Estimating sulphide ore grade in broken rock using visible/infrared hyperspectral reflectance spectra

The field of hyperspectral remote sensing has developed rapidly for widespread mineral mapping from airborne platforms. The purpose of the current study was to examine whether hyperspectral spectrometry (0.35-2.5 w m) can be used in an underground mining environment for mapping the grade of sulphide ore in rock faces, hand specimens and core logging. Naturally broken samples of barren and ore-bearing rocks were collected from mines in the Sudbury Basin, Ontario, and dry and wet reflectance were measured. The sulphide minerals exhibit a one-sided absorption band at short wavelengths known as a conductance band. The hydroxyl-bearing silicates exhibit a triple absorption feature near 2.3 w m. Two ratios, one describing the conductance band and one describing the hydroxyl band, can be used to separate high grade ores (>20-25% sulphides) from barren and lower grade rocks. The conductance band ratio can also be used to estimate the concentration of chalcopyrite alone, - 15% chalcopyrite, absolute. Errors are proportional to the concentration of pyrrhotite and pentlandite. Errors can be reduced if total sulphides are estimated by other means, which a parallel study indicates is possible using thermal reflectance wavelengths. The study indicates that there is a high potential to use hyperspectral tools to grade sulphide ores.

[1]  G. Hunt Near-infrared (1.3-2.4 mu m) spectra of alteration minerals; potential for use in remote sensing , 1979 .

[2]  Lawrence C. Rowan,et al.  Analysis of airborne visible-infrared imaging spectrometer (AVIRIS) data of the Iron Hill, Colorado, carbonatite-alkalic igneous complex , 1995 .

[3]  Lawrence C. Rowan,et al.  Remote mineralogic and lithologic mapping of the ice river alkaline complex , 1996 .

[4]  A. J. B. Anderson,et al.  Numeric examination of multivariate soil samples , 1971 .

[5]  J. Salisbury,et al.  Visible and near infrared spectra of minerals and rocks. VI. Additional silicates , 1973 .

[6]  K. Baker,et al.  Optical properties of the clearest natural waters (200-800 nm). , 1981, Applied optics.

[7]  G. Hunt Visible and near-infrared spectra of minerals and rocks : I silicate minerals , 1970 .

[8]  John W. Salisbury,et al.  Visible and near infrared spectra of minerals and rocks: IX. Basic and ultrabasic igneous rocks , 1974 .

[9]  A. B. Lefkoff,et al.  Expert system-based mineral mapping in northern death valley, California/Nevada, using the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) , 1993 .

[10]  G. Hunt SPECTRAL SIGNATURES OF PARTICULATE MINERALS IN THE VISIBLE AND NEAR INFRARED , 1977 .

[11]  B. Rivard,et al.  Ore detection and grade estimation in the Sudbury mines using thermal infrared reflectance spectroscopy , 2001 .

[12]  F. Kruse Identification and mapping of minerals in drill core using hyperspectral image analysis of infrared reflectance spectra , 1996 .

[13]  David C. Pieri,et al.  Analysis of Airborne Visible/Infrared Imaging Spectrometer (AVTRIS) data of volcanic hot spots , 1993 .

[14]  R. Clark,et al.  High spectral resolution reflectance spectroscopy of minerals , 1990 .