Diagnostic methods for the evaluation of the state of health (SOH) of NiMH batteries through electrochemical impedance spectroscopy

In this work, we have characterized single nickel metal hydride (NiMH) cells with Electrochemical Impedance Spectroscopy (EIS) technique to determine online the state of the batteries. Studying the variations of the obtained impedance spectra at specific frequencies, which correspond to part of the spectra that change mostly during the charge and discharge processes of the batteries, we have constructed and interpreted diagnostic diagrams through a mathematical model based on Dempster-Schafer Theory of Evidence in order to determine the SOH.

[1]  P. Bernard,et al.  Life duration of Ni–MH cells for high power applications , 2002 .

[2]  F. Huet A review of impedance measurements for determination of the state-of-charge or state-of-health of secondary batteries , 1998 .

[3]  A. Salkind,et al.  Dynamic characterization of small lead-acid cells , 2001 .

[4]  Andreas Jossen,et al.  Methods for state-of-charge determination and their applications , 2001 .

[5]  Alvin J. Salkind,et al.  Impedance modeling of intermediate size lead–acid batteries , 2003 .

[6]  C. Fennie,et al.  Fuzzy logic modelling of state-of-charge and available capacity of nickel/metal hydride batteries , 2004 .

[7]  D. Depernet,et al.  Online impedance spectroscopy of lead acid batteries for storage management of a standalone power plant , 2012 .

[8]  T. M. Nahir,et al.  Impedance Spectroscopy: Theory, Experiment, and Applications, 2nd ed Edited by Evgenij Barsoukov (Texas Instruments Inc.) and J. Ross Macdonald (University of North Carolina, Chapel Hill). John Wiley & Sons, Inc.: Hoboken, NJ. 2005. xvii + 596 pp. $125.00. ISBN 0471-64749-7. , 2005 .

[9]  D. Cuscueta,et al.  An EIS based study of a Ni–MH battery prototype. Modeling and identification analysis , 2010 .

[10]  E. Barsoukov,et al.  Impedance spectroscopy : theory, experiment, and applications , 2005 .

[11]  Antonio Sciarretta,et al.  Advances in Electrochemical Models for Predicting the Cycling Performance of Traction Batteries: Experimental Study on Ni-MH and Simulation , 2010 .

[12]  Gregory L. Plett,et al.  Extended Kalman filtering for battery management systems of LiPB-based HEV battery packs: Part 3. State and parameter estimation , 2004 .

[13]  Pritpal Singh,et al.  Equivalent circuit parameters of nickel/metal hydride batteries from sparse impedance measurements , 2004 .

[14]  Gregory L. Plett,et al.  Extended Kalman filtering for battery management systems of LiPB-based HEV battery packs: Part 2. Modeling and identification , 2004 .

[15]  Simona Salicone,et al.  Measurement Uncertainty: An Approach Via the Mathematical Theory of Evidence , 2006 .

[16]  Sun Zechang,et al.  A new SOH prediction concept for the power lithium-ion battery used on HEVs , 2009, 2009 IEEE Vehicle Power and Propulsion Conference.

[17]  U. Troeltzsch,et al.  Characterizing aging effects of lithium ion batteries by impedance spectroscopy , 2006 .