论文信息 - SN2 reactions in the gas phase. Nucleophilicity effects

SN2 reactions in the gas phase. Nucleophilicity effects

The heats and entropies of gas phase association of chloride, bromide and iodide with the respective methyl halides are reported. Comparison of these results with results published for SN2 reactions in solution suggests that the solvent is the dominant factor in determining relative halide nucleophilicities for the reactions in solution.

R. Dougherty | Ralph C. Dougherty | J. David Roberts | J. Roberts

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