETSAT columns shows higher mean differences of about 5 DU.

[1]  A. Thompson,et al.  Atmospheric comparison of electrochemical cell ozonesondes from different manufacturers, and with different cathode solution strengths: The Balloon Experiment on Standards for Ozonesondes , 2008 .

[2]  Kevin W. Bowman,et al.  Estimating the summertime tropospheric ozone distribution over North America through assimilation of observations from the Tropospheric Emission Spectrometer , 2008 .

[3]  John A. Nelder,et al.  A Simplex Method for Function Minimization , 1965, Comput. J..

[4]  Clive D Rodgers,et al.  Inverse Methods for Atmospheric Sounding: Theory and Practice , 2000 .

[5]  David L. Phillips,et al.  A Technique for the Numerical Solution of Certain Integral Equations of the First Kind , 1962, JACM.

[6]  M. Matricardi,et al.  Fast radiative transfer model for simulation of infrared atmospheric sounding interferometer radiances. , 1999, Applied optics.

[7]  J. Seinfeld,et al.  Atmospheric Chemistry and Physics: From Air Pollution to Climate Change , 1997 .

[8]  S. A. Clough,et al.  Operational trace gas retrieval algorithm for the Infrared Atmospheric Sounding Interferometer , 2004 .

[9]  B. T. Marshall,et al.  Validation of ozone measurements from the Atmospheric Chemistry Experiment (ACE) , 2008 .

[10]  N. Smith,et al.  With contributions from , 2007 .

[11]  S. C. Liu,et al.  Tropospheric ozone and climate , 1979, Nature.

[12]  A. Thompson,et al.  Assessment of the performance of ECC‐ozonesondes under quasi‐flight conditions in the environmental simulation chamber: Insights from the Juelich Ozone Sonde Intercomparison Experiment (JOSIE) , 2007 .

[13]  Jennifer A. Logan,et al.  Ozone climatological profiles for satellite retrieval algorithms , 2007 .

[14]  Lieven Clarisse,et al.  Monitoring of atmospheric composition using the thermal infrared IASI/METOP sounder , 2009 .

[15]  Tilman Steck,et al.  Methods for determining regularization for atmospheric retrieval problems. , 2002, Applied optics.

[16]  ANN OZONE RETRIEVAL WITHIN THE OPERATIONAL IASI LEVEL 2 PROCESSOR , 2008 .

[17]  J. Fishman,et al.  Global distribution of tropospheric ozone from satellite measurements using the empirically corrected tropospheric ozone residual technique: Identification of the regional aspects of air pollution , 2003 .

[18]  P. Bernath,et al.  Carbon monoxide distribution from the ACE‐FTS solar occultation measurements , 2005 .

[19]  Shepard A. Clough,et al.  Atmospheric radiative transfer modeling: a summary of the AER codes , 2005 .

[20]  H. Worden,et al.  Validation of Tropospheric Emission Spectrometer (TES) nadir ozone profiles , 2008 .

[21]  Cathy Clerbaux,et al.  First satellite ozone distributions retrieved from nadir high‐resolution infrared spectra , 2002 .

[22]  Toshihiro Ogawa,et al.  Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998–2000 tropical ozone climatology 1. Comparison with Total Ozone Mapping Spectrometer (TOMS) and ground-based measurements , 2003 .

[23]  T. Clarmann,et al.  Elimination of hidden a priori information from remotely sensed profile data , 2006 .

[24]  Kevin W. Bowman,et al.  Calculation of altitude-dependent tikhonov constraints for TES nadir retrievals , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[25]  Cathy Clerbaux,et al.  Retrieval and characterization of ozone vertical profiles from a thermal infrared nadir sounder , 2005 .

[26]  D. Blumstein,et al.  The IASI/MetOp1 Mission: First observations and highlights of its potential contribution to GMES2 , 2007 .

[27]  Jonathan P. Taylor,et al.  The ISSWG line-by-line inter-comparison experiment , 2003 .

[28]  Reinhard Beer,et al.  Comparisons of Tropospheric Emission Spectrometer (TES) ozone profiles to ozonesondes: Methods and initial results , 2007 .

[29]  Costas A. Varotsos,et al.  Geophysical validation of MIPAS-ENVISAT operational ozone data , 2007 .

[30]  Gang Li,et al.  The HITRAN 2008 molecular spectroscopic database , 2005 .

[31]  Reinhard Beer,et al.  Satellite measurements of the clear-sky greenhouse effect from tropospheric ozone , 2008 .

[32]  Johannes Orphal,et al.  Tropospheric ozone distributions over Europe during the heat wave in July 2007 observed from infrared nadir spectra recorded by IASI , 2008 .

[33]  Cathy Clerbaux,et al.  Measurements of total and tropospheric ozone from IASI: comparison with correlative satellite, ground-based and ozonesonde observations , 2009 .

[34]  Xiong Liu,et al.  Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation , 2005 .

[35]  T. Clarmann,et al.  MIPAS: an instrument for atmospheric and climate research , 2007 .

[36]  Franck Lefèvre,et al.  First direct simultaneous HCl and ClONO2 profile measurements in the Arctic Vortex , 1998 .